Insight into the microstructural characterization of ferritic steels using micromagnetic parameters

The influence of tempering-induced microstructural changes on the micromagnetic parameters such as magnetic Barkhausen emission (MBE), coercive force (H _c), residual induction (B _r), and maximum induction (B _max) has been studied in 0.2 pct carbon steel, 2.25Cr-1Mo steel, and 9Cr-1Mo steel. It is observed that, after short tempering, the micromagnetic parameters show more or less linear correlation with hardness, which is attributed to the reduction in dislocation density, but long-term tempering produces nonlinear behavior. The variation in each of these parameters with tempering time has been explained based on the changes in the size and distribution of ferrite laths/grains and precipitates. It has been shown that the individual variation in the microstructural features such as size and distribution of laths/grains and precipitates during tempering can be clearly identified by the MBE parameters, which is not possible from the hysteresis loop parameters (H _c and B _r). It is also shown that the MBE parameters can not only be used to identify different stages of tempering but also to quantify the average size of laths/grains and second-phase precipitates.     

Fabrication of three-dimensional nano, micro and micro/nano scaffolds of porous poly(lactic acid) by electrospinning and comparison of cell infiltration by Z-stacking/three-dimensional projection technique

The use of electrospun extracellular matrix (ECM)-mimicking nanofibrous scaffolds for tissue engineering is limited by poor cellular infiltration. The authors hypothesised that cell penetration could be enhanced in scaffolds by using a hierarchical structure where nano fibres are combined with micron-scale fibres while preserving the overall scaffold architecture. To assess this, we fabricated electrospun porous poly(lactic acid) (PLA) scaffolds having nanoscale, microscale and combined micro/nano architecture and evaluated the structural characteristics and biological response in detail. Although the bioactivity was intermediate to that for nanofibre and microfibre scaffold, a unique result of this study was that the micro/nano combined fibrous scaffold showed improved cell infiltration and distribution than the nanofibrous scaffold. Although the cells were found to be lining the scaffold periphery in the case of nanofibrous scaffold, micro/nano scaffolds had cells dispersed throughout the scaffold. Further, as expected, the addition of nanoparticles of hydroxyapatite (nHAp) improved the bioactivity, although it did not play a significant role in cell penetration. Thus, this strategy of creating a three-dimensional (3D) micro/nano architecture that would increase the porosity of the fibrous scaffold and thereby improving the cell penetration, can be utilised for the generation of functional tissue engineered constructs in vitro.     

Ecological health assessment of the Ousteri wetland in India through synthesizing remote sensing and inventory data

Ousteri Lake is one of the important wetlands in India, harbouring many different types of flora and providing a suitable habitat for many different fauna, being declared as a sanctuary in October 2008. The National Wetland Conservation Program of Ministry of Environment and Forests identified Ousteri Lake as a nationally important wetland, and the Bombay Natural History Society (BNHS) named it an Important Bird Area (IBA). The International Union for Conservation of Nature and Natural Resources (IUCN) also has identified this lake as a heritage site. The present study examined the state of environment in and around the Ousteri wetland, assessing the probable threats to the lake and its ecological environs. Ousteri Lake supports diverse rich and rare flora and fauna. Because of its extreme hydrological fluctuations over the annual cycle, the lake exhibits interesting patterns of flora and fauna. The north‐east monsoons leave the lake flooded during the winter months, while the scorching summers leave it totally dry. Ousteri Lake had been primarily used as a tank for irrigation purposes, with ~2,000 acres being cultivated. The main crop is paddy, and the only subsidiary is sugar cane. The natural vegetation, significantly altered by human activities, consists of over 220 species belonging to 63 families. The vegetation study conducted earlier have reported a total of 472 plant species, with the herbs being 40% of this total, followed by trees (21%). Other life forms in the lake are represented by less than 100 species. Ousteri Lake and its environs also provide a wide variety of habitat for many floral species, with 190 species being listed as least concern, 23 species as near threatened and 24 species as vulnerable, according to the IUCN Red List. About 14 floral species are being categorized as endemic. Further, about 202 fauna are listed as least concern, 13 species as near threatened, two species as vulnerable, three species as endangered and one as critically endangered. Moreover, five species are in an endemic category.     

Performance of Choline-Based Deep Eutectic Solvents in the Extraction of Tocols from Crude Palm Oil

Deep eutectic solvents are emerging green solvents that have potential in many separation processes. This study investigates the performance of choline‐based deep eutectic solvents in the extraction of tocopherols and tocotrienols (collectively known as tocols) from palm oil, a major natural source of tocols. Deep eutectic solvents comprised of choline chloride salt and selected carboxylic acids as hydrogen bond donors were prepared and used in the extraction of tocols from crude palm oil by liquid–liquid extraction. Tocols concentration in the extracted product was at least double that in the control (8671 mg/kg compared to 3285 mg/kg, respectively). Increasing the amount of the deep eutectic solvents increased the tocols concentration in the extracted product up to 18,525 mg/kg, but the yields lowered from 4 % to less than 1 %. The tocols profile was significantly improved by the increase of the tocotrienols fraction in the products from 80.8 to 99.8 %. This study showed that unique interaction between the selected deep eutectic solvents with the tocols make it possible to selectively separate individual tocols in palm oil, where products with fractions rich in tocotrienols and low in tocopherols (particularly α‐tocopherol) are favorable.     

