Alloying effects on the hydride formation of Zr(Mn1−xCox)2

To study the alloying effects on ZrMn₂-H system, thermodynamic properties of Zr(Mn_1−xCo_x)₂ hydride were measured by volumetric method. ZrMn₂ gave a single plateau region in the pressure-composition isotherm. On the other hand, double plateaus were clearly observed in Zr(Mn_0.7Co_0.3)₂ and Zr(Mn_0.6Co_0.4)₂-H systems. The appearance of the double plateau characteristics would be explained in view of the hydrogen binding in the tetrahedral occupation sites in Zr(Mn_1−xCo_x)₂. Since the hydrogen binding in the tetrahedral 2ZrMnCo site would be less stable than that in the 2Zr2Mn site, the equilibrium pressure increases with increasing cobalt content. The appearance of the first plateau was ascribed the increase in the bonding of Mn-H in 2Zr2Mn site adjoining the 2ZrMnCo site.     

Self-powered structural health monitoring with nonlinear energy harvesting system

The present paper describes the application of the fully self-powered structural health monitoring (SHM). Based on the nonlinear process of microgenerators that directly convert ambient mechanical energy into electrical energy, using the synchronized switch harvesting (SSH) method developed in our laboratory, the nonwired SHM system is equipped. The system is separated into two parts. One is an autonomous wireless transmitter (AWT), its mass is 28.9 g, and it generates a radio frequency (RF) signal and a Lamb waveform as a damage index signal. Another part is these receivers, called autonomous wireless receiver (AWR), and its weight is of 67.6 g. A preliminary design of the device using shelf electronics and surface mounted piezoelectric patches is presented. The energy balance shows that more than enough energy to operate these processes can be obtained within 10 s (when around 50 Hz and more than 2 MPa of the stress level). Some different damage index measurements of SHM are finally discussed.     

Impact force detection using an energy flow estimator with piezoelectric sensors

Currently, there are numerous methods for estimating impact locations. One is to find more detailed information because the system becomes complicated. Another method is to reduce energy, for which various autonomic energy harvesting methods have been developed. However, the occupied energy is still small. This paper proposes a simple, rapid, and low-powered impact estimation method based on energy flow direction estimation through a pair of piezoelectric sensors. The estimation energy flow is expressed by a Poynting vector subsequently linked to piezoelectric sensor voltage outputs. The presented approach is verified by numerical simulations and experiments.     

Nickel/Zinc Chloride‐Promoted Domino Reaction of Enynes and Enones Including Unstrained C?C Bond Cleavage

Unstrained C C bond cleavage proceeds during the domino reaction of enynes and enones that includes successive C C bond formation under the nickel/zinc/zinc chloride system. The cleavage occurs through β‐syn‐elimination of the 1,3‐dicarbonyl part. In addition, β‐carbon elimination is selective, unlike the β‐hydrogen elimination in the presence of excess zinc chloride.     

Chemical analysis and acetylcholinesterase inhibitory effect of anthocyanin-rich red leaf tea (cv. Sunrouge)

BACKGROUND: The purpose of this study was to evaluate the effects of leaf order or crop season on anthocyanins and other chemicals in the anthocyanin‐rich tea cultivar ‘Sunrouge’ (Camellia sinensis x C. taliensis) by using high‐performance liquid chromatography, and to study the effect of ‘Sunrouge’ extract on acetylcholinesterase (AChE) activity in human neuroblastoma SK‐N‐SH cells. RESULTS: The total anthocyanin content was higher in the third (3.09 mg g^?1) than in the second (2.24 mg g^?1) or first crop season (1.79 mg g^?1). The amount of anthocyanins contained in the stem was high (1.61 mg g^?1). In the third crop season, the concentrations of delphinidin‐3‐O‐β‐D ‐(6‐(E)‐p‐coumaroyl)galactopyranoside (DCGa), cyanidin‐3‐O‐β‐D ‐(6‐(E)‐p‐coumaroyl)galactopyranoside, delphinidin‐3‐O‐β‐D ‐galactopyranoside, delphinidin‐3‐O‐β‐D ‐(6‐O‐(Z)‐p‐coumaroyl)galactopyranoside, cyanidin‐3‐O‐β‐D ‐galactoside, and delphinidin‐3‐O‐β‐D ‐glucoside were 1.57 mg g^?1, 0.52 mg g^?1, 0.40 mg g^?1, 0.22 mg g^?1, 0.14 mg g^?1, and 0.11 mg g^?1, respectively. DCGa accounted for about 50% of the anthocyanins present. The suppressive effect of ‘Sunrouge’ water extract on AChE activity in human neuroblastoma SK‐N‐SH cells was the strongest among the three tea cultivars (‘Sunrouge’, ‘Yabukita’ and ‘Benifuuki’). CONCLUSION: These results suggested that ‘Sunrouge’ might protect humans from humans from AChE‐related diseases by suppressing AChE activity. To obtain sufficient amounts of anthocyanins, catechins and/or caffeine for a functional food material, ‘Sunrouge’ from the third crop season should be used. Copyright © 2012 Society of Chemical Industry     

