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11.
Hydroxy teminated polybutadiene (HTPB) was grafted onto the surface of nanosilica particles via toluene di‐isocyanate (TDI) bridging to reduce filler–filler interactions and improve dispersion of nanosilica in rubber. Also, this prepolymer as modifier contains double bonds which participate in sulfur curing of styrene butadiene rubber (SBR) matrix to enhance filler/polymer interaction and reinforcement effects of silica. The reactions were characterized by titration and Fourier transforms infrared spectroscopy. Thermogravimetric analysis was utilized to evaluate the weight percentage of grafted TDI and HTPB. About 60% of the hydroxyl sites of silica were reacted with excess TDI in the first reaction. In the second reaction, HTPB as desired reactive coating was grafted on the functionalized nanosilica to constitute about 24 wt % of the final modified silica. The sedimentation experiments showed good suspension stability for the modified nanosilica in the organic media. Scanning electron microscopy revealed nanoscale dispersion of modified silica aggregates in the SBR matrix at concentration of about 14 phr. Also, vulcanization characteristics and mechanical properties of compounds demonstrated that HTPB grafting improved dispersion of nanosilica as well as its interaction to the rubber matrix as an efficient reinforcement. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011  相似文献   
12.
ABSTRACT

Vertex colouring is among the most important problems in graph theory which has been widely applied across different real-world problems. In vertex colouring problem (VCP), the goal is to assign a distinct colour to each vertex of the graph in such a way that no two adjacent vertices have the same colour. This paper presents a fuzzy irregular cellular automaton (FICA) for finding a near-optimal solution for the VCP. FICA is an extension fuzzy cellular automaton (FCA) in which the cells of the automaton can be arranged in an irregular structure. The aim of the proposed method is to reap the benefits of both FCA and irregular cellular automata while minimising their drawbacks. To evaluate the proposed method, various computer simulations have been conducted on a variety of graphs. The results suggest that the proposed method is able to achieve better results in terms of the minimum number of required colours and the execution time of the algorithm, compared to other peer algorithms.  相似文献   
13.
The hybrid complex consist of molybdenylacetylacetonate complex covalently linked to a lacunary Keggin-type polyoxometalate, K8[SiW11O39] (POM), was synthesized and characterized by elemental analysis, SEM, XRD, diffuse reflectance UV–Vis and FT-IR spectroscopic methods. The hybrid complex, [MoO2(acac)–POM] (1), was used for alkene epoxidation with tert-BuOOH in 1,2-dichloroethane as solvent. The complex (1) can catalyze epoxidation of various olefins including non-activated terminal olefins. The effect of reaction parameters such as oxidant, solvent, and temperature on the epoxidation of cyclooctene was also investigated. This heterogeneous catalyst was reused several times in the oxidation of cyclooctene.  相似文献   
14.
The magnetic pulse welding (MPW) is a high speed solid state welding process which has been used successfully to provide metallurgical and electrical bonds between flexible printed circuit board (FPCB) with using: (1) welding with aluminum driver sheet and (2) without driver sheet. The optimum bank energy for reliable bonding was about 1 kJ with 160–180 kA maximum current. The maximum tensile shearing for most welded samples was nearly same as tensile shearing strength of copper layer of FPCB sheet.  相似文献   
15.
In the flooded lead_acid batteries (FLAB), gas bubbles are initially formed on the surface of the electrodes, which are produced by electrochemical reactions, and then released into the electrolyte. In the present investigation, the effect of surface characterization of electrodes of FLAB on the gas bubble dynamic parameters in the electrolyte flow at different charging/discharging rates (C-rates) are studied utilizing particle image velocimetry (PIV) method. The results show that the capacity of FLAB have a linear behav-ior due to changes in each of the two parameters of the surface characterization of electrodes and the C-rate. At all State of charges (SOCs) of FLAB cells in different tests, increasing average roughness (Ra) and average wavelength of the roughness (ka) in the electrode surfaces, results in an increase in average bub-ble diameter and bubble rising velocity. Nevertheless, a sharp decrease in the void fraction of bubbles within the electrolyte was observed due to the increment in ka and Ra. Also, the effect of the rising move-ment of gas bubbles within the electrolyte on the average electrolyte velocity pattern in the gap between the electrodes by changing the surface characterization of electrodes are investigated in detail.  相似文献   
16.
Silicon - In this paper, a new structure: triple work function metal gate SOI MESFET, intended for integration into the deep-submicron CMOS technology, is proposed. The gate of the device consists...  相似文献   
17.
 The effects of 2.2% Ni and 0.6% Mo additions on the kinetics, microstructure and mechanical properties of ductile aluminum cast iron were studied in the as-cast and tempered conditions. Test bars machined from cast to size samples, were used for mechanical and metallurgical studies. The results showed that the addition of Ni and Mo to the base iron produces an upper bainitic structure resulting in an increase in strength and hardness. The same trend was shown when the test bars tempered from 300oC in the range of 300 to 400oC. The elongation increased with increasing the temperature from 300 to 400oC. The carbon content of the retained austenite also increased with increasing temperature. The results also showed that the kinetics, microstructure and mechanical properties of this iron are similar to Ni-Mo alloyed silicon ductile iron.  相似文献   
18.
We develop a fuzzy multi-objective linear programming (FMOLP) model for solving multi-objective mixed-model assembly line problem. In practice, vagueness and imprecision of the goals in this problem make the fuzzy decision-making complicated. The proposed model considers minimizing total utility work, total production rate variation, and total setup cost, using a two-phase linear programming approach. In the first phase, the problem is solved using a max–min approach. The max–min solution not being efficient, in general, we propose a new model in the second phase to maximize a composite satisfaction degree at least as good as the degrees obtained by phase one. To show the effectiveness of the proposed approach, a numerical example is solved and the results are compared with the ones obtained by the fuzzy mixed integer goal programming and weighted additive methods. The computational results show that the proposed FMOLP model achieves lower objective functions as well as higher satisfaction degrees.  相似文献   
19.
This study was aimed at investigating the fortification of probiotic yoghurt with rice bran to increase nutritional properties of the product. The different levels of rice bran (0.3%, 0.6%, 0.9% and 1.2%) were incorporated into milk. The yoghurt samples were produced after pasteurisation, addition of starter culture and 1% Lactobacillus acidophilus suspension (6 × 108 CFU mL?1) and incubation. During sample storage in refrigerator, the viability of L. acidophilus, viscosity and physicochemical and sensory properties of product were investigated. Rice bran significantly increased the viability of L. acidophilus (< 0.05). In addition, all probiotic yoghurts incorporating rice bran indicated higher viscosity and acidity and lower pH and syneresis compared to plain yoghurts. Furthermore, increments in rice bran incorporation levels resulted in a reduction in consumers' sample preferences. In general, the addition of rice bran at a suitable level could increase L. acidophilus viability and improve quality attributes of yoghurt.  相似文献   
20.
River water management is challenging not only since they are open systems with changing physical structures, but also because the water values are mostly unknown over varied sectors. If policymakers grasp water values, water management will be more efficient. This research intends to examine the values of water in agriculture, which receives the most substantial portion of water resources, with the values of water in the environment in Isfahan located in the Zayandehrood River basin of Iran. The consequences of contingent valuation and production function methods revealed that per cubic metre value of water is 13 times higher in the environment than agriculture. The government should reconsider the higher value of the environment despite it is a non‐market value. The contingent valuation model additionally proved that women exhibited 21% more willingness to pay than men in order to protect the environment; however, they are paid less by 36%.  相似文献   
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