Photocurable propyl-cinnamate-functionalized polyhedral oligomeric silsesquioxane as a gate dielectric for organic thin film transistors

A polyhedral oligomeric silsesquioxane (POSS)-based insulating material with photocurable propyl-cinnamate groups (POSS-CYNNAM) was designed and synthesized through simple single step reaction for use as a gate dielectric in organic thin-film transistors (OTFT). POSS-CYNNAM was soluble in common organic solvents and formed a smooth thin film after spin-casting. A thin film of POSS-CYNNAM was cross-linked and completely solidified under UV irradiation without the use of additives such as photoacid generators or photoradical initiators. ITO/insulator/Au devices were fabricated and characterized to measure the dielectric properties of POSS-CYNNAM thin films, such as leakage current and capacitance. A pentacene-based OTFT using the synthesized insulator as the gate dielectric layer was fabricated on the transparent indium tin oxide (ITO) electrode, and its performance was compared to OTFTs using thermally cross-linked poly(vinyl phenol) (PVP) as the insulator. The fabricated POSS-CYNNAM OTFT showed a comparable performance to devices based on the PVP insulator with 0.1 cm²/Vs of the field effect mobility and 4.2 × 10⁵ of an on/off ratio.     

Design and practical implementation of multifrequency RF front ends using direct RF sampling

The use of direct RF sampling has been explored as a means of designing multifrequency RF front ends. Such front ends will be useful to multifrequency RF applications such as global navigation satellite system receivers that use global positioning system (GPS) L1, L2, and L5 signals and Galileo signals. The design of a practical multifrequency direct RF sampling front end is dependent on having an analog-to-digital converter whose input bandwidth accommodates the highest carrier frequency and whose maximum sampling frequency is more than twice the cumulative bandwidth about the multiple carrier signals. The principle of direct RF sampling is used to alias all frequency bands of interest onto portions of the Nyquist bandwidth that do not overlap. This paper presents a new algorithm that finds the minimum sampling frequency that avoids overlap. This design approach requires a multifrequency bandpass filter for the frequency bands of interest. A prototype front end has been designed, built, and tested. It receives a GPS coarse/acquisition code at the L1 frequency and GPS antispoofing precision code at both L1 and L2. Dual-frequency signals with received carrier-to-noise ratios in excess of 52 dB-Hz have been acquired and tracked using this system.     

Carrier Lifetime Measurements in Long-Wave Infrared InAs/GaSb Superlattices Under Low Excitation Conditions

Minority carrier lifetime in long-wave infrared (LWIR) type?II InAs/GaSb superlattices was studied using the optical modulation response (OMR) technique in wide ranges of excitation and temperature. The measured carrier lifetime was found to increase superexponentially with decreasing excitation power density below the level of 1?mW/cm² to 2?mW/cm². The phenomenon was qualitatively explained by the presence of shallow trapping centers.     

Functionality of Dual‐Phase Lithium Storage in a Porous Carbon Host for Lithium‐Metal Anode

Lithium (Li) metal is regarded as the most attractive anode material for high‐energy Li batteries, but it faces unavoidable challenges—uncontrollable dendritic growth of Li and severe volume changes during Li plating and stripping. Herein, a porous carbon framework (PCF) derived from a metal–organic framework (MOF) is proposed as a dual‐phase Li storage material that enables efficient and reversible Li storage via lithiation and metallization processes. Li is electrochemically stored in the PCF upon charging to 0 V versus Li/Li⁺ (lithiation), making the PCF surface more lithiophilic, and then the formation of metallic Li phase can be induced spontaneously in the internal nanopores during further charging below 0 V versus Li/Li⁺ (metallization). Based on thermodynamic calculations and experimental studies, it is shown that atomically dispersed zinc plays an important role in facilitating Li plating and that the reversibility of Li storage is significantly improved by controlled nanostructural engineering of 3D porous nanoarchitectures to promote the uniform formation of Li. Moreover, the MOF‐derived PCF does not suffer from macroscopic volume changes during cycling. This work demonstrates that the nanostructural engineering of porous carbon structures combined with lithiophilic element coordination would be an effective approach for realizing high‐capacity, reversible Li‐metal anodes.     