Hydrolyzable‐emulsifier‐containing polymer latices as dispersants and binders for waterborne carbon black paint

Poly(styrene‐co‐butyl methacrylate) and poly(styrene‐co‐butyl acrylate) latices were prepared by emulsion polymerization with alkali‐hydrolyzable and nonhydrolyzable cationic emulsifiers and were used as a dispersant and binder for waterborne carbon black (CB) paint. CB was dispersed in the latex solutions and then coated on filter paper pretreated with dilute aqueous Na₂CO₃ under mild conditions. The styrene (St)‐rich rigid copolymer latices easily dispersed the CB but fixed a little amount of the pigment on the paper surface. In contrast, the methacrylate‐ and acrylate‐rich soft latices tended to increase the adhesibility on it. We also demonstrated that the hydrolyzable‐emulsifier‐containing latices always had a higher adhesibility than the nonhydrolyzable‐emulsifier‐containing ones. Thus, the hydrolyzable‐emulsifier‐containing latices with an appropriate St content had the highest paintability, rapid adhesion, quick drying, reduced fading, superior fastness, and so on. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3869–3873, 2013     

Study of molecular behavior in oxidation of insulating oil using terahertz spectroscopy

The stock of aged power equipment is increasing and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes a basic study of molecular behavior in the oxidation of insulating oil by terahertz spectroscopy. The oxidation of insulating oil was modeled by using various compositions of dodecane and 2‐octanol. The terahertz measurements indicated that signi?cant absorption related to hydroxyl groups (‐OH) occurred between 6 and 7 THz. The absorption band was also observed in accelerated aging alkylbenzene, which is used in power equipment as insulating oil and is sensitive to hydrogen bonds. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 183(1): 9–15, 2013; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/eej.22335     

Measurement of topcoat thickness of thermal barrier coating for gas turbines using terahertz waves

The topcoat thickness of thermal barrier coating (TBC) samples was measured using terahertz (THz) waves. The index of refraction of yttria‐stabilized zirconia (YSZ), which is the topcoat material, is necessary to obtain the topcoat thickness from time domain re?ectometry. Time domain THz spectroscopy was applied to YSZ samples, and the index of refraction was measured to be 4.8 in the frequency region 0.1 to 1.2 THz. The topcoat thickness of six di?erent TBC samples, which varied from 300 to 600 µm, was measured using THz waves. The results were in agreement with microscope observation results to within measurement error. In addition, the topcoat thickness pro?le of a turbine blade sample was measured with a resolution of 2.4 µm. The pro?le showed a standard deviation of 4 µm, which re?ects the actual variation in the topcoat thickness. The results showed that THz waves are e?ective for high‐resolution measurement of the topcoat thickness. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 183(4): 1–9, 2013; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/eej.22385     

Low-temperature synthesis in vacuum of c-axis oriented ferroelectric YMnO3 thin films using alkoxy-derived precursors

Abstract

Hexagonal YMnO₃ thin films were prepared on Pt(111)/TiO_x/SiO₂/Si and Pt(111)/Al₂O₃(0001) substrates using alkoxy-derived precursor solutions. The films were prepared by spin coating the YMnO₃ precursor solutions and then, the films were calcined and crystallized via rapid thermal annealing in oxygen or vacuum ambient. The annealing conditions and substrates were critical for crystallization of ferroelectric YMnO₃ films. When annealed in vacuum, the films both on Pt(111)/TiO_x/SiO₂/Si and Pt(111)/Al₂O₃(0001) substrates crystallized to hexagonal YMnO₃ and the orientation depended on the substrates. The film on Pt(111)/Al₂O₃(0001) had c-axis orientation and the film on Pt(111)/TiO_x/SiO₂/Si had no preferred orientation. In addition, it was found that crystallization behavior, orientation and morphology of YMnO₃ films on Pt(111)/TiO_x/SiO₂/Si substrates depended on the annealing condition. The heat-treatment in vacuum at initial stage for crystallization affected the restraint of perovskite phase and formation of hexagonal phase. The following heat-treatment in oxygen promoted the c-axis orientation and grain growth. The optimum annealing procedure for crystallization of the c-axis oriented YMnO₃ films on Pt(111)/TiO_x/SiO₂/Si was addressed.