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81.
Multi‐Atomic Layers of Metallic Aluminum for Ultralong Life Lithium Storage with High Volumetric Capacity 下载免费PDF全文
Jianan Gu Bin Li Zhiguo Du Chao Zhang Di Zhang Shubin Yang 《Advanced functional materials》2017,27(27)
Metallic aluminum (Al) have been explored as potential anode materials for lithium storage because of its high theoretical capacity (993 mAh g–1) and low voltage plateaus. Al possesses high electric conductivity, low cost and environmental friendliness. Unfortunately, Al suffers from huge volume change (>100%) during the lithiation/delithiation process, which inevitably results in the pulverization of electrode and rapid capacity decay during cycling processes. To circumvent above issues, a simple but efficient strategy is demonstrated to fabricate free‐standing multi‐atomic layers of metallic Al by harnessing the good ductility of Al under pressure. The resultant multi‐atomic Al layers are ultrathin, ≈3 nm, and have a large aspect ratio. Such unique features enable multi‐atomic Al nanosheets to construct uniform and compact films with graphene. Thus, the hybrid films with different ratios are achieved, in which the notorious volume change of metallic Al can be efficiently circumvented via the good flexibility of graphene, and the density of whole electrode can be significantly enhanced. As a consequence, the optimized multi‐atomic Al layers‐graphene (AlL‐G) film exhibits a very high volumetric capacity of 1089 mAh cm–3, high‐rate capability and ultralong cycle life up to 20 000 cycles for lithium storage. 相似文献
82.
We propose a self-assembly method for forming large-area high-quality solution-processed titanium oxide (TiO2) films as efficient electron transport layer for organic solar cells. The self-assembled solution-processed TiO2 layers are highly ordered and significantly improved in surface morphology over commonly-used spin-coating process resulting in better charge collection and significant material saving. When incorporated into polymer solar cells, the TiO2 device shows enhanced performance. Furthermore, we demonstrate the TiO2 can form large-area films, and achieve very uniform and improved device performances. Consequently, the self-assembled TiO2 films can be efficient and low-cost electron transport layer potentially for large-area organic optoelectronics. 相似文献
83.
An improved low distortion sigma-delta ADC(analog-to-digital converter) for wireless local area network standards is presented.A feed-forward MASH 2-2 multi-bit cascaded sigma-delta ADC is adopted;however,this work shows a much better performance than the ADCs which have been presented to date by adding a feedback factor in the second stage to improve the performance of the in-band SNDR(signal to noise and distortion ratio),using 4-bit ADCs in both stages to minimize the quantization noise.Data weighted ... 相似文献
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Kai‐Ming Hu Yun‐Qi Liu Liang‐Wei Zhou Zhong‐Ying Xue Bo Peng Han Yan Zeng‐Feng Di Xue‐Song Jiang Guang Meng Wen‐Ming Zhang 《Advanced functional materials》2020,30(34)
Obtaining a delamination‐free wrinkled functional graphene surface in layered systems is an interesting challenge because the interface is usually too weak to withstand interfacial stress mismatch, which can trigger mechanical instability. In this paper, a general strategy is proposed toward addressing the delamination limitation imposed by fabricating conformal graphene wrinkles with bilayer systems of poly(methyl methacrylate) (PMMA) and polydimethylsiloxane (PDMS). To improve the interfacial strength, a postcuring transfer process is introduced to form a gradient interface layer without interfacial liquid between the PMMA and PDMS by entanglement of polymer chains during high‐temperature curing. Compared to the conventional wet transfer of graphene,the transfer method can greatly enhance the interfacial strength. The chemical and mechanical mechanisms underlying the enhancement are revealed both experimentally and theoretically in terms of the transition from the buckled‐induced delamination state to the delamination‐free wrinkled state. Moreover, the light diffraction behaviors of multiscale graphene wrinkles are initially demonstrated to be an interesting continuous pattern induced by overlapping. The delamination‐free conformal wrinkled functional graphene surface can provide valuable insight and design guidelines for the fundamental problems of deformed graphene and its applications in flexible functional devices. 相似文献
87.
为提高稀布阵脉冲孔径雷达探测能力和小目标的发现概率,采用降低信号处理门限的方法,致使虚警概率高。常规方法难以完成目标航迹检测,需要通过TBD处理来完成目标检测。文中给出了基于多帧相关的TBD算法,利用目标的运动特性,通过对多帧数据的帧间相关处理,沿目标轨迹累积能量,从而提高信噪比,实现了在高虚警环境下的目标航迹检测。 相似文献
88.
针对突发自适应调制信号中的PSK和QAM调制方式识别问题,本文提出了一种能够识别BPSK、QPSK、8PSK以及16QAM、32QAM、64QAM、128QAM、256QAM八种信号类型的盲识别算法。该算法首先对信号的循环平稳性进行了分析和讨论,给出了利用循环高阶累积量的特征实现信号识别分类的理论依据。然后,提出了三种基于循环累积量的特征分别实现了QAM和PSK类间识别、MPSK类内识别以及方形QAM与十字形QAM的识别。最后通过对MQAM信号的瞬时幅度分布特性的深入研究和分析,提出了一种基于瞬时包络平方的方差的特征实现了QAM的类内识别。该算法选择了二叉树支持向量机作为识别分类器,并设计了一种新的识别流程完成了对上述信号调制方式的识别。该算法无需精确同步,对载波相位具有较好的鲁棒性,并能够对中频信号进行识别。仿真实验表明,该算法能够实现在较低信噪比条件下突发信号的识别。 相似文献
89.
基于S盒优化的轻量级加密算法设计 总被引:1,自引:0,他引:1
分组密码一直是解决信息系统安全问题的常用加密方法。分组密码的典型代表数据加密标准DES(Data Encryption Standard)被广泛应用于软件加密和硬件加密,其中所体现的设计思想和设计原则依然值得研究和借鉴。S盒作为DES算法的一个关键环节,它的设计好坏直接影响DES的加密性能。通过对分组密码安全性设计的分析,立足于DES算法框架,提出了一种轻量级安全加密算法LEA(Light weight Encryption Algorithm),通过增加位选逻辑陷阱来对S盒中的元素进行选取和重新优化设计,最后从S盒统计特性角度对其安全性进行分析。该算法能有效解决低成本系统的安全问题。 相似文献
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