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51.
52.
Ji‐Sun Im Ju‐Hyung Lee Seung‐Kook An Ki‐Won Song Nam‐Ju Jo Jang‐Oo Lee Kohji Yoshinaga 《应用聚合物科学杂志》2006,100(3):2053-2061
A new type of polyimide/silica (PI/SiO2) hybrid composite films was prepared by blending polymer‐modified colloidal silica with the semiflexible polyimide. Polyimide was solution‐imidized at higher temperature than the glass transition temperature (Tg) using 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA) and 4,4′‐diaminodiphenyl ether (ODA). The morphological observation on the prepared hybrid films by scanning electron microscopy (SEM) pointed to the existence of miscible organic–inorganic phase, which resulted in improved mechanical properties compared with pure PI. The incorporation of the silica structures in the PI matrix also increased both Tg and thermal stability of the resulting films. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2053–2061, 2006 相似文献
53.
Yongwon Seo Sung-Ho Jo Ho-Jung Ryu Hee Dal Bae Chong Kul Ryu Chang-Keun Yi 《Korean Journal of Chemical Engineering》2007,24(3):457-460
A bubbling fluidized bed reactor was used to study CO2 capture from flue gas by using a potassium-based solid sorbent, sorbKX35 which was manufactured by the Korea Electric Power
Research Institute. A dry sorbent, sorbKX35, consists of K2CO3 for absorption and supporters for mechanical strength. To increase initial CO2 removal, some amount of H2O was absorbed in the sorbent before injecting simulated flue gas. It was possible to achieve 100% CO2 removal for more than 10 minutes at 60°C and a residence time of 2 s with H2O pretreatment. When H2O pretreatment time was long enough to convert K2CO3 of sorbKX35 into K2CO3 · 1.5H2O, CO2 removal was excellent. The results obtained in this study can be used as basic data for designing and operating a large scale
CO2 capture process with two fluidized bed reactors.
This work was presented at the 6
th
Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
54.
55.
Choonghee Jo 《Polymer》2007,48(11):3349-3360
A constitutive model for tensile behavior of high density polyethylene (HDPE)/clay nanocomposite foams was proposed. The elastic modulus of HDPE/clay nanocomposite was developed using micromechanics theory, and the modulus for foams was obtained by using representative volume element (RVE) concept. In order to describe the tensile behavior of the foams, a constitutive equation obtained from a viscoelastic model was proposed. The constitutive model was expressed in terms of microstructural properties of polymer, and physical properties of the foams. The effects of the material parameters and processing conditions on the foam morphologies and mechanical properties of HDPE/clay nanocomposite foams were investigated. Microcellular closed-cell nanocomposite foams were manufactured with HDPE, where the nanoclay loadings of 0.5, 1.0, and 2.0 wt% were used. The effect of clay loading and foaming conditions on the volume expansion ratio, elastic modulus, tensile strength, and elongation at break was investigated. Except for the elongation at break, the mechanical properties were improved with nanoclay loading. The tensile experimental data of the foams were compared with the prediction by the theoretical model. It was demonstrated that the tensile behaviors of HDPE/clay nanocomposite foams were well described by the constitutive model. 相似文献
56.
The different melting temperatures of N‐methyl morpholine N‐oxide (NMMO) hydrates in the cellulose–NMMO hydrate solution may be explained by the rather different crystal structures of NMMO hydrates, which are determined by the amount of the hydrates. The preparative process of cellulose–NMMO hydrate solution may result in cellulose structural change from cellulose I to cellulose II, depending on the amount of the hydrate. Mixtures of cellulose and NMMO hydrate in a blender was changed from the granules to slurry with increasing mixing time at 60–70°C, which is below the melting point of the NMMO hydrate. In the case of 15 wt % cellulose–NMMO hydrate granules, which were made by mixing for 20 min, the melting points of various NMMO hydrates were obtained as 77.8°C (n = 0.83), 70.2°C (n = 0.97), and 69.7°C (n = 1.23), respectively, depending on the hydrate number. However, the melting points of cellulose–NMMO hydrate slurry and solution were shifted lower than those of cellulose granules, while the mixing time of slurry and solution are 25 and 35 min, respectively. These melting behaviors indicate instantaneous liquefaction of the NMMO hydrate and the diffusion of the NMMO hydrate into cellulose during mixing in a blender. When cellulose was completely dissolved in NMMO hydrate, the crystal structure of cellulose showed only cellulose II structure. In the cellulose–NMMO products of granules or slurry obtained by high‐speed mixing, which is a new preparation method, they still retained the original cellulose I structure. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1687–1697, 2004 相似文献
57.
