Molecular weight effect on the obtainment of parallel and perpendicular orientation in thermotropic poly(diethylene glycol <Emphasis Type="Italic">p,p′</Emphasis>-bibenzoate)

Summary The effect of molecular weight on the uniaxial orientation process has been analyzed in two samples of thermotropic poly(diethylene glycol p,p′-bibenzoate), evaluating the influence of that parameter on the type of orientation obtained. Several strain rates and deformation temperatures have been tested in order to map out the conditions for obtaining the two different kinds of orientation. The results show that in the lower molecular weight PDEB sample (M_w=31200) it is rather easy to get exclusively perpendicular “anomalous” orientation, with the molecular axes aligned transversely to the stretching direction. However, it is extremely difficult to obtain 100% parallel “normal” orientation. On the contrary, either type of orientation or a mixture of them can be easily developed for the higher molecular weight PDEB sample (M_w=102900).     

Synthesis of TiO<Subscript>2</Subscript> Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

TiO₂ hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO₂ nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.     

"十五"农村水电发展分析与"十一五"发展预测

本文分析了"十五"期间农村水电发展情况,对"十一五"农村水电发展政策环境及增长情况进行了预测。     

Luminescence from praseodymium doped AlN thin films deposited by RF magnetron sputtering and the effect of material structure and thermal annealing on the luminescence

Thin films of Praseodymium doped AlN are deposited on silicon (111) substrates at 77 K and 950 K by rf magnetron sputtering method. About 500–1000 nm thick films are grown at 100–200 watts RF power and 5–8 mTorr nitrogen, using a metal target of Al with Pr. X-rays diffraction results show that films deposited at 77 K are amorphous and those deposited at 950 K are crystalline. Cathodoluminescence studies are performed at room temperature and luminescence peaks are observed in a wide range from ultraviolet to infrared region. The most intense peak is obtained in green at 526 nm from amorphous films as a result from ³P₁→³H₅ transition. In crystalline films the intense peak was obtain in red at 648 nm as a result from ³P₀→³F₂ transition. Films are thermally activated at 1300 K for half an hour in a nitrogen atmosphere. Thermal activation enhances the intensity of luminescence. Two peaks at 488 nm and 505 nm merged after thermal activation, giving rise to a single peak at 495 nm.     

矩形垂直筛板的流体力学性能研究

在600mm的有机玻璃冷模塔中,用水-空气体系测定矩形垂直筛板的塔板压降、漏液和雾沫夹带等流体力学性能,确定了合理的塔板结构,使其具有较高的气液通量和较宽的操作范围,空塔动能因子最大可达3.0kg1/2(m1/2.s)-1,液流强度可达21.6m3/(m.h)。并对不同气液流量下塔板的流体力学实验数据进行关联和分析,得出了矩形垂直筛板的干板压降计算关联式以及漏液率随液流强度和空塔动能因子的变化关系,为矩形垂直筛板的设计提供了依据。与新垂直筛板相比,矩形垂直筛板具有更低的塔板压降。     

快速色谱分析技术在油气勘探中的应用

文章通过对五口井的现场应用介绍，阐述了快速色谱分析技术在油气层识别和解释方面的准确性，探讨了该技术在薄油气层的发现和评价、快速钻进条件下油气层的发现、对油气层全烃组份变化的统一、水平井的地质导向以及排除钻井液添加荆对油气显示的影响五个方面的优势，从而论证了快速色谱分析技术在油气勘探中的应用价值。     

Measurement of the density and surface tension of Ni-based superalloys in the liquid and mushy states

The densities of three Ni-based superalloys have been measured in both liquid and mushy states by both a modified sessile drop method (MSDM) and a modified pycnometric method (MPM) for alloys CMSX-4 and CM186LC, and for CMSX-10 alloy by MSDM only. The surface tensions of liquid CMSX-4, CM186LC, and CMSX-10 superalloys were measured using the sessile drop method. All measurements were carried out in a highly purified argon atmosphere with the oxygen partial pressure of less than 10⁻¹⁹ MPa in the gas outlet. The densities of all superalloys in both liquid and mushy states were found to decrease with increasing temperature. The volume thermal expansion of each superalloy in the mushy state was found to be higher than that in the liquid state. The densities determined by different methods have been critically assessed and recommended values in both liquid and mushy states are given as a linear function of temperature for the three Ni-based superalloys. The surface tension of liquid CMSX-4 superalloy was found to decrease with increasing temperature, while that of liquid CMSX-10 superalloy increases with increasing temperature. The wetting behavior of liquid CM186LC on the alumina substrate was found (1) to differ significantly from that of CMSX-4 and CMSX-10 and (2) to vary with time. A HfO₂-rich layer was found in the contact area of CM186LC with the alumina substrate, which could lead to some uncertainty in the value obtained for the surface tension determined for CM186LC.     

低渗透油田合理注采井距的确定--以纯41块沙4段低渗透油田为例

以纯41块沙4段低渗透油田为例，从低渗透油田渗流机理出发，分析了造成低渗透油田开发效果差的主要原因。在计算注水井最大井底流压、油井最小井底流压、油水井之间可建立的最大注采压差的基础上，结合室内试验确定的最小启动压力梯度公式计算油田技术极限注采井距，并结合经济合理井距计算结果，确定了油田合理注采井距，并提出了下二步调整方案，实施后取得了显著的效果。该方法为低渗透油田合理井距的确定、提高低渗透油田的开发效果提供了理论依据。     

SPW中自定义模块的创建与测试

SPW是一个先进的通信系统建模、仿真工具，它具有丰富的通信仿真模块和非常灵活的创建自定义模块功能。通过创建一个简单的自定义模块并对其进行功能测试，介绍了在SPW中创建及测试用户自定义模块的方法。这一实例表明，在SPW中可以将现成的模块与用户自定义模块有机结合在一起，从而大大提高了工程人员的工作效率，同时又扩展了SPW的应用领域。     

A novel broadcast scheduling strategy using factor graphs and the sum-product algorithm

This paper presents a novel self-organizing distributed algorithm for finding a broadcasting schedule in a packet radio network via only local collaborative interactions among neighboring network stations. Inspired by the huge success of the low density parity check (LDPC) codes in the field of error control coding, we transform the broadcast scheduling problem (BSP) into an LDPC-like problem through a factor graph. In the proposed algorithm, the constraint rules of the BSP are divided into many simple local rules, each of which is enforced by a local processing unit in the factor graph. The soft-information, describing the probability that each station will transmit a data packet, is then efficiently exchanged among the local processing units by using the sum-product algorithm to iteratively optimize the broadcasting schedule. Simulation results indicate that the proposed algorithm performs better than the other existing central-processing algorithms in terms of the channel utilization and the average packet delay. This is true especially when the network scenario is very complex. Furthermore, the proposed algorithm is both low in complexity and completely distributed, which makes it suitable for implementation in practical network applications.