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101.
    
Do-it-yourself methods have been used in many fields (cooking, home improvement, decoration, gardening, etc.) for a long time, but their application to the cosmetics sector is relatively recent and seems to be linked to a number of health scandals. The objective of this work is to analyse homemade cosmetics based on a study of blogs and their authors. We made a study of 150 blogs advocating homemade cosmetics. With only one exception, the blog authors were women, mostly in their thirties, with no specific qualifications or knowledge in the fields of cosmetic formulation or chemistry. The most highly qualified of them (with at least a Master's degree) had studied marketing and management. So, the situation is an illustration of the Dunning-Kruger effect, with authors believing themselves to be qualified in a field wholly outside their own. This leads to scientific falsehoods about, for example, preservatives like parabens and phenoxyethanol. On the contrary, the relevance of the ecological motivation frequently mentioned in these blogs is undeniable.  相似文献   
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Sequence-defined synthetic polymers have recently emerged as an attractive medium to store information at the molecular level, where comonomers of the chains are defined as letters of an alphabet. The main read-out methodology employed to retrieve such molecularly encoded information is tandem mass spectrometry (MS/MS), but a major current limitation remains the low storage capacity of readable chains. Ordering short oligomers at discrete locations onto surfaces to compose long messages is an attractive alternative to the difficult synthesis of long coded polymers. Yet, such surface storage requires a reliable sampling technique to be coupled on-line with MS/MS. Because it combines fast surface extraction with efficient analyte ionization in ambient conditions, desorption electrospray ionization (DESI) is shown here to be perfectly suited to envisage bidimensional data storage. The present study demonstrates performances of DESI-MS/MS at mapping oligomers used to write letters of a word, extracting digital labels from materials tagged for anticounterfeiting purposes, and imaging text written with coded polymeric inks.  相似文献   
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In their article ( https://doi.org/10.1002/adfm.201703511 ), Bojnicic‐Kninski et al. expose the known methods used for creating, on a same substrate, patterns composed of different types of particles. This approach is called “combinatorial particle patterning.” They describe various techniques and group them depending on the used methods or driving forces that enable the directed assemblies of particles. A substantial part of the article (Part 2: Electrical Particle Patterning) referred to particle assemblies guided by electrostatic forces, i.e., electrophoretic or dielectrophoretic forces. However, this part, especially the paragraph on “Nanoxerography” (cf. 2.2 of the article) suffers from some inaccuracies that lead to partially wrong conclusions regarding combinatorial particle patterning. The goal of this comment is double: i) giving a complete and up to date definition of nanoxerography ii) reporting the results on combinatorial particle patterning using nanoxerography to correct the article inaccuracies.  相似文献   
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Strata title was introduced in Australia over 50 years ago and offered a legal mechanism for space to be vertically subdivided and traded. Importantly, it allowed individualised property rights to be applied to multi-unit housing. In New South Wales, recent changes to the Strata Scheme Development Act allow termination of strata schemes with less than unanimous support of owners. A central feature of the discussion surrounding the implementation of these changes was to question the rights associated with ownership of strata. This paper presents findings from key-informant interviews undertaken in the lead up to the reforms to the NSW legislation governing strata termination. Analysis of these interviews demonstrates the complex ways in which property rights are understood in relation to strata termination within the broader context of housing. This paper argues that successful implementation of the new legislation impacting upon property rights in strata will require concerted engagement with wider social concepts and understanding of housing within the Australian community.  相似文献   
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Carbon particulates generated during detonation depend upon high explosive type, composition, and detonation conditions. Although explosive composition greatly affects particulates, the focus of this work is on how detonation geometries that induce much higher temperatures and pressures in the high explosive lead to differing particulate morphologies. In this study, two geometries were used: Detonations were initiated in Composition B cylinders at one end in conventional detonations and initiated at both ends to produce colliding detonations. Each of these detonations was observed on the sub-μs timescale using fast radiography capturing images of the front moving through the cylinder, and colliding detonation fronts in real-time. These imaging experiments were complemented with time-resolved small-angle x-ray scattering (SAXS) experiments that were able to observe and determine the varying condensed carbon morphologies at different locations and times in each detonation. The detonations could be timed in such a way that the spatial and temporal dependence of the carbon morphology could be superimposed onto radiography images collected at the same point in time. The complementary approach is able to show that the carbon condensates are much larger when formed in the elevated temperature and pressure conditions near the location of colliding detonation fronts. Thermochemical modeling suggests that these larger particulates form either in the diamond phase or on the liquidus line of the carbon phase diagram. The increase in size observed by SAXS may correlate well with the increased residence time deeply in the diamond phase. These particulates can be described as nano-sized phases with some surface texture or otherwise near-surface intra-particle heterogeneity.  相似文献   
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Biological structures control cell behavior via physical, chemical, electrical, and mechanical cues. Approaches that allow us to build devices that mimic these cues in a combinatorial way are lacking due to there being no suitable instructive materials and limited manufacturing procedures. This challenge is addressed by developing a new conductive composite material, allowing for the fabrication of 3D biomimetic structures in a single manufacturing method based on two‐photon polymerization. The approach induces a combinatorial biostimulative input that can be tailored to a specific application. Development of the 3D architecture is performed with a chemically actuating photocurable acrylate previously identified for cardiomyocyte attachment. The material is made conductive by impregnation with multiwalled carbon nanotubes. The bioinstructive effect of 3D nano‐ and microtopography is combined with electrical stimulation, incorporating biochemical, and electromechanical cues to stimulate cells in serum‐free media. The manufactured architecture is combined with cardiomyocytes derived from human pluripotent stem cells. It is demonstrated that by mimicking biological occurring cues, cardiomyocyte behavior can be modulated. This represents a step change in the ability to manufacture 3D multifunctional biomimetic modulatory architectures. This platform technology has implications in areas spanning regenerative medicine, tissue engineering to biosensing, and may lead to more accurate models for predicting toxicity.  相似文献   
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