利用STAR-CD软件分析2气门直喷式柴油机的螺旋气道

简单叙述2气门直喷式柴油机发展现状，针对2气门直喷式柴油机的螺旋进气道的流场以及压力场等运用STAR-CD软件进行模拟并分析。     

进气道型式对四气门汽油机低速低负荷燃烧压力循环变动的影响

在发动机试验台上,利用CB-466燃烧分析仪研究了整体式和分体式进气道对四气门汽油机燃烧压力循环变动的影响.结果表明,分体式进气道与整体式相比平均指示压力和最高燃烧压力循环变动率较低,仅为整体式进气道的73.3%和87.6%.二者随转矩的增加逐渐减小,整体式进气道中等转矩时的平均指示压力和最高燃烧压力循环变动率大约仅为小转矩时的50.1%和67.1%,而分体式进气道时,则为小转矩时的76.2%和73.8%.整体式进气道平均指示压力和最高燃烧压力循环变动率随转速的增加逐渐增加;分体式进气道平均指示压力循环变动率随转速的增加逐渐增加,而最高燃烧压力循环变动率先随转速增加,当达到中等转速后又逐渐减小.     

Physical and electrochemical properties of spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathode materials

A (Ni_1/3Co_1/3Mn_1/3)CO₃ precursor with an uniform, spherical morphology was prepared by coprecipitation using a continuously stirred tank reactor method. The as-prepared spherical (Ni_1/3Co_1/3Mn_1/3)CO₃ precursor served to produce dense, spherical Li_1+x(Ni_1/3Co_1/3Mn_1/3)_1−xO₂ (0 ≤ x ≤ 0.15) cathode materials. These Li-rich cathodes were also prepared by a second synthesis route that involved the use of an M₃O₄ (M = Ni_1/3Co_1/3Mn_1/3) spinel compound, itself obtained from the carbonate (Ni_1/3Co_1/3Mn_1/3)CO₃ precursor. In both cases, the final Li_1+x(Ni_1/3Co_1/3Mn_1/3)_1−xO₂ products were highly uniform, having a narrow particle size distribution (10-μm average particle size) as a result of the homogeneity and spherical morphology of the starting mixed-metal carbonate precursor. The rate capability of the Li_1+x(Ni_1/3Co_1/3Mn_1/3)_1−xO₂ electrode materials, which was significantly improved with increased lithium content, was found to be better in the case of the denser materials made from the spinel precursor compound. This result suggests that spherical morphology, high density, and increased lithium content were key factors in enabling the high rate capabilities, and hence the power performances, of the Li-rich Li_1+x(Ni_1/3Co_1/3Mn_1/3)_1−xO₂ cathodes.     

锅壳式锅炉"8"字型回燃室壳板强度稳定计算

对锅壳式锅炉回燃室的结构式进行了分析,并通过分析详述了强度稳定计算的过程,得出强度合格的结论。     

偏航制动器摩擦片工作寿命预估方法探讨

针对风电机组中偏航系统采用的盘式制动器的维护问题,本文通过介绍制动器摩擦片工作寿命的理论计算方法与磨损试验预估方法,并结合制动器磨损试验数据,对两者两种方法进行对比,总结出更贴近风电机组偏航工况的计算方法,从而为偏航制动器的现场维护工作提供参考,有效避免偏航刹车盘损伤事故的发生。     

Development and characterization of covalently cross-linked SPEEK/Cs-TPA/CeO2 composite membrane and membrane electrode assembly for water electrolysis

Covalently cross-linked SPEEK/Cs-TPA/CeO₂ composite membrane was prepared for the polymer electrolyte membrane water electrolysis. Tungstophosphoric acid (TPA) with a cesium was added to the SPEEK to increase proton conductivity. CeO₂ was used to scavenge free radicals which attack the membrane in the water electrolysis and to improve the durability of the membrane. The composite membrane featured the electrochemical characteristics, such as 0.130 S/cm of proton conductivity at 80 °C, and 2.324 meq./g-dry-memb. of ion-exchange capacity. Pt(NH₃)₄Cl₂, Pd(NH₃)₄Cl₂, RhCl₃ and Co(NH₆)₄Cl₃ were used to prepare a variety of the membrane electrode assemblies (MEAs) as electrocatalytic precursors. Electrochemical activity surface area (ESA) of the Pt–Pd electrode prepared with 2 mM Pt(NH₃)₄Cl₂ and 2 mM Pd(NH₃)₄Cl₂ showed the best properties of 26.2 m²/g with CL-SPEEK/Cs-TPA/CeO₂ membrane. In water electrolysis performance, the cell voltage of Pd/PEM/Pt–Pd MEA with CL-SPEEK/Cs-TPA/CeO₂(1%) composite membrane showed cell property of 1.82 V at 1 A cm⁻² and 80 °C.     

一种简单合成7-羟基-高异黄酮的催化方法

以间苯二酚和苯丙酸为原料,三氟化硼乙醚为催化剂合成了2',4'-二羟基二氢查尔酮(收率84%),再经过增碳成环得到7-羟基-高异黄酮(收率84%)。此法绿色简捷,生产成本较低。     

红外伪装涂料的性能及存在问题

详细论述了红外伪装涂料的作用机理和影响因素以及存在问题.     

水玻璃的固化机理及其提高耐水性途径分析

伴随环保要求的提升和人们环境意识的提高,水玻璃作为一种环境友好型粘结剂受到广大研究者以及消费者的垂青。但水玻璃因其自身的结构而导致的固化后耐水性差的问题尚未得到彻底的解决,不同的固化途径而产生的固化机理亦是琳琅满目,从而使水玻璃在其应用原理以及解决其相应的缺陷上受到阻碍。笔者对近几年来所研究的水玻璃固化机理以及提高其耐水性途径进行了详细的分析,以促进和拓宽水玻璃的改性研究及应用领域。     

Study of electrochemical hydrogen charge/discharge properties of FePO4 for application as negative electrodes in hydrogen batteries

We report the electrochemical hydrogen charge/discharge properties of electrodes containing crystalline and amorphous FePO₄ as active material in KOH electrolyte. Crystalline and amorphous FePO₄ were synthesized by an alcohol-assisted precipitation method, and the powders obtained were characterized by X-ray diffraction. X-ray photoelectron spectroscopy is used to investigate the mechanism of hydrogen charge/discharge behavior of FePO₄. The electrochemical hydrogen charge/discharge properties of electrodes containing crystalline and amorphous FePO₄ were investigated for potential application as negative electrodes in rechargeable hydrogen batteries. In galvanostatic discharge/charge mode at 25 °C, the crystalline FePO₄ showed a maximum discharge capacity of 109 mA h g⁻¹, while the amorphous FePO₄ showed a maximum discharge capacity of 81.4 mA h g⁻¹. The electrochemical kinetic properties, exchange current density, and proton diffusivity were calculated using linear polarization measurement and the potential-step method.