Robustness and coordination in voltage control of large-scale power systems

In this paper it is shown how the robustness and the coordination of the voltage regulation actions for the transmission grid can be improved. Simpler approaches which ensure higher robustness and performances can be used if the control objectives are pursued at two hierarchical levels of different nature. Also, this is a way to coordinate means of control of different nature with a sufficient time and methodological separation in order to avoid negative mutual influence. At the first level, called the static level, optimal reachable set-points are computed for the second control level, called the dynamic level. The static level can be combined with the shunt reactive power compensation. The system non-linearities are taken into account at the static level while the dynamic level is a linear robust predictive control which takes into account the presence of asynchronous transmission delays. The predictive control strategy is based on the separation property; the output delays are handled using an original steady-state Kalman predictor of order equal to the length of the state of the system without delays. The robustness is improved at the dynamic level against uncertain delays, parametric uncertainties (like, e.g., moderate topological errors and load variations not taken into account in the control model) and unmodelled dynamics. The two-level organisation of the control allows, on one hand, to take into account the important evolutions of the system (like, e.g., large and known topological and load changes) and, on the other hand, a coherent hybrid reactive power control: the switched control of the grid shunt compensation for the reactive power is done at the static level while the reactive power injection provided by the generators is continuously handled at the dynamic level. This is a theoretical analysis of how concepts of automatic control and voltage regulation of power systems can be combined. To be applied as a control scheme, the results presented here should be adapted to a specific context (particularities of the power system and of the organisation of the power industry). They can be used, eventually in conjunction with other improvements, to existing horizontally-organised interconnections (in which all generators of a controlled region can be easily managed since owned by the same utility) or to face specific requirements of moving to the open access in the electric power industry like, e.g., tolerating simplified models in order to cover larger regions, taking into account the interaction between regions, recalibrating set-points, assisting human operator when necessary or facilitating implementation of mechanisms for the management of the reactive power based on price signals.     

Specific interactions in ternary system quaternized polysulfone/mixed solvent

Theoretical and experimental aspects on the specific interactions developed via electrostatic interactions and hydrogen‐bonding in a ternary system formed of a proton‐donor solvent (N,N‐dimethylformamide or methanol), a proton‐acceptor solvent (water), and a quaternized polysulfone with various contents of ionic chlorine, which indicates a proton‐acceptor character, are investigated. Thus, the interactions of the ternary systems are corrected on the basis of the association phenomena defined through association constants. Numerical values for these constants were evaluated as a function of the system composition, by mathematical simulations for an accurate adjustment of preferential adsorption, determined by the Flory–Huggins–Pouchly theoretical approach applied to the experimental data. POLYM. ENG. SCI., 2009. © 2008 Society of Plastics Engineers     

MHD boundary-layer flow due to a moving extensible surface

The flow due to a moving extensible sheet that obeys a more general stretching law is considered. The sheet occupies the negative x-axis and is moving continually in the positive x-direction, in an incompressible viscous and electrically conducting fluid. The sheet somehow disappears in a sink that is located at (x, y) = (0, 0). The governing system of partial differential equations is first transformed into a system of ordinary differential equations, and the transformed equations are solved numerically using a finite-difference scheme, namely the Keller-box method. The features of the flow and heat-transfer characteristics for different values of the governing parameters are analyzed and discussed. It is found that dual solutions exist for the flow near x = 0, where the velocity profiles show a reversed flow.     

INFLUENCE OF MODEL UNCERTAINTY ON THE DYNAMIC OPTIMAL CONTROL PERFORMANCE OF A BATCH CORN DRYING PROCESS

A semi-empirical nonlinear model of moisture content and wet-milling quality degradation in com drying is established. The model uncertainty is expressed as a relative error level which includes a pre-specified percentage of experimental data. An optimal control strategy for batch drying is determined which maximizes the dryer throughput, while simultaneously satisfying two quality constraints on the final state: achieving specified moisture content and wet-milling quality levels. Taking into account the model uncertainty results in a conservative but less efficient control strategy. The performance - robustness compromise is discussed.     

Synthesis and characterization of some 2,4′-dibenzyldiisocyanate ionic polymers. V. Ionene polymers

Cationic polyurethanes containing piperazine rings on the macromolecular chain were synthesized by a Menschutkin reaction. A prepolymer with tertiary dimethylamino end groups and a dihalide were used in the first step, and N,N′-dimethylpiperazine in the second step. The viscometric behaviour of dilute solutions in solvents with high dielectrical constants was studied.     

Spectroscopic evidence for the bulk polymerization of N-vinyl carbazole in the presence of single-walled carbon nanotubes

The bulk polymerization reaction of N-vinylcarbazole (VK) at 70 °C in the presence of single-walled carbon nanotubes (SWNTs) leads to a new composite, whose optical properties were studied by photoluminescence (PL), surface enhanced Raman scattering (SERS) and Fourier transform infrared (FTIR) spectroscopies. A dramatic reduction of the poly(N-vinylcarbazole) (PVK) PL efficiency and a change in the vibrational structure of the PL spectrum of this polymer were observed by adding SWNTs to the synthesis mixture. Steric hindrance effects were evidenced both in SERS spectra of the VK when it interacts mechanico-chemically with SWNTs and in FTIR spectra of the un-doped PVK/SWNTs' composites. Cyclic voltammetry was used to demonstrate the doping process of PVK in PVK/SWNTs' composite.     

A Binary Gas Transport Model Improves the Prediction of Mass Transfer in Freeze Drying

Monitoring partial vapor pressure in the freeze-drying chamber is a cheap, global, and non-intrusive way to assess the end of the primary drying stage. Most existing dynamic freeze-drying models which predict this partial pressure describe mass transfer between the product and the condenser via a mass transfer resistance or a mass transfer coefficient. Experimental evidence suggests that such models can be significantly in error for some values of the sublimation flux, leading to physically inconsistent predictions and possibly incorrect assessment of primary drying termination, with potential risk of product damage if moving to secondary drying and increasing shelf temperature while some ice is still present. Assuming a binary gas transport model for vapor and inert gas leads to improved and consistent predictions and explains the apparent variation of the mass transfer resistance with total pressure, shelf temperature, and product sublimation area.