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81.
Jiang Lu Masami Kamigaito Mitsuo Sawamoto Toshinobu Higashimura Yun-Xiang Deng 《应用聚合物科学杂志》1996,61(6):1011-1016
The polymerization of β-pinene with the AlCl3/SbCl3 binary catalyst was investigated in toluene at −40°C and was compared with that of α-pinene. The polymerization of β-pinene with AlCl3 alone was very rapid and retarded on addition of SbCl3, in sharp contrast to that of α-pinene where added SbCl3 remarkably accelerated it to give relatively high molecular weight oligomers. Attempted copolymerization of the two isomers with the binary catalyst, in turn, induced their parallel homopolymerizations, indicating that the copolymerization was difficult due to the large difference in reactivity. The homopolymerizations with AlCl3/SbCl3 were not seriously affected by a sterically hindered base, 2,6-di-tert-butyl-4-methylpyridine (DTBMP); the initiating species, therefore, would be different in nature from a proton. © 1996 John Wiley & Sons, Inc. 相似文献
82.
83.
This paper presents the real-time sensing-based risk-mitigation control of hydrogen dispersion and accumulation in a partially open space with low-height openings by forced ventilation. In the partially open space we previously considered (Matsuura et al., Int J Hydrogen Energy, 35(10), p. 4776–4786 (2010)), a hydrogen buoyant plume is subjected to cross flows during forced ventilation, and hydrogen travels over a long distance in the lower part of the space, which enhances the hydrogen concentration there. On the basis of those results, we alternatively propose in this paper a new partially open space that permits the almost vertical rising of hydrogen from a leak source, and exhausts, by forced ventilation, hydrogen temporarily accumulated near the roof. We first describe computational geometries and scenarios, mathematical models and numerical procedures. 相似文献
84.
Masakazu Kawashita Ayumi Kamitani Toshiki Miyazaki Naoko Matsui Zhixia Li Hiroyasu Kanetaka Masami Hashimoto 《Materials science & engineering. C, Materials for biological applications》2012,32(8):2617-2622
The zeta potential of alumina (Al2O3) powder with different crystalline phases, prepared by heat treatment of boehmite, was measured in simulated body fluids in order to discuss the mechanism on in vivo formation of a calcium and phosphorus (CaP)-rich layer on bone cement containing δ-Al2O3-based bead powder. γ, δ, and θ-Al2O3 powders were obtained by heat treatment of boehmite powder at 600 °C, 900 °C, and 1025 °C, respectively. It was found that δ-Al2O3 gave a negative zeta potential in an acidic simulated body fluid, whereas γ-Al2O3 and θ-Al2O3 gave a positive potentials. During the bone fracture healing process, acidic conditions are maintained at the site of fracture for several days. Consequently, it is speculated that the negative surface potential of δ-Al2O3 in an acidic body fluid, similar to the fracture site, might be responsible for the in vivo formation of the CaP-rich layer on the overlying bone cement, given that the negatively charged surface of δ-Al2O3 would attract calcium ions from the surrounding body fluid, thereby facilitating the formation of the CaP-rich layer. 相似文献
85.
Kiyoshi Mizuuchi Kanryu Inoue Yasuyuki Agari Toru Nagaoka Masami Sugioka Motohiro Tanaka Takashi Takeuchi Jun-ichi Tani Masakazu Kawahara Yukio Makino Mikio Ito 《Composites Part B》2012,43(4):2012-2019
Silicon carbide (SiC)-particle-dispersed-aluminum (Al) matrix composites were fabricated in a unique fabrication method, where the powder mixture of SiC, pure Al and Al–5mass% Si alloy was uniquely designed to form continuous solid–liquid co-existent state during spark plasma sintering (SPS) process. Composites fabricated in such a way can be well consolidated by heating during SPS processing in a temperature range between 798 K and 876 K for a heating duration of 1.56 ks. Microstructures of the composites thus fabricated were examined by scanning electron microscopy and no reaction was detected at the interface between the SiC particle and the Al matrix. The relative packing density of the Al–matrix composite containing SiC was higher than 99% in a volume fraction range of SiC between 40% and 55%. Thermal conductivity of the composite increased with increasing the SiC content in the composite at a SiC fraction range between 40 vol.% and 50 vol.%. The highest thermal conductivity was obtained for Al–50 vol.% SiC composite and reached 252 W/mK. The coefficient of thermal expansion of the composites falls in the upper line of Kerner’s model, indicating strong bonding between the SiC particle and the Al matrix in the composite. 相似文献
86.
