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101.
锝化学研究 Ⅸ.脑显像剂Tc~(Ⅴ)ON_2S_2类配合物结构稳定性和价态的研究 总被引:1,自引:0,他引:1
采用改进的CNDO/2法模拟了BAT类脑显像剂Tc(Ⅴ)O配合物价态的转换过程,发现N2S2类配体与Tc(Ⅴ)O核配位时,可能存在配位平衡离子X。在溶液中由于X离子的优先解络,瞬间存在+1价对称性99Tcm配合物,并且,它又自动向相对稳定的0价不对称性99Tcm配合物转换,在动态转换过程中,将导致仅有一个配位N原子保留一个质子,这与实验结果一致。采用键级削弱百分数概念,表征配位过程的二个配位N原子上保留程度,解释了Tc(Ⅴ)O核、Tc(Ⅴ)≡N核N2S2类配合物两个N-H键上质子保留程度不同的原因,为今后设计不同价态锝配合物结构提供理论依据。 相似文献
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Herein, we report an efficient process for preparing monodisperse Au@SiO2 nanoparticles using homogeneous shaking and without the use of surface‐coupling silane agents or large stabilizers. The resulting pure‐silica surface of the Au@SiO2 nanoparticles is very important for straightforward surface functionalization with different functional groups via well‐established silica surface chemistry. Subsequent covalent bioconjugation of the aldehyde‐functionalized Au@SiO2 nanoparticles with various biomolecules is successfully employed to make robust nanoprobes for fast, colorimetric DNA and protein detection based on the sequence‐specific hybridization properties of DNA and the specific binding affinity between proteins, respectively. 相似文献
106.
The Testbed for Distributed Processing, or Ted, consists of Intel Corp.'s iSBC 8086 single board computers (SBCs) organized into groups or clusters. Each cluster consists of several SBCs that communicate via a shared memory. Intercluster communication occurs through an Ethernet interface. A hardware monitor designed and implemented to handle the monitoring activities within a cluster in the Ted system is described. By using specified patterns and don't-care masks, the system can detect accesses to selected data, addresses, or blocks of addresses. This function helps monitor events such as the access or usage of a memory location or a group of mailbox addresses. It also determines the amount of time consumed by the performance of specific operations 相似文献
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A pilot-scale fluidised pellet bed (FPB) bioreactor, which combines chemical coagulation, biological degradation, particle pelletisation and separation in one unit, was applied for onsite wastewater treatment and reuse. As a result of rational use of inorganic coagulant and organic polymer and moderate mechanical agitation, spherical particles were generated in the upflow column and a well-fluidised bed was formed. With a continuous supply of dissolved oxygen through a recycling loop, an aerobic condition was kept in the bottom section of the FPB column. Under such conditions the pellets in the FPB column showed the following characteristics: (1) compact structure and high density; (2) rich in microorganisms; and (3) high MLSS and MLVSS concentrations. Therefore, the FPB bioreactor achieved more than 90% removal of SS, COD, BOD and TP from raw domestic wastewater within a total hydraulic retention time (HRT) of only about 30 minutes. It also showed nitrification and denitrification ability and the TN removal could be about 50% as the recycling ratio was increased to 1:1. The treated water quality is generally competitive with the secondary effluent from a conventional activated sludge process. With these advantages the FPB bioreactor is recommendable as a compact system for onsite wastewater treatment and reuse. 相似文献
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文章结合平常工作经验,对低水头电站规划设计中需要注意的包括坝(闸)址选择,库区淹(浸)没、枢纽布置、施工导流、正常蓄水位与上下游梯级衔接五个问题加以分析探讨,进行总结和思考。 相似文献
110.
Shealy J.B. Hashemi M.M. Kiziloglu K. DenBaars S.P. Mishra U.K. Liu T.K. Brown J.J. Lui M. 《Electron Device Letters, IEEE》1993,14(12):545-547
A technology for increasing both the two-terminal gate-drain breakdown and subsequently the three-terminal-off-state breakdown of AlInAs/GaInAs high-electron-mobility transistors (HEMTs) to record values without substantial impact on other parameters is presented. The breakdown in these structures is dependent on the multiplication of electrons injected from the source (channel current) and the gate (gate leakage) into the channel. In addition, holes are generated by high fields at the drain and are injected back into the gate and source electrodes. These phenomena can be suppressed by increasing the gate barrier height and alleviating the fields at the drain. Both have been achieved by incorporating a p+-2DEG junction as the gate that modulates the 2DEG gas and by utilizing selective regrowth of the source and drain regions by MOCVD. The 1-μm-gate-length devices fabricated have two-terminal gate-drain and three-terminal-off-state breakdown voltages of 31 V and 28 V, respectively 相似文献