58.
Christine Baatz Nadine Thielecke Ulf Prüße 《Applied catalysis. B, Environmental》2007,70(1-4):653-660
In this work, two deposition–precipitation methods for the preparation of gold catalysts for glucose oxidation were investigated. Thus far, gold colloids immobilized on carbon have been used for catalytic glucose oxidation, but the long-term stability of these systems was not sufficient. To improve the long-term stability we used the deposition–precipitation methods using NaOH (DP NaOH) or urea (DP urea) as precipitation agents as they were described by Haruta and Dekkers, respectively, using alumina as a support material. With these methods, it was possible to prepare highly active and selective catalysts which showed an excellent long-term stability. DP urea was found to be the preferred method, because in contrast to DP NaOH, no losses of gold occurred during the preparation, and it was possible to adjust various gold contents up to 10 wt% Au. 相似文献
59.
Male and female weanling rats that were born to dams fed a diet low in linolenic acid received diets of 15% lipids by weight
containing 45% elaidic acid (as trielaidin) and 8.5% or 0.1% linolenic acid for 10 weeks. Four other groups, in which palmitic
or oleic acid replaced elaidic acid in the diet, served as controls. The fatty acid profiles of several lipid classes were
determined in adipose tissue, adrenals, testes, heart and brain. Elaidic acid was incorporated into tissue lipids in varying
degrees, depending on the organ and on the lipid class. Feeding elaidic acid induced no changes in the polyunsaturated fatty
acid (PUFA) profiles of testes lipids but resulted in definite modifications of the PUFA patterns of heart phosphatidylcholine
(PC) and phosphatidylethanolamine (PE). In linolenic acid-deprived rats, arachidonic acid was decreased in PC and linoleic
acid was increased in both PC and PE; 22∶5n−6 was strongly depressed in both PC and PE. In linolenic acid-fed rats, 22∶6n−3
was decreased in PC and PE. These changes, on the whole, were more evident in females, and some also were observed in adrenal
cholesteryl esters but only slightly in brain phospholipids. the apparent inhibition of the biosynthesis of PUFA induced by
dietary elaidic acid appeared to be complex and of greater intensity in the n−6 fatty acid series than in their n−3 homologues. 相似文献
60.
The pulsed arc discharge to the surface of wastewater was applied to the degradation of a textile azo dye (Acid Red 27). A
high-voltage electrode (discharging electrode) was vertically placed above the surface of the wastewater while the wastewater
itself was grounded. The pulsed arc discharge occurred between the tip of the discharging electrode and the surface of the
wastewater, producing various oxidative species. Oxygen was used as the working gas instead of air to prevent nitrogen oxides
from forming. The effect of several parameters on the chromaticity and chemical oxygen demand (COD) removal was examined.
The results obtained showed that the chromaticity of the wastewater was completely removed by this process and the COD also
decreased significantly. It has been found that ozone formed in the gas phase mainly affects the removal of the dye. The contribution
of other effects such as ultraviolet light emission and OH radical formation during the arc discharge to the degradation of
the dye was found to be less than 15%. For the present reactor system, the optimum pH, pulse repetition rate and agitation
speed were found to be 3.0, 110 Hz and 300 rpm, respectively. 相似文献