Thin films of microcrystalline (CnH2n + 1NH3)2PbBr4 (n = 4, 5, 7 and 12) have been prepared by a modified spin-coating method, and the effect of the number of carbon atoms of the alkyl chain length (n) on optical properties has been investigated. Absorption spectra reveal that (CnH2n + 1NH3)2PbBr4 films show stable excitons with a binding energy of a few hundred meV. The excitonic structure of (CnH2n + 1NH3)2PbBr4 varies with the number of carbon atoms. The lowest-energy exciton splits into a few fine-structure levels at low temperature. (CnH2n + 1NH3)2PbBr4 films (n = 5, 7 and 12) show not only singlet excitons but also triplet excitons at low temperature, while (C4H9NH3)2PbBr4 films show only singlet excitons. The intersystem crossing from excited singlet state to triplet state plays an important role in the relaxation process of excitons. 相似文献
87.
Hiroshi Abe Yusuke Imai Takefumi Goto Yukihiro Yoshimura Masami Aono Takahiro Takekiyo Hitoshi Matsumoto Takashi Arai 《Metallurgical and Materials Transactions A》2010,41(5):1137-1143
Crystal structures of room-temperature ionic liquid (RTIL)-H2O mixtures are determined by the X-ray diffraction method. The RTIL is N,N-diethyl-N-methyl-N-2-methoxyethyl ammonium tetrafluoroborate, [DEME][BF4]. At 0.9 mol pct H2O, two kinds of superstructures occur simultaneously without a strain. Also, the volume of the unit cell is very small only
at 0.9 mol pct additives. This relates to the composite domain structure, including a twin-related one, as an elastic anomaly.
At other water concentrations, such an extraordinary behavior is not observable. By assuming a sublattice having an equivalent
lattice constant, a water network at 1 mol pct H2O is simulated using a Monte Carlo (MC) method. The network develops over the medium range in the simulation box. 相似文献
88.
Masami Tsubota Satoshi Hino Hironobu Fujii Chie Oomatsu Masashi Yamana Takayuki Ichikawa Yoshitsugu Kojima 《International Journal of Hydrogen Energy》2010
The possibility of using ammonia as a hydrogen carrier is examined for the reaction between magnesium ammine complex MgCl2(NH3)6 and lithium hydride LiH. Sample was milled at low temperature of −40 °C to avoid decomposition of MgCl2(NH3)6 during the milling. The effects of milling time, milling speed (revolutions per minute), and catalysts on hydrogen storage properties were investigated by thermogravimetry, thermal desorption mass spectroscopy, and X-ray diffraction experiments. Experimental results indicated that a milled composite of Mg(NH3)6Cl2 and catalyzed-LiH desorbed the ∼100% H2 gas even at 125 °C in a closed system. The reverse reaction also proceeded by separately cooling MgCl2 at lower temperature than 100 °C and heating LiNH2 at 300 °C in the closed system. 相似文献
89.
Toshiaki Sakurai Ryogo Kubo Masami Watanabe Hiromi Ogi 《IEEJ Transactions on Electrical and Electronic Engineering》2008,3(1):1-4
The concept of ‘recycling’ was adopted to solve the overuse of resources by mass production and mass consumption of products in the 20th century. In the latter half of the 20th century, all companies started recycling activities slowly but positively, and some of them established their own recycling plants. This article introduces the processes through which used home appliances are made into materials (for reuse), and the machines, facilities, and methods for such reuse, as well as the results of their actual application by the study of a recycling plant. It is expected that this article would motivate the readers for recycling and to consider and feel what we, consumers, should do. Copyright © 2007 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
90.
Yoshio Nosaka Masami Matsushita Junichi Nishino Atsuko Nosaka 《Science and Technology of Advanced Materials》2013,14(2):143-148
In order to utilize visible light in photocatalytic reactions, nitrogen atoms were doped in commercially available photocatalytic TiO2 powders by using an organic compound such as urea and guanidine. Analysis by X-ray photoelectron spectroscopy (XPS) indicated that N atoms were incorporated into two different sites of the bulk phase of TiO2. A significant shift of the absorption edge to a lower energy and a higher absorption in the visible light region were observed. These N-doped TiO2 powders exhibited photocatalytic activity for the decomposition of 2-propanol in aqueous solution under visible light irradiation. The photocatalytic activity increased with the decrease of doped N atoms in O site, while decreased with decrease of the other sites. Degradation of photocatalytic activity based on the release of nitrogen atoms was observed for the reaction in the aqueous suspension system. 相似文献