Growth and optical property of zinc oxide thornballs

A new microstructure, thornball, of zinc oxide (ZnO) was synthesized by a very simple solid vapor deposition process under lead oxide (PbO) atmosphere. The microthornballs consist of numerous needles, which extend outwards in all directions symmetrically. They have dimensions of 120 μm in diameter, while the average diameter of the needles is about 100-200 nm. The needles on the balls grow along the 〈0 0 0 1〉 orientation and have gradient compositions along radial. Control experiments proved that PbO played an important role in the growth. Additionally, photoluminescence property was observed and provided the evidence that PbO did not deteriorate the optical properties of ZnO thornballs. This kind of microstructures has potential applications in the field of photochemical catalysis.     

Functionalization of soluble polymers

Summary The synthesis of di-(4-formylphenyloxyethyl) poly(oxyethylene) and the corresponding oxime derivative are described. Kinetic aspects of the reaction of the dichloro telechelic with 4-hydroxy benzaldehyde are investigated and discussed.     

PMD Measurement of Hollow-Core Photonic Bandgap Fiber by Investigating Power Penalty of Optically Generated Microwave Signals

A simple method based on carrier suppression modulation for measuring first-order polarization-mode dispersion of hollow-core photonic bandgap fiber (HC-PBGF) is proposed and investigated. By adjusting the incident optical wavelength and measuring the power penalty of optically generated microwave signals, the wavelength-dependent differential group delay (DGD) in HC-PBGF can be obtained. Moreover, this proposed method is chromatic-dispersion-insensitive. The experimental results indicate that a segment of 20-m HC-PBGF exhibits highly birefringent DGD of 25, 59, and 84 ps with measurement error less than 2 ps for the incident optical wavelength of 1560, 1575, and 1580 nm, respectively     

负载化非茂单活性中心催化剂乙烯聚合的研究

在硅胶上负载了双(N-环己基-3-叔丁基水杨醛亚胺基)二氯化锆配合物,得到负载化非茂单活性中心催化剂。该催化剂用于乙烯聚合,考察了配合物用量、共聚单体1-己烯用量、聚合温度、聚合压力、聚合时间、三乙基铝用量对乙烯聚合性能的影响及对聚合物的相对分子质量、相对分子质量分布、熔体流动指数和密度的影响。实验结果表明,负载化非茂单活性中心催化剂保持了原均相催化剂的乙烯聚合性能;该催化剂在淤浆聚合工艺中聚合平稳,所得聚合物的颗粒形态良好。     

离子液体用于燃料油深度脱硫的研究进展

首先介绍了加氢催化脱硫和其他脱硫技术的特点,综述了近年来国内外利用离子液体在萃取脱硫、萃取脱硫与氧化脱硫耦合、萃取脱硫与生物脱硫耦合等方面的研究。认为离子液体萃取脱硫具有操作简便、可循环使用、无需氢气、环境友好、能深度脱硫等特点,是一项具有广阔发展前景的技术。若要实现该技术的工业化应用,还需进一步加强离子液体在合成工艺、脱硫选择性及回收再生等方面的研究。     

加快改革解决电煤供需问题

分析了电力行业煤炭采购垄断的弊端。提出要用市场手段和改革的作法解决电煤供需的问题，探索发展多种形式的煤炭资源配置方式，提高能源经济运行的质量。