异丙苯在Cu-HMS分子筛上的催化氧化

以含Cu的中孔分子筛(Cu-HMS)为催化剂,研究异丙苯的催化氧化。研究发现,Cu-HMS催化剂的加入使异丙苯氧化的诱导期显著缩短。在75℃下,以Cu-HMS为催化剂,O2为氧化剂的纯异丙苯氧化反应,苯乙酮为主要副产物,反应的选择性和转化率都很高。当催化剂用量为1 5×10-4mol/ml时,反应8h后,异丙苯转化率为32 7%,目的产物的累积浓度(质量分数)为37 7%,选择性为99%;反应12h后,异丙苯转化率为42 4%,目的产物的累积浓度为46 3%,选择性为95 6%。     

铝冷轧制油应用和生产工艺研究

通过对铝材冷轧工艺的分析。研究，以退火工艺中的斑痕为重点，提出采用加氢处理，异构化精制的石蜡基航空煤油组分为基础油，采用不同复合添加剂生产的通用铝冷轧制油完全可以满足客户要求。     

基于DOCSIS标准的HFC数据加密算法的分析

基于DOCSIS标准的增强型基线保密性接口（BPI＋）采用56bit DES加密分组数据，采用二密钥三重DES加密通信量加密密钥。这种多重加密技术的应用为HFC网络的数据传输提供了相当于或更好于专线级的网络安全与加密性能。     

基于CDMA智能网平台的增值业务--"位置服务"

本主要介绍基于CDMA智能网平台的一种增值业务——“位置服务”，阐述这个业务的网络结构、涉及到的技术问题和解决方案，并将这个整体思路投入到开发业务中去。     

Control of free-radical emulsion polymerization of methyl methacrylate by oxygen injection. II. Experimental study

Oxygen injection has been proposed and experimentally demonstrated as an effective control measure for limiting the rate of heat release and altering the rate of polymerization in emulsion processes. A detailed mathematical model has been previously developed to describe the system behavior with and without oxygen injection. A simple lab scale apparatus was constructed and run extensively. Only trace quantities of oxygen are needed to inhibit the reaction completely. The facile response makes this method attractive for fast temperature control. However, because of the rapid penetration of dissolved oxygen into the polymer particles, growing radical chains are terminated prematurely, lowering product molecular weights. To minimize this detrimental effect, pulsed oxygen control is used and extensive experimental work was performed to determine the effects of controller set points on molecular weight. Moderate oxygen flows and moderate set point temperatures are found to give the optimal response without significant lowering of the final molecular weight. Injected quantities agree well with the order-of-magnitude sparging calculations needed to completely stop initiation. However, complete agreement between model simulations and experimental results was not reached due to an unmeasured loss of monomer from the reactor. Chain transfer to monomer is found to be important in modeling the polymer molecular weight. It has, however, a negligible effect on the reaction rate.     

地源热泵——辐射地板联供试验

通过地源热泵－辐射地板系统冬夏联供试验，讨论了该系统作为新型环保节能空调方式的可行性及优越性，并对运行中出现的问题进行分析。     

河道治理工程水土保持设计

河道治理工程的实施会对工程区域内的自然生态环境和水土保持带来负面影响。以独流减河左堤治理工程为例 ,分析工程建设中可能造成的水土流失影响 ,从工程和生物两方面提出水土保持的防治措施 ,并对其投资进行了初步估算。     

金竹林隧道渗漏水治理技术

金竹林隧道是万梁高速公路上一座双跨连拱式隧道 ,隧道位于黄泥塘背斜北东倾伏端 ,岩层在隧道内呈单斜构造。隧道穿越北西向的山脊 ,脊顶狭窄 ,坡面顺直 ,自然坡度 2 0°～ 3 0° ,局部达 4 5°,相对高差约 1 2 0m。隧道东西口及洞身大多基岩裸露 ,植被稀少 ,仅在东洞口有小范围的粘土夹碎块石覆土层 ,厚2～ 8m ,隧道范围内孔隙水不发育 ,大气降水和地表水亦不发育 ,基岩裂隙水主要由大气降水补给。在隧道开挖过程中涌水量为 90m3 d。1　病害现状及成因分析在隧道建成后 ,但尚未正式投入运营时 ,发现中墙顶部以下多数地段 ,特别是洞口段存…     

高温预析出对Al-Zn-Mg系铝合金时效硬化和应力腐蚀的影响

研究了高温固溶后降温处理工艺对中强可使预析出LC52和7039铝合金的组织、时效硬化和应力腐蚀的影响。金相观察发现,高温预析出可优先在晶界处产生,并提高随后时效状态下晶界析出相的不连续分布程度,温度降低到一定程度晶内和晶界产生大量析出。合金拉伸性能和应力腐蚀结果表明,预析出在保持强度和塑性的同时,可提高抗应力腐蚀性能。而预析出温度降低,合金强度呈下降趋势。