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951.
Seon Jeong Kim Seoung Gil Yoon Young Moo Lee Kay Hyeok An Sun I. Kim 《应用聚合物科学杂志》2003,90(5):1389-1392
Temperature‐responsive interpenetrating polymer network (IPN) hydrogels constructed with poly(vinyl alcohol) and poly(diallyldimethylammonium chloride) using the sequential IPN method were studied. The characteristics of IPN hydrogels were investigated using the dynamic vapor sorption system. IPN hydrogels exhibited a relatively high sorption ratio, 180–360% at room temperature. The sorption ratio of hydrogels depended on temperature. Diffusion coefficients were calculated according to the Fickian Law at several temperatures. The apparent activation energy was 5.43 kJ mol?1, which corresponds to typical diffusion processes. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1389–1392, 2003 相似文献
952.
Four temporarily solubilised azo disperse dyes based on 1-substituted-2-hydroxypyrid-6-one were synthesised and characterised. The dyes showed high extinction coefficients and had a yellow shade on polyester fabric. They were successfully applied to polyester without the use of dispersants and the optimum pH was found to be 5. It was found that the dyes could be alkali-cleared due to ionisation of the dye under mild alkaline conditions. The dyes exhibited good to excellent fastness properties on the polyester fabric. 相似文献
953.
An interpenetrating polymer network (IPN) hydrogel composed of chitosan and polyallylamine exhibited electric‐sensitive behavior. The chitosan/polyallylamine IPN hydrogel was synthesized by radical polymerization using 2,2‐dimethoxy‐2‐phenylacetophenone (DMPAP) and methylene bisacrylicamide (MBAAm) as initiator and crosslinker, respectively. The swelling behavior of the IPN was studied by immersion of the gel samples in aqueous NaCl solutions at various concentrations and pHs. The swelling ratio decreased with increasing concentration and pH of electrolyte solution. The stimuli response of the IPN hydrogel in electric fields was also investigated. When a swollen the IPN was placed between a pair of electrodes, the IPN exhibited bending behavior in response to the applied electric field. The IPN also showed stepwise bending behavior depending on the electric stimulus. In addition, thermal properties of the IPN were investigated by differential scanning calorimetry (DSC) and dielectric analysis (DEA). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2290–2295, 2002 相似文献
954.
Ozonolysis of cyclododecene was carried out to produce an w-formyl carboxylic acid (12-oxododecanoic acid) which is derived
from zwitterion and aldehyde moiety that are formed during the reaction. The ozonolysis was performed to examine the product
distribution under such reaction variables as temperature, kinds of solvent, and presence of catalyst. The yield of polymeric
ozonide, which is undesirable product, was measured to be dominantly 86% without pyridine catalyst, whereas, only 10.25% with
the catalyst. The optimum reaction condition was to be in MC (methylene chloride) solvent, and in the presence of equimolar
olefin and pyridine catalyst at O°C, at which the yields of polymeric ozonide, 1,12-dodecanedialdehyde, 1,12-dodecanedicarboxylic
acid, and 12-oxo-dodecanoic acid were 10.25%, 26.72%, 26.31%, and 36.72%, respectively. 相似文献
955.
Online learning has grown exponentially in recent years; however, dropout problem remains challenging for some online programmes. The dropout problem can be attributed to a number of reasons, with a lack of interaction between learners and the instructor constituting one of the main reasons. The lack of interaction also leads to learners' feeling of isolation. Learning communities can provide learners with an environment conducive to increased interactions and alleviate their feeling of isolation. Unfortunately, there are no clear rules that instructors can follow to help learners create learning communities. In this paper, we propose guidelines for online instructors to facilitate the development of learning communities in online courses. We first review the definition of a learning community, importance of a learning community and factors affecting the development of a learning community. Afterwards, based on a review of the existing guidelines and other relevant literature, we propose guidelines for facilitating the development of learning communities in online courses. 相似文献
956.
Boo Young Shin Sang Hee Jang In Jae Chung Bong Shik Kim 《Polymer Engineering and Science》1992,32(1):73-79
Two thermotropic liquid crystalline polyesters (TLCPs) with long flexible spacer groups in the main chain were prepared by melt polymerization: one was a homopolymer with only decane groups (LCPHO) and the other was a copolymer with hexane or decane groups (LCPCO) between mesogen units. These polyesters were blended with a matrix polymer of poly(ethylene terephthalate) (PET). Scanning electron microscopy (SEM) revealed the excellent interfacial adhesion between polyester and PET, and the large aspect ratio of polyester microfibrils in the blend fiber made by extruding and drawing the blend through a die. The aspect ratio was estimated by using the modified Halpin-Tsai equation. The fiber with LCPHO showed more extensive fibril formation than that with LCPCO. 相似文献
957.
In order to solve the transformation problem of Bill of Materials (BOM) from engineering BOM to maintenance BOM for Maintenance, Repair and Overhaul (MRO) systems, a formal transformation model of BOM view is proposed. In this model, the intermediate component, inherited component, virtual component are defined in the specific maintenance management domain, and the transformation process from engineering BOM to maintenance BOM is discussed through feature recognition methods and rules. The proposed transformation model has been developed and deployed in an MRO system for a steel manufacturing enterprise. 相似文献
958.
959.
960.
A new method is presented for preparing highly monodispersed silica particles using a two-stage semibatch/batch hydrolysis reaction of Si(OC2 H5 )4 . The slower rate of hydrolysis of the tetraethylorthosilicate (TEOS) that occurred during the semibatch process resulted in larger silica particles with a higher yield and narrower size distribution. This was in direct contrast to the batch process. In addition, the ability of four different mixed processes to produce silica particles with good packing density, narrower particle-size distribution, and higher yield were evaluated. These were batch/batch (B-B), batch/semibatch (B-S), semibatch/batch (S-B), and semibatch/semibatch (S-S) processes. The S-S system produced the largest particles with the highest yields. The size of the silica particles obtained by the S-B method decreased with increasing reaction time, while the particles obtained by the B-S process had the best particle-size distribution and packing density. In conclusion, a mixed batch/semibatch system was the best way to produce an extremely narrow particle-size distribution and a good packing density. 相似文献