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51.
A first‐principles‐based effective Hamiltonian is developed and employed to investigate finite‐temperature structural properties of a prototype of perovskite halides, that is CsPbI3. Such simulations, when using first‐principles‐extracted coefficients, successfully reproduce the existence of an orthorhombic Pnma state and its iodine octahedral tilting angles around room temperature. However, they also yield a direct transformation from Pnma to cubic upon heating, unlike measurements that reported the occurrence of an intermediate long‐range‐tilted tetragonal P4/mbm phase in‐between the orthorhombic and cubic phases. Such disagreement, which may cast some doubts about the extent to which first‐principle methods can be trusted to mimic hybrid perovskites, can be resolved by “only” changing one short‐range tilting parameter in the whole set of effective Hamiltonian coefficients. In such a case, some reasonable values of this specific parameter result in the predictions that i) the intermediate P4/mbm state originates from fluctuations over many different tilted states; and ii) the cubic phase is highly locally distorted and develops strong transverse antiphase correlation between first‐nearest neighbor iodine octahedral tiltings, before undergoing a phase transition to P4/mbm under cooling. 相似文献
52.
Strength of Materials - The use of a damping system is one of the seismic protection systems that improve the seismic response of structures. The proposed methodology estimates the location (which... 相似文献
53.
Strength of Materials - The statistical analysis performed on the defectiveness of rails in the Kiev subway railway shows that the main cause of the occurrence of most defects is the contact... 相似文献
54.
Loboda P. I. Minitsky A. V. Byba Ye. G. Sysoev M. O. Radchuk S. V. 《Powder Metallurgy and Metal Ceramics》2020,58(11-12):651-656
Powder Metallurgy and Metal Ceramics - The infiltration of aluminum melts into porous metal skeletons produced by powder metallurgy methods, including 3D printing, under a pressure gradient was... 相似文献
55.
56.
Strength of Materials - Methodical aspects of experimental investigation of brittle materials under local edge loading by scratching the specimen surface with a Rockwell indenter to its edge... 相似文献
57.
Measurement Techniques - A method is proposed for transferring the unit of mean power of laser radiation by means of measuring high-intensity power (kilowatts), with the possibility of constant... 相似文献
58.
Kevin J. Hanley 《International journal for numerical methods in engineering》2020,121(21):4865-4877
An algorithm is presented for discrete element method simulations of energy-conserving systems of frictionless, spherical particles in a reversed-time frame. This algorithm is verified, within the limits of round-off error, through implementation in the LAMMPS code. Mechanisms for energy dissipation such as interparticle friction, damping, rotational resistance, particle crushing, or bond breakage cannot be incorporated into this algorithm without causing time irreversibility. This theoretical development is applied to critical-state soil mechanics as an exemplar. It is shown that the convergence of soil samples, which differ only in terms of their initial void ratio, to the same critical state requires the presence of shear forces and frictional dissipation within the soil system. 相似文献
59.
Wireless Personal Communications - In the fusion experiment, sensitive radio frequency signal diagnostic instruments need to be protected against high power stray radiation coming from the Electron... 相似文献