表面活性剂对纳米MCM-41分子筛分散性的影响

采用聚乙二醇为分散剂,十六烷基三甲基溴化铵为模板剂,正硅酸乙酯为硅源,在室温碱性条件下合成了粒径为40～60 nm的单分散纳米球形MCM-41分子筛.利用XRD、TEM和N2吸附脱附等手段研究了聚乙二醇用量对纳米球形MCM-41的分散性和介孔结构的影响.结果表明,表面活性剂PEG的加入,可以明显改善纳米颗粒的分散性并且对颗粒形貌影响不大;表面活性剂PEG的加入,样品的六方结构有序性和孔尺寸发生变化.PEG量在1%～20%范围内,样品仍具有较高的六方孔道有序性;PEG量过大(60%)有序性明显下降.随着PEG加入量的增加,纳米MCM-41的晶面间距增大,孔尺寸增大.适量的聚乙二醇可以得到有序性好、比表面积大、孔径均一和孔隙率大的单分散纳米球形MCM-41分子筛.     

西门子PLC在拱墅区政府大楼中央空调控制系统中的应用

介绍了西门子PLC及Profi Bus网络在中央空调控制系统中的应用.主要阐述控制系统的硬件配置、软件编程和要实现的功能,并对PLC与DDC作了一些比较.     

浅淡基于IPv6的家庭网络技术

家庭网络将在不远的将来得到极大的普及。与IPv4协议相比，IPv6在地址数量、地址自动配置能力、安全性以及支持移动性等方面具备一系列先进特性，使其可以广泛应用于家庭网络的构建。文章指出将IPv6、信息家电和ICP三者相结合，才能构建高效的家庭网络并开发出吸引用户的家庭网络服务。     

三维网络SiC/Cu金属基复合材料的凝固显微组织

用挤压铸造法制备了三维网络SiC/Cu金属基复合材料,研究了铸造压力、网络SiC骨架预热温度、浇注温度等工艺条件对复合材料凝固显微组织的影响.结果表明,三维网络SiC陶瓷骨架在晶体生长和结晶过程中有重要作用,在一定条件下在网孔内可形成垂直于骨架表面的枝晶网络,或形成粒度细小且分布均匀的等轴晶组织;骨架的孔径对显微组织的影响也很大,细小的孔径有利于晶粒细化和组织均匀化,粗大的孔径助长宏观偏析和铅的偏聚.骨架减轻了复合材料中锡的反常偏析,使锡的偏析主要发生在骨架表面附近的微小区域,从而避免了在铸件表层的集中偏析.     

500kV H-GIS的应用

本文结合广东境内近期建设的几座500kV变电站,介绍日本三菱公司生产的500kV H-GIS的结构和技术特 点,以及运输、安装、试验的情况。     

Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.     

The role of induced contrast in images obtained using the environmental scanning electron microscope

Generation of contrast in images obtained using the environmental scanning electron microscope (ESEM) is explained by interpretation of images acquired using the gaseous secondary electron detector (GSED), ion current, and the Everhart-Thornley detector. We present a previously unreported contrast component in GSED and ion current images attributed to signal induction by changes in the concentration of positive ions in the ESEM chamber during image acquisition. Changes in positive ion concentration are caused by changes in electron emission from the sample during image acquisition and by a discrepancy between the drift velocities of negative and positive charge carriers in the imaging gas. The proposed signal generation mechanism is used to explain contrast reversal in images produced using the GSED and ion current signals and accounts for discrepancies in contrast observed, under some conditions, in these types of images. Combined with existing models of signal generation in the ESEM, the proposed model provides a basis for correct interpretation of ESEM images.     

Ultrastructural characteristics of spermatogenesis in Pallas's mastiff bat, Molossus molossus (Chiroptera: Molossidae)

Despite the large number of species, their wide distribution, and unique reproductive characteristics, Neotropical bats have been poorly studied, and important aspects of the reproduction of these animals have not been elucidated. We made an ultrastructural analysis of spermatogenesis in Molossus molossus (Molossidae). The process of spermatogonial differentiation is similar to that found in other bats and is also relatively similar to that of Primates, with three main spermatogonia types: A(d), A(p), and B. Meiotic divisions proceed similarly to those of most mammals, and spermiogenesis is clearly divided into 12 steps, in the middle of the range known for bats (9-16 steps). Formation of the acrosome is similar to that known from other mammals; however, the ultrastructure of spermatozoa was found to have unique characteristics, including many wavy acrosomal projections on its surface, which seems to be specific for the family Molossidae. Comparing the ultrastructure of the spermatozoon of M. molossus with other bats already study, we observed that three characters vary: morphology of the outer dense fibers, of the perforatorium, and of the spermatozoon head. The great similarity of morphological characters between M. molossus and Platyrrhinus lineatus suggests that M. molossus is more closely related to the Phyllostomidae than to the Rhinolophidae and the Vespertilionidae.     

Predicting the spontaneous termination of atrial fibrillation based on poincare section in the electrocardiogram phase space

Atrial fibrillation (AF) is a commonly encountered cardiac arrhythmia. Predicting the conditions under which AF terminates spontaneously is an important task that would bring great benefit to both patients and clinicians. In this study, a new method was proposed to predict spontaneous AF termination by employing the points of section (POS) coordinates along a Poincare section in the electrocardiogram (ECG) phase space. The AF Termination Database provided by PhysioNet for the Computers in Cardiology Challenge 2004 was applied in the present study. It includes one training dataset and two testing datasets, A and B. The present investigation was initiated by producing a two-dimensional reconstructed phase space (RPS) of the ECG. Then, a Poincare line was drawn in a direction that included the maximum point distribution in the RPS and also passed through the origin of the RPS coordinate system. Afterward, the coordinates of the RPS trajectory intersections with this Poincare line were extracted to capture the local behavior related to the arrhythmia under investigation. The POS corresponding to atrial activity were selected with regard to the fact that similar ECG morphologies such as P waves, which are corresponding to atrial activity, distribute in a specific region of the RPS. Thirteen features were extracted from the selected intersection points to quantify their distributions. To select the best feature subset, a genetic algorithm (GA), in combination with a support vector machine (SVM), was applied to the training dataset. Based on the selected features and trained SVM, the performance of the proposed method was evaluated using the testing datasets. The results showed that 86.67% of dataset A and 80% of dataset B were correctly classified. This classification accuracy is in the same range as or higher than that of recent studies in this area. These results show that the proposed method, in which no complicated QRST cancelation algorithm was used, has the potential to predict AF termination.     

ZJS_1径流式涡轮增压器出厂试验台位

<正> 我厂径流式涡轮增压器出厂试验以往是在柴油机上进行的,只能作初运转试验,所得结果十分粗略,无法满足增压器出厂试验技术要求。以110J 涡轮增压器为例,额定工况转速为58000r/min 极限转速为64000r/min,而在柴油机上试车只能达到44000～46000r/min,……,为了实现 Q/WNJ8—81,65J、80J、110J 径流式涡轮增压器技术条件中出厂试验规范要求,我厂自行设计、制造了