Analysis and enhancement of multi‐channel MAC protocol for ad hoc networks

In this paper, an analytical model is proposed to calculate the network throughput of dedicated control channel protocols that are designed to schedule multiple packets to be transmitted on different data channels simultaneously. Based on the analytical model, a scheme by tuning the initial contention window size is proposed to maximize the network throughput. We also present a novel multi‐channel MAC protocol for single‐hop scenario. Simulation results show that the proposed model is capable of modeling the behaviors of dedicated control channel protocols accurately. Furthermore, the proposed scheme can reduce the cost of collisions and enhance the network throughput up to 22% for 1 kB packet size and 80 nodes. Compared with other dedicated control channel protocols, the proposed protocol can schedule more control packets and use multiple channels more efficiently. Copyright © 2010 John Wiley & Sons, Ltd.     

A hidden mutual authentication protocol for low‐cost RFID tags

Radio‐frequency identification (RFID) technology enables the identification and tracking of objects by means of the wireless signals emitted by a tag attached to the objects of interest. Without adequate protection, however, malicious attackers can easily eavesdrop, scan or forge the information within the tag, thereby threatening the integrity of the system. Previous research has shown that the basic security requirements of RFID systems, i.e. identity authentication, information privacy and location privacy, can be satisfied using conventional cryptographic components. However, such components are expensive, and therefore conflict with the general requirement for low‐cost tag designs. Accordingly, this paper presents a low‐cost challenge‐response security protocol designated as the hidden mutual authentication protocol (HMAP) to accomplish both a mutual authentication capability between the tag and the reader and information privacy. The results show that HMAP provides an efficient means of concealing the authentication messages exchanged between the tag and the reader and is robust toward replay attacks. In addition, it is shown that HMAP is easily extended to provide complete location privacy by utilizing a hash function to generate different tag identifiers in each authentication session. Copyright © 2011 John Wiley & Sons, Ltd.     

Efficient non-coherent demodulation scheme for IEEE 802.15.4 LR-WPAN systems

An efficient non-coherent demodulation algorithm to compensate for the frequency offset effectively is proposed for IEEE 802.15.4 LR-WPAN systems working in the 868/915 MHz band. In the proposed algorithm, the decision criterion is changed depending on the frequency offset estimated in the preamble, and the received signal is differentially demodulated by using the phase difference between two consecutive bits. Simulation results show that the proposed method achieves better performance compared to conventional non-coherent algorithms, without increasing hardware costs significantly.     

Chiral Stereoisomer Engineering of Electron Transporting Materials for Efficient and Stable Perovskite Solar Cells

A series of chiral stereoisomers of electron transporting materials with two chiral substituents is rationally designed and synthesized, and the influence of stereoisomerism on their physical and electronic properties is investigated to demonstrate highly efficient and stable perovskite solar cells (PSCs). Compared to mesomeric naphthalene diimide (NDI) derivatives, which have heterochiral side groups with centrosymmetric molecular packing of symmetric‐shaped conformers in the crystalline state, enantiomeric NDI derivatives have homochiral side groups that exhibit non‐centrosymmetric molecular packing of asymmetric‐shaped conformers in the crystalline state and exhibit better solution processability based on one order of magnitude higher solubility. A similar trend is observed in different rylene diimide stereoisomers based on larger semiconducting core perylene diimide. The PSCs based on NDI enantiomers with good film‐forming ability and a very high lowest phase transition temperature (T_lowest) of 321 °C exhibit a high and uniform average power conversion efficiency (PCE) of 19.067 ± 0.654%. These PSCs also have a high temporal device stability, with less than 10% degradation of the PCE at 100 °C for 1000 h without encapsulation. Therefore, chiral stereoisomer engineering of charge transporting materials is a potential approach to achieve high solution processability, excellent performance, and significant temporal stability in organic electronic devices.