New modified stop-and-wait ARQ protocols for mobile communications

Mobile communication channels are frequently plagued by severe noise and disturbances such as multipath fading and doppler effects that severely degrade performance. Among the automatic-repeat-request (ARQ) protocols used to improve the communication channel reliability, the stop-and-wait (SW) is positively characterized by simple implementation and negatively by low throughputs. This work describes the application of some new SW protocols that retain the simple implementation of the classical SW schemes, while reducing the transmitter's wait state time to increase throughput. The performance of the modified SW protocols, derived through computer simulations, is shown to be comparable to that of more complex ARQ protocols.     

Dyeability of silk fabrics modified with dibasic acid anhydrides

Silk fabrics were chemically modified with different kinds of dibasic acid anhydrides. Samples with different acyl contents, ranging from 24 to 107 mol/10⁵g, were obtained by reaction with succinic (S), glutaric (G), phthalic (PA), and 0-sulfobenzoic (OSBA) anhydrides. Dyeability with a cationic dye (Rhodamine B, C.I. Basic Violet 10) was determined by measuring dye uptake and K/S values. Following acylation, the absorption of basic dye was significantly enhanced for all samples. The maximum dye uptake was attained by OSBA-treated silk fabrics, while samples treated with S. G. and PA did not differ significantly. Dye uptake increased regardless of the content, at least in the range examined. Reflectance measurements and K/S values confirmed the trend evidenced by dye uptake results. © 1994 John Wiley & Sons, Inc.     

Changes in physical properties of methacrylonitrile (MAN)-grafted silk fibers

Changes in physical properties of silk fibers, grafted with methacrylonitrile (MAN), were investigated as a function of the weight gain. The weight gain increased steadily during the first 60 min of reaction and gradually attained an equilibrium value (60%) after about 4 h. The initial tensile resistance of silk fibers decreased by MAN grafting. The crystalline structure of silk fibers remained unchanged, regardless of MAN grafting, however. a minor and broad peak appeared in the X-ray diffraction curves of MAN-grafted silk fibers with a weight gain of 60%, corresponding to the unoriented MAN polymer attached inside the fibers. Molecular orientation of silk fibroin chains in the crystalline regions, evaluated from X-ray diffraction curves, did not change significantly, while both birefringence and isotropic refractive index decreased as the weight gain increased, implying that MAN polymer attached preferentially to the amorphous and not to the crystalline regions. Dynamic vis-coelastic measurements showed that the position at which the E′ value began to decrease shifted to a lower temperature as the weight gain increased. These findings suggest that the thermal movement of silk fibroin molecules was accelerated by the presence of the poly-MAN chains attached to the amorphous regions of silk fibroin fibers. © 1993 John Wiley & Sons, Inc.     

Studies on substances with antiblastic activity. IX. Anthramycin and analogs. IX. Synthesis of 7-methoxy-8-hydroxy-10,11-dihydro-5H-pyrrolo[2,1-c] [1,4] benzodiazepine and other compounds related to oxotomaymycin

The synthesis of some pyrrolobenzodiazepine derivatives related to oxotomaymycin, an antibiotic recovered together with tomaymycin from fermentation broths of Streptomyces achromogenes var. tomaymycetics, is described. Reaction between 2-nitro-4-benzyloxy-5-methoxybenzylbromide and pyrrole-2-carboxyaldehyde afforded 1-(2-nitro-4-benzyloxy-5-methoxybenzyl)pyrrole-2-carboxyaldehyde. Catalytic reduction of this compound with hydrogen in the presence of Pd/C gave 10,11-dihydro-8-hydroxy-7-methoxy-5H-pyrrolo[2.1-c] [1,4]benzodiazepine. Amides obtained from condensation between 2-nitro-4-benzyloxy-5-methoxybenzoic acid chloride and proline or hydroxyproline were reduced catalytically to 2,3-dihydro-8-hydroxy-7-methoxy-1H-pyrrolo [2,1-c] [1,4]benzodiazepine-5,11 (10H, 11aH)-dione and its 2-hydroxyderivative respectively. The synthesis of 10,11-dihydro-8-hydroxy-9-methoxy-5-pyrrolo [2,1-c] [1,4]benzodiazepine is also reported.     

Planning optimal paths: A simple assessment of survey spatial knowledge in virtual environments

In spatial cognition studies several cognitive factors were analysed in order to identify the aspect that could constitute the basis for the capacity of organising spatial knowledge into survey maps.     

A framework for assessing the use of lean production practices in manufacturing cells

This study introduces a framework for assessing the use of lean production (LP) practices in manufacturing cells (MCs). The development of the framework included four stages: (a) defining LP practices applicable to MC, based on criteria such as the inclusion of practices that workers could observe, interact with and use on a daily basis; (b) defining attributes for each practice, emphasising the dimensions which were typical of their implementation in LP environments; (c) defining a set of evidence and sources of evidence for assessing the existence of each attribute–the sources of evidence included direct observations, analysis of documents, interviews and a feedback meeting to validate the assessment results with company representatives; (d) drawing up a model of the relationships among the LP practices, based on a survey with LP experts. This model supports the identification of improvement opportunities in MC performance based on the analysis of their interfaces. A case study of an MC from an automobile parts supplier is presented to illustrate the application of the framework.