Phenol Removal from Aqueous Solutions by Tamarind Nutshell Activated Carbon: Batch and Column Studies

Activated carbons prepared from tamarind nutshell, an agricultural waste by‐product, have been examined for the removal of phenol from aqueous solutions. The activated carbon was prepared by sulfuric acid activation. Both batch and column studies were performed for the sorption of phenol. The kinetic data were fitted to the models of Lagergren, pseudo‐second‐order and intraparticle diffusion, and closely followed the pseudo‐second‐order chemisorption model. The Freundlich and Langmuir isotherm models were well fitted. The solution pH greatly affects the sorption process. The column study results indicate that the sorption of phenol is dependent on the flow rate, the inlet phenol concentration as well as on the particle size of the adsorbent.     

Influence of the macrotidal environment on the source to sink pathways of suspended flux in the Gulf of Kachchh,India: evidence from the Ocean Colour Monitor (IRS‐P4)

A series of tide‐synchronous satellite images, obtained from the Ocean Colour Monitor (OCM) onboard the Indian Remote Sensing Satellite (IRS‐P4), in situ measurements and hydrodynamic model simulations were used to describe dispersal pathways and sources of total suspended matter (TSM) in the Gulf of Kachchh, a macrotidal system with insignificant freshwater inputs. Strong alongshore currents are prevalent at the mouth that move in (out) clockwise during flood (ebb) and undergo cyclic, dynamic changes with the tidal phases. The Gulf, unlike other regions of the Indian coastline, has dynamic turbidity that is zonal (very high in the outer Gulf and in the creeks of the Gulf), particularly during flooding, and reduced in the central region throughout the entire tidal cycle. From this dynamic turbidity with regard to the prevalent currents, it is deduced that inland amplifying flood currents draw in TSM‐rich offshore waters into the Gulf, and are the major source of turbidity in the outer regions of the Gulf. In the inner Gulf, because of these high‐magnitude currents, scouring of the creek bed leads to resuspension to create higher turbidity. Most of the scoured flux sinks off the mouths of these creeks because of the fanning out of ebbing flows from the narrow creeks into the wider Gulf. The areas under specific influence of different sources of turbidity are delineated schematically.     

Failure analysis of an ammonia refrigerant condenser tube

A detailed failure analysis was conducted on an ammonia refrigerant condenser tube component that failed catastrophically during its initial hours of operation. Evidence collected clearly demonstrated that the weld between a pipe and a dished end contained a sharp unfused region at its root (lack of penetration). Component failure had started from this weld defect. The hydrogen absorbed during welding facilitated crack initiation from this weld defect during storage of the component after welding. Poor weld toughness at the low operating temperature facilitated crack growth during startup, culminating in catastrophic failure as soon as the crack exceeded critical length.     

Inhibitory effects of fruit extracts on nitric oxide-induced proliferation in MCF-7 cells

Nitric oxide is a free radical involved in the pathogenesis of cancer by increasing tumour vascularization and metastasis. Studies using nitric oxide inhibitors have shown decrease in tumour growth and a role in cancer therapy. To analyse the effect of fruits on nitric oxide, we carried out experiments using a nitric oxide donor on the breast cancer cell line, MCF-7. Proliferating MCF-7 cells were treated with the methanolic extract of the fruits. The inhibitory activity of fruit extracts on cell proliferation was measured using the MTT assay. Chiku and dragon fruit showed high inhibitory activity when compared to the other fruits tested. The total polyphenol and flavonoid content and nitric oxide scavenging activity were found to be high in pomegranate, chiku, litchi, durian, grape and apple. This study shows that phytochemicals present in fruits scavenge nitric oxide and inhibit MCF-7 cell proliferation.     

A decomposable parameter space for the detection of ellipses

Hough transform is a well-known method for detecting parametric curves in binary images. One major drawback of the method is that the transform requires time and memory space exponential in the number of parameters of the curves. An effective approach to reduce both the time and space requirement is the parameter space decomposition. In this paper, we present two methods for the detection of ellipses based on the straight line Hough transform (SLHT).

The SLHT of a curve in the θ-π space can be expressed as the sum of two terms, namely, the translation term, and the intrinsic term. One useful property of this representation is that it allows the translation, rotation and intrinsic parametersof the curve be separated easily. Timing performance of the proposed methods compares favorably with the other Hough-based methods.