基于逆向工程的塑料产品快速开发方案

详细介绍了曲面重构的3种主要方案：①以B-Spline为基础的重构;②以三角Bezier为基础的重构;③以扫描点直接产生曲面.刘样件进行曲面重构后,还需进行三维建模,才能进行改型设计和尺寸修改.将完成的CAD模型导入CAE软件中进行有限元分析,再优化CAD模型,之后通过快速原型设备完成样件制造.实践证明此快速开发方案可缩短开发周期.     

磷钨酸催化合成丁酮乙二醇缩酮

以磷钨酸H3 PW12 O40 为催化剂 ,通过丁酮和乙二醇反应合成丁酮乙二醇缩酮。探讨了H3 PW12 O40 对缩酮反应的催化活性 ,较系统地研究了酮醇物质的量比、催化剂用量、反应时间等因素对产品收率的影响。实验表明 :H3 PW12 O40 是合成丁酮乙二醇缩酮的良好催化剂 ,在n(酮 )∶n(醇 ) =1∶1.75 ,催化剂用量为反应物料总质量的 1.2 5 % ,环己烷为带水剂 ,反应时间 2 .0h ,反应温度 72～ 96℃的优化条件下 ,丁酮乙二醇缩酮的收率可达 5 9.5 %。     

2—（2—氨基噻唑—4—基）—2—甲氧基亚氨基乙酸乙酯的合成

以乙酰乙酸乙酯为起始原料,经肟化、甲基化、溴化和缩合四步反应合成2-(2-氨基噻唑-4-基)-2-甲氧基亚氨基乙酸乙酯,总收率63.14％,高于文献报道。     

Oligomer and Polymer Formation in Hexamethylcyclotrisiloxane (D<Subscript>3</Subscript>) – Hydrosilane Systems Under Catalysis by tris(pentafluorophenyl)borane

Summary Reactions of hexamethylcyclotrisiloxane, D₃, with 1,1,3,3-tetramethyldisiloxane, ^HMM^H, 1,1,1,3,3-pentamethyldisiloxane, ^HMM, phenyldimethylsilane and phenylmethylsilane catalyzed by tris(pentafluorophenyl)borane were studied. These reactions lead to ring opening of D₃ by the SiH reactant producing open chain oligomers with hydrosilane functionality at one or both chain ends. The reactivity of the hydrosilanes toward D₃ decreases in the series: PhMeSiH₂ > ^HMM^H > PhMe₂SiH > ^HMM. Competitive self-oligomerization of ^HMM^H and ^HMM also occurs. Primary products of these processes are able to enter into reactions with the SiH and D₃ reactants; some also undergo cyclization. Thus, consecutive and competitive processes lead to a series of various oligohomologues. Gas chromatography in conjunction with chemical ionization mass spectroscopy permitted identification of structure and determination of the basic directions of these oligomerization processes. Polysiloxanes of higher molecular weight may be also formed in some of these systems. The reactions, which occur in the systems studied, are rationalized on the basis of the mechanism involving the hydride transfer from silicon to trivalent boron. This includes the transient formation of tertiary trisilyloxonium borate which decomposes by the hydride transfer to one of the silicon atoms of the trisilyloxonium center. Footnote: This paper is dedicated to Professor Ian Manners in recognition of his significant contributions to the field of organometallic polymers.     

Detecting video frame-rate up-conversion based on periodic properties of inter-frame similarity

Video frame-rate up-conversion is one of the common operations for tampering digital videos in the temporal domain, such as creating fake high-quality videos and splicing two video clips with different frame rates. However, few existing works have been proposed for detecting this form of tampering operation. Based on the analysis of extensive experiments, we found that frame-rate up-conversion algorithms employed in most current video editing softwares will inevitably introduce some periodic artifacts into inter-frame similarity in the resulting video frame sequence. By analyzing such artifacts, we propose a simple yet very effective method to expose video after frame-rate up-conversion, and further estimate its original frame rate. The experimental results evaluated on 100 original videos at different frame rates have shown the effectiveness of the proposed method. The average detection accuracy can achieve as high as 99 % on noise-free videos in uncompressed and H.264/AVC formats. Besides, the proposed method is robust to noise as the detection accuracy could reach over 85 % and 95 % on noised videos with Gaussian white noise when SNR is 33 db and 36 db respectively.     

