In order to prepare low resistance ohmic contacts to p-ZnSn by the “deposition and annealing (DA)” technique which has been
extensively used for GaAs and Si-based devices, formation of a heavily doped layer by the p-ZnSe/metal reaction is required.
For p-ZnSe/Ni contacts, Ni and Se reacted preferentially at the ZnSe/Ni interface upon annealing at temperatures higher than
250°C. However, capacitance-voltage measurements showed that the net acceptor concentration (NA-ND) close to the p-ZnSe/Ni interface was reduced upon the Ni/ZnSe reaction, resulting in high contact resistance. For p-ZnSe/Au
contacts, neither Au/ZnSe reaction nor reduction of the acceptor concentration were observed after annealing at temperatures
lower than 300°C. This indicates that although the metal/p-ZnSe reaction is mandatory to prepare a heavily doped layer, the
reaction induced an increase in the compensation donors in the p-ZnSe substrate. In order to increase the acceptor concentration
in the vicinity of the p-ZnSe/metal interface through diffusion from the contact materials, Li or O which was reported to
play the role of an acceptor in ZnSe was deposited with a contact metal and annealed at elevated temperatures. Ni or Ag was
selected as the contact metal, because these metals were expected to enhance Li or O doping by reacting with ZnSe. However,
the current density-voltage characteristics of the Li(N)/Ni and Ag(O) contacts exhibited rectifying behavior, and the contact
resistances increased with increasing annealing temperature. The present results indicated that, even though the acceptor
concentration in the p-ZnSe substrate increased by diffusion of the dopants from the contact elements, an increment of the
compensation donors was larger than that of the acceptors. The present experiments indicated that preparation of low resistance
ohmic contacts by forming a heavily doped intermediate layer between p-ZnSe and metal is extremely difficult by the DA technique. 相似文献
Crystals of yttria partially stabilized zirconia were grown by the arc-image floating-zone technique and studied by transmission electron microscopy. Crystals annealed at 1700°C consist of tetragonal precipitates and a cubic matrix. The platelike domains in a precipitate are twin-related tetragonal variants stacked alternately parallel to the (011) twin plane. The axial relations between the tetragonal precipitate and the cubic matrix are [100]tetragonal|[100]cubic, [011]tetragonal|[011]cubic. 相似文献
The demand for energy in Japan is expected to increase steadily into the future, and it seems that the importance of nuclear power generation will be heightened more when the situation of our country which is not rich in energy resources is taken into account.
Furthermore, when we consider the present situation that the light water reactors have become common, recent outlook for the supply and demand for uranium resources, trends in the development of the fast breeder reactor technology, etc., the light water reactors are expected to remain dominant in the nuclear power generation of our country until at least the second half of the 21st century.
Based on such a background five PWR utilities in Japan (Hokkaido, Kansai, Shikoku, Kyushu, and the Japan Atomic Power), and Mitsubishi Heavy Industries, Ltd. have jointly started researching the Next Generation PWR which is expected to be the leading nuclear power plant taking place of APWR. 相似文献
An ultrasonic atomizer was used in the spray pyrolysis method to prepare fine, spherical and uniform ZnO particles. Almost spherical particles were obtained successfully which had a mean particle size of 0.15 m and had a very narrow particle size distribution. By using alcohol as the solvent, it was found that the particles do not have hollow shell layers which could usually be observed in the spray pyrolysis process by using water as the solvent. The morphology of the ZnO particles was strongly affected by the concentration of the starting solution. 相似文献
The Ta2O5 powders synthesized by the hydrolysis of tantalum pentaethoxide, Ta(OC2H5)5 in alcoholic solution were monodispersed fine oxide particles, which were a uniform, spherical shape, non-agglomerate, and had a narrow size distribution. They grew to 1.2m after ageing for 1 h after hydrolysis. Powder X-ray diffraction and differential thermal analysisthermogravimetric analysis showed the particles were amorphous and hydrated. These particles lost the water at 290° C and gave well-crystalline Ta2O at 740° C. Throughout these thermal processes, the particle morphology was kept almost the same. 相似文献
The thermal diffusivity of AlN ceramics was significantly decreased by the addition of SiO2. The AlN ceramics with 4 wt% SiO2 could not be densified by pressureless sintering in the temperature range 1400° to 1800°C. The thermal diffusivity of these samples was very low because of their porous structure. The AlN ceramics containing 2, 4, and 8 wt% SiO2 were densified by hot-pressing and also had low thermal diffusivity. In these samples, the grains of the 27R polytype that resulted from the reaction between AlN and SiO2 were dispersed, obstructing the conduction of heat. The relation between the amount of 27R polytype and the thermal diffusivity of the AlN ceramics was determined. 相似文献
The processability of polyethylene in sheet-extrusion or calendering may be improved by the addition of plastic flakes. The effects of plastic flake parameters and flow conditions on the viscosity and the die swell of the suspension were determined, and the structure in flow (morphology or dispersion state) and applications were discