Plasma parameters of argon and argon/molecular gas mixture plasmas produced in microwave discharge

The experimental results and their analysis are presented concerning electron density and temperature of the microwave discharge plasma (power range 100–500 W) produced in Ar gas and Ar–N₂ and Ar–N₂–NO gas mixture at the total pressure of 0.5 Torr. The triple probe method was primarily used in order to set-up a direct and on-time technique to measure electron temperature in complex plasma. The results were compared with those obtained using a cylindrical probe mounted in a circuit with reference electrode. Each probe was made of tungsten wires of 0.5 mm diameter and 3 mm in length each. When plasma contains only one maxwellian group of electrons, within the experimental errors, both the probes systems get comparable value of plasma parameters. When the characteristic of cylindrical probe shows two groups of thermal electrons within the microwave plasma the triple probe may show always results concerning one group but of which temperature depends on the ratio of the densities of those two groups of electrons.     

Face Editing Using Part-Based Optimization of the Latent Space

We propose an approach for interactive 3D face editing based on deep generative models. Most of the current face modeling methods rely on linear methods and cannot express complex and non-linear deformations. In contrast to 3D morphable face models based on Principal Component Analysis (PCA), we introduce a novel architecture based on variational autoencoders. Our architecture has multiple encoders (one for each part of the face, such as the nose and mouth) which feed a single decoder. As a result, each sub-vector of the latent vector represents one part. We train our model with a novel loss function that further disentangles the space based on different parts of the face. The output of the network is a whole 3D face. Hence, unlike part-based PCA methods, our model learns to merge the parts intrinsically and does not require an additional merging process. To achieve interactive face modeling, we optimize for the latent variables given vertex positional constraints provided by a user. To avoid unwanted global changes elsewhere on the face, we only optimize the subset of the latent vector that corresponds to the part of the face being modified. Our editing optimization converges in less than a second. Our results show that the proposed approach supports a broader range of editing constraints and generates more realistic 3D faces.     

Sinanodonta woodiana (mollusca: bivalvia: unionidae): isolation and characterization of the first microsatellite markers

Sinanodonta woodiana (Lea, 1834) is a large Unionid species with a real invasion success. It colonized Europe, Central America, the Indonesian Islands and recently North America. The species life cycle involves a larval parasitic stage on freshwater fish species which contributes to the spread of the mussel. In this paper we describe, for the first time, eight polymorphic microsatellite loci for the species Sinanodonta woodiana. The genetic screening of individuals confirmed that all loci were highly polymorphic. The number of alleles per locus ranged from 7 to 14 and the observed heterozygosity ranged from 0.650 to 0.950. These loci should prove useful to study the species population genetics which could help to infer important aspects of the invasion process.     

Upper eyelid orbicularis oculi flap with tarsoconjunctival island for reconstruction of full-thickness lower lid defects

BACKGROUND: Various cryopreservation techniques have been investigated to elongate preservation time, however, most have failed to be clinically induced because of damage due to ice crystal formation. Subzero nonfreezing conditions could theoretically reduce organ metabolism without damage due to ice crystal formation. We evaluated the superiority of subzero nonfreezing storage compared with conventional hypothermic storage using isolated rat hepatocytes stored in University of Wisconsin (UW) solution without cryoprotectants. METHODS: Hepatocytes of Wistar rats isolated by collagenase digestion were suspended in UW solution and divided into the following three groups: subzero nonfreezing group (-4 degrees C), zero nonfreezing group (0 degrees C), and control group (4 degrees C). They were stored for 48 hr at the temperatures indicated. After 24 and 48 hr of storage, we carried out a trypan blue exclusion test and a 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazolium bromide (MTT) assay, and measured lactate dehydrogenase release, lactic acid, ATP content, and the ability of hepatocytes to synthesize urea. After 48 hr of storage, morphological differences between the control group and the subzero nonfreezing group were investigated by scanning and transmission electron microscopy. RESULTS: Significant improvements of the trypan blue exclusion test and ATP contents in the subzero nonfreezing group were observed. Lactic acid production was also significantly suppressed in the subzero nonfreezing group compared with that in the control group. The MTT assay value was significantly better at -4 degrees C than at 4 degrees C. The rate of urea synthesis at -4 degrees C was higher than that at 4 degrees C. Electron microscopy revealed that subzero nonfreezing delayed the lethal bleb-forming process of stored hepatocytes, which was followed by mitochondrial swelling, compared with the control group. CONCLUSIONS: Subzero nonfreezing storage (-4 degrees C) in UW solution could provide better preservability for isolated rat hepatocytes with protection against hypoxic cell injury compared with conventional hypothermic storage (4 degrees C).     

Lanthanum cobaltite nanoparticles using the polymeric precursor method

The present study reports the evolution of reactive lanthanum cobaltite nanoparticles obtained by a polymeric precursor route, using citric acid as chelating agent. The crystallization from amorphous precursor, particle growth and the formation of nanoparticle agglomerates at different calcination temperatures was carried out by conventional and high-resolution electron microscopy, electron diffraction and energy-dispersive X-ray analysis and Raman spectroscopy. Microstructure measurements were compared with X-ray diffraction and chemical analysis results. Electron diffraction, combined with TEM, was used to determine the proportion of amorphous phase. The presence of amorphous carbon during the decomposition of the amorphous precursor was analyzed by Raman spectroscopy. The coherent crystalline domain size and the particle size have been monitored by XRD and electron microscopy in order to determine the evolution of both crystal size and the temperature onset for the formation of polycrystalline aggregates.The results demonstrate that at 550 °C we obtain pure single-phase equiaxed nanopowders of LaCoO₃ with crystal size of 20 nm, free of amorphous carbon and without the presence of polycrystalline aggregates.     

The influence of neutron irradiation on (B0.65C0.35)Ba1.4Sr0.6Ca2Cu3Oz superconducting phase: The role of the grain edge

Using the transport and magnetization measurements, the influence of neutron irradiation at a fluence of 5 × 10¹⁷ n cm⁻² on (B_0.65C_0.35)Ba_1.4Sr_0.6Ca₂Cu₃O _z has been investigated. The neutron irradiation was found to decrease critical temperature and transport critical current density, increase the residual and normal state resistivity, and improve the intragranular critical current density with 1.6 × 10⁵ A/cm² (at 77.3 K and in the applied field up to 160 kA m) and ΔM _irr/ΔM _nonirr ratio (up to factor of 3) at highest field used for investigation. The field dependence of this ratio, which is below the unity at very low field but higher than 1 at high fields, correlated with the shape of the hysteretic loops as well as with the change of the transport parameters after irradiation suggests the role of the irradiation-induced effects on the grain edges. We discuss these effects in the framework of the Bean-Livingstone surface barriers and geometrical barriers.     

In vitro assessment and monitoring of the implant titanium materials – physiological environment interactions

Long‐term monitoring (for 8000 exposure hours) of titanium and its implant alloys (Ti‐5Al‐4V, Ti‐6Al‐4Fe) interactions with Ringer's solutions of different pH‐values (2.5, 4.35, 6.98), simulating various conditions that can appear at the contact between implant and tissues was carried out in this paper. All data were statistics treated using Medcalc program. In vitro electrochemical behaviour of titanium and its alloys reveals their self‐passivation in Ringer's solutions. Monitoring of the open circuit potentials with time and pH have shown that the passive films on the implant materials studied were very stable for all tested periods. Interactions due to the non‐uniformity of the physiological electrolyte pH can not produce any form of local corrosion. The tested materials present low corrosion rates which attest their very good stability for 8000 exposure hours in simulated biological environment. Surface topography characterisation using atomic force microscopy (AFM) data, correlated with the electrochemical parameters, were arguments for the stability of the samples in studied bioliquids.     

Variable Cross-Section Cylinder-Type Corona and Combined Corona–Dielectric Barrier Discharge Precipitators for Fly-Ash Particles

This article is aimed at evaluating three designs of cylindrical-type electrostatic precipitators that might be installed at the output of household boilers in order to reduce the pollution due to burning wood or fossil fuels. The first design is the “standard” precipitator, which consists in a thin copper wire (0.16 mm in diameter), coaxial with a cylindrical aluminum cylinder, 345 mm in length, of constant radius (20 mm). The second and third designs, equipped with a similar wire electrode, are characterized by the same global length, but are divided into three sections, two having the same cross-section as the “standard” precipitator, while the third section, 20 mm in length and located between them, has a smaller radius (11.5 mm). The reduction of the diameter in this central section of the precipitator is done by introducing an aluminum ring, covered by a sleeve made of either aluminum (design #2) or polyvinyl chloride (design #3). Together with the modification of the conditions for mechanical collection of particles, the more intense corona (design #2) or dielectric barrier discharges (design #3) generated in these sections of reduced diameter contribute to a significant increase of precipitation efficiency.     

Properties of anodic oxides grown on a hafnium–tantalum–titanium thin film library

A ternary thin film combinatorial materials library of the valve metal system Hf–Ta–Ti obtained by co-sputtering was studied. The microstructural and crystallographic analysis of the obtained compositions revealed a crystalline and textured surface, with the exception of compositions with Ta concentration above 48 at.% which are amorphous and show a flat surface. Electrochemical anodization of the composition spread thin films was used for analysing the growth of the mixed surface oxides. Oxide formation factors, obtained from the potentiodynamic anodization curves, as well as the dielectric constants and electrical resistances, obtained from electrochemical impedance spectroscopy, were mapped along two dimensions of the library using a scanning droplet cell microscope. The semiconducting properties of the anodic oxides were mapped using Mott–Schottky analysis. The degree of oxide mixing was analysed qualitatively using x-ray photoelectron spectroscopy depth profiling. A quantitative analysis of the surface oxides was performed and correlated to the as-deposited metal thin film compositions. In the concurrent transport of the three metal cations during oxide growth a clear speed order of Ti > Hf > Ta was proven.     

Mesoporous silica directly modified by incorporation or impregnation of some heteropolyacids: Synthesis and structural characterization

The synthesis of heteropolyacids-mesoporous silica composites was carried out in acidic media by impregnation and/or by direct incorporation of active phase. The effect of incorporation of heteropolyacids (HPAs) species into organized mesoporous silica was studied by using non-ionic and cationic surfactants. A comparison between direct incorporation of HPAs into mesoporous silica and impregnation of HPAs on mesoporous silica was done. The structure and texture of H₃PMo₁₂O₄₀ and H₄PVMo₁₁O₄₀ included on mesoporous silica were studied by XRD, SEM-EDS, FT-IR and Raman spectroscopies and BET and pore size distribution. Thermal stability was determined by thermo gravimetric analysis (TGA) and differential thermal analysis (DTA). FT-IR and Raman studies showed that HPAs anions preserved their Keggin structure after incorporation or impregnation on mesoporous silica support.