3D video components generation using object tracking technique

2D-to-3D conversion that would be a solution of the lack of 3D contents has been a worthy and challenging research field. In this paper, we propose a computer interactive conversion method to capture components which is used to generate 3D sequences. First, we divide the key frame into foreground and background, and then label the objects by convenient computer interactive operation. Depth information of objects is labeled after segmentation. Second, we use object tracking technique which synthesizes the advantages of kernel-based mean shift tracker and contour tracker to accomplish object depth capture for non-key frame. Finally, all the 3D information is prepared to render 3D sequences. After all, we propose our future work direction: a 2D-to-3D system which can generate 3D sequence interactively.     

Speech enhancement with an adaptive Wiener filter

This paper proposes an adaptive Wiener filtering method for speech enhancement. This method depends on the adaptation of the filter transfer function from sample to sample based on the speech signal statistics; the local mean and the local variance. It is implemented in the time domain rather than in the frequency domain to accommodate for the time-varying nature of the speech signals. The proposed method is compared to the traditional frequency-domain Wiener filtering, spectral subtraction and wavelet denoising methods using different speech quality metrics. The simulation results reveal the superiority of the proposed Wiener filtering method in the case of Additive White Gaussian Noise (AWGN) as well as colored noise.     

On the Gröbner basis triangularization of constraint equations in natural coordinates

Efficient dynamic simulation code is essential in many situations (including hardware-in-the-loop and model-predictive control applications), and highly beneficial in others (such as design optimization, sensitivity analysis, parameter identification, and controller tuning tasks). When the number of modeling coordinates n exceeds the degrees-of-freedom of the system f, as is often the case when closed kinematic chains are present, the governing dynamic equations consist of n second-order ordinary differential equations (ODEs) coupled with m=n?f algebraic constraint equations. This set of n+m index-3 differential-algebraic equations can be difficult to solve in an efficient yet accurate manner. Embedding (or generalized coordinate partitioning) can be used to obtain f ODEs (one for each independent acceleration), which are generally more amenable to numerical integration; however, the dependent positions are typically computed from the independent positions at each time step. Newton–Raphson iteration is often used for solving the position-level kinematics, but only provides solutions to within a specified tolerance, and can require several iterations to converge. In this work, Gröbner bases are used to obtain recursively solvable symbolic solutions for the dependent positions, which can then be evaluated to within machine precision using a fixed number of arithmetic operations. Natural coordinates are particularly attractive in this context, since the resulting constraint equations are maximally quadratic polynomials and are, therefore, easily triangularized. The proposed approach is suitable for use in an automated formulation procedure and, as demonstrated by three examples, is capable of generating highly efficient simulation code with minimal additional effort required at the formulation stage.     

Discovering small-world in association link networks for association learning

Association Link Network (ALN) is a kind of Semantic Link Network built by mining the association relations among multimedia Web resources for effectively supporting Web intelligent application such as Web-based learning, and semantic search. This paper explores the Small-World properties of ALN to provide theoretical support for association learning (i.e., a simple idea of “learning from Web resources”). First, a filtering algorithm of ALN is proposed to generate the filtered status of ALN, aiming to observe the Small-World properties of ALN at given network size and filtering parameter. Comparison of the Small-World properties between ALN and random graph shows that ALN reveals prominent Small-World characteristic. Then, we investigate the evolution of Small-World properties over time at several incremental network sizes. The average path length of ALN scales with the network size, while clustering coefficient of ALN is independent of the network size. And we find that ALN has smaller average path length and higher clustering coefficient than WWW at the same network size and network average degree. After that, based on the Small-World characteristic of ALN, we present an Association Learning Model (ALM), which can efficiently provide association learning of Web resources in breadth or depth for learners.     

浸入式水口燃烧式烘烤预热温度场研究

浸入式水口在浇钢以前必须进行充分预热 ,利用燃烧的煤气烘烤水口是常用的预热烘烤方式。本工作运用有限元技术对浸入式水口燃烧式烘烤预热的瞬态传热过程进行了研究 ,得到了水口烘烤预热后的温度场分布和水口的升温曲线。研究结果表明 ,在燃烧式预热烘烤方式下 ,水口沿轴线方向的温度变化梯度较大 ,水口颈部预热后的温度较低 ,是导致水口颈部频繁断裂和较易出现竹节样裂纹的主要原因。欲提高水口颈部的预热温度 ,必须改进水口的预热烘烤方式