Multichannel AR parameter estimation from noisy observations as an errors-in-variables issue

In various applications from radar processing to mobile communication systems based on CDMA or OFDM, M-AR multichannel processes are often considered and may be combined with Kalman filtering. However, the estimations of the M-AR parameter matrices and the autocorrelation matrices of the additive noise and the driving process from noisy observations are key problems to be addressed. In this paper, we suggest solving them as an errors-in-variables issue. In that case, the noisy-observation autocorrelation matrix compensated by a specific diagonal block matrix and whose kernel is defined by the M-AR parameter matrices must be positive semi-definite. Hence, the parameter estimation consists in searching every diagonal block matrix that satisfies this property, in reiterating this search for a higher model order and then in extracting the solution that belongs to both sets. A comparative study is then carried out with existing methods including those based on the Extended Kalman Filter (EKF) and the Sigma-Point Kalman Filters (SPKF). It illustrates the relevance and advantages of the proposed approaches.     

Fast three-dimensional temperature reconstruction

The work presented here deals with the reconstruction of the thermal field inside a three-dimensional structure when only some pointwise temperature measurements along a time interval [0, T] are available. The model-based reconstruction procedure builds upon optimal control theory applied to the determination of the unknown boundary conditions. The proposed dual approach enables one to reduce the on-line computational cost so that the resulting algorithm can be part of a real-time process. The complexity of the resulting algorithm does not depend on geometry. The paper details a novel methodology that enables to implement the reconstruction procedure using standard finite element tools, despite the difficulty to define the pointwise values of a three-dimensional field in the usual functional spaces where finite element methods converge.     

The Reactivity of Difluorocarbene with Hydroxylamines: Synthesis of Carbamoyl Fluorides

Carbamoyl fluorides are formed in reactions of hydroxylamines with difluorocarbene generated from sodium bromodifluoroacetate as readily available and non‐toxic carbene precursor. The process shows a high functional group tolerance, and the reaction path has been rationalized by computational calculations.

     

Structural and rheological investigation of interphase in polyethylene/polyamide/nanoclay ternary blends

This study aims at investigating and characterizing the interphase in Polyethylene (PE)/Polyamide (PA) blends with nodular morphology, filled with organically modified Montmorillonite (C30B), using structural and rheological experimental techniques. PE/PA/C30B blends have been prepared by simultaneous mixing at a dispersed phase fraction (PE or PA) of 20% and a clay fraction ranging from 1 to 6%. Structural properties of the interphase have been investigated using XRD combined with TEM micrographs. The presence of numerous interphase defects is evidenced, and the effect of interphase disorder is discussed. Linear viscoelastic properties show the contribution of the interphase in PE matrix ternary blends at all clay fractions, whereas interphase effects are masked by the contribution of dispersed nanoclay particles in PA matrix ternary blends.     

Case Study: Retrofitting Large Bridge Piers on the Nakdong River, South Korea

The Gupo Bridge crosses the Nakdong River near the city of Busan, South Korea. During Typhoon Maemi in 2003, the old Gupo Bridge collapsed due to excessive pier scour. More recently, the highway construction on the left-bank floodplain required right-bank channel widening to restore the channel flood-carrying capacity. This 7?m deep floodplain excavation is expected to cause significant local scour around the 8–10?m wide and 3?m thick spread footings of Piers 11 and 12 of the Subway Bridge and Piers 15 and 16 of the Gupo Bridge. Three design options are examined for retrofitting floodplain bridge piers with massive spread footings. A solution with sheet piles and riprap was recommended in 2006 as the most appropriate design, but Plan III with a conical riprap structure around the footings was ultimately constructed in 2007 for economic reasons. Laboratory experiments also highlight the need to place gravel and synthetic filters under the designed riprap.     

Real-space tight-binding approach to electronic structure and stability in substitutional alloys

A real-space approach based on the tight-binding approximation is proposed for studying electronic structure properties, stability and order in substitutional multi-component chemically random alloy based on periodic as well as topological disordered lattices. We show that the coherent potential approximation (CPA) equations including Shiba's off-diagonal disorder can be solved self-consistently in real-space with the same accuracy currently achieved in reciprocal space. An effective one-electron Green function is given by a continued fraction expansion, and the associated effective medium is used to determine the effective cluster interactions which enter the expression of the configurationl part of the total energy for describing order-disorder phenomena in alloys. Some applications will be presented.     

Doubly rotated quartz resonators with a low amplitude-frequencyeffect: the LD-cut

This article deals with a crystal quartz cut with virtually no amplitude-frequency effect (also called "isochronism defect" or "anisochronism"). The cut, called LD-cut (Low isochronism Defect), is set in a BVA-type structure for later use in an Ultra-Stable Oscillator (USO). Various design parameters are presented, along with the properties of the resonator. The resonance frequencies of various modes, the temperature dependence, the motional parameters and the phase noise in relation to the power supplied to the resonator are mainly studied. These properties are compared to those of the SC-cut resonators     

Modelling and estimating the reliability of stochastic dynamical systems with Markovian switching

In this paper, a general framework for the modelling of physical phenomena with stochastic dynamical systems switched by jump Markov processes is given. A methodology of the associated estimation procedures is provided. A particular attention is paid to the estimation of the underlying jump process, which is not observable.As an application, a stochastic model is proposed for the fatigue crack growth problem. The estimation of the model parameters is made on a real crack growth data set. We are thus able to simulate some crack growth paths which are used for reliability analysis through Monte Carlo techniques.