Fracture behaviour of composite maritime T-joints

This paper outlines a study on the fracture behaviour of a glass fibre reinforced polymer T-joint commonly used in composite marine vessels. Finite element analysis was conducted using the virtual crack closure technique (VCCT) to investigate the fracture behaviour of the structure. The structure analysed contained initial disbond in various locations with various sizes under a straight pull-off load. The strain energy release rate (SERR) at the disbond tips were used to predict the failure loads and crack growth mechanism of the structure. The experimental results validated the VCCT as a tool for assessing the fracture behaviour and damage criticality of such structures. It was also discovered that skewed loading affected the SERR at the crack tips which altered the fracture behaviour of such structures, therefore sensitivity analysis is recommended to enhance the prediction accuracy.     

Coprecipitation of Pu(IV) with Fe(III) and Cr(III) hydroxides from nitrate-acetate solutions under hydrothermal conditions simulating deep disposal of liquid radioactive wastes

Precipitation of Fe(III), Cr(III), Ni(II), and Mn(II) from nitrate-acetate solutions and coprecipitation of Pu(IV) with Fe(III) and Cr(III) were studied. The degree of precipitation of 80–95% is attained for Fe(III) at 95–200°C and pH>0.5–0.6, and for Cr(III), at T=95°C and pH≥4.0 or T=200°C and pH≥1.0. The phase composition of the precipitates formed by thermal hydrolysis of iron nitrate in model solutions was analyzed. Depending on pH and temperature, the solid phase contains various modifications of Fe₂O₃, FeOOH, and amorphous phases. Noticeable coprecipitation of plutonium from nitrate-acetate solutions is observed at pH≥4, and it is incorporated in the precipitate only at formation of FeOOH. No coprecipitation of Pu(IV) with Fe₂O₃ was found. Under the given experimental conditions, plutonium in aqueous solutions occurs in the oxidation state +4 forming monoacetate (or, probably, hydroxo acetate) complexes.     

Self-assembling of zinc and tellurium impurities in zinc-blende MgS

Conditions providing a thermodynamic advantage governing the self-assembly of Zn and Te impurities in metastable magnesium sulfide (MgS) with zinc-blende structure have been theoretically studied. The formation of tetrahedral 1Te4Zn cells is thermodynamically favorable in Zn_xMg_{1 ? x} Te_yS_{1 ? y} (x ≥ 4y) solid solutions enriched in MgS in the region of dilute Te concentrations. At temperatures selected for the growth (230°C) and annealing (500°C), the free energy of a solid solution in which separate Te atoms must be surrounded only by Zn atoms is lower than that of the solution with a random arrangement of these impurities. This phenomenon is due to a thermodynamic advantage of the formation of Mg-S and Zn-Te bonds over Zn-S and Mg-Te bonding, as well as due to a decrease in the elastic strain energy upon self-assembly of the given isoelectronic impurities.     

Two-wave-plate compensator method for full-field retardation measurements

The two-wave-plate compensator (TWC) method is expanded for full-field retardation measurements by use of a polarization microscope. The sample image is projected onto a CCD camera connected to a computer, allowing the retardation to be measured at all pixels. The retardation accuracy of this implementation of the TWC is evaluated to be 0.06 nm. The method is applied to polarization-maintaining fibers and long-period fiber gratings. The measured retardation is in good agreement with the crossed-polarizer images of the fibers. The method achieves a spatial resolution of 0.45 microm and a retardation resolution of 0.07 nm. The full-field TWC method can thus be a useful tool for characterizing and monitoring the fabrication of optical devices.     

Undercooling and demixing of copper-based alloys

Since the beginning of materials science research under microgravity conditions immiscible alloys have been an interesting subject. New possibilities to investigate such systems are offered by containerless processing techniques. Of particular interest is the ternary system Cu-Fe-Co, and its limiting binaries, Cu-Co and Cu-Fe. They all show a metastable miscibility gap in the regime of the undercooled melt. Within the ESA-MAP project “CoolCop”, different aspects of this alloy have been investigated; results obtained so far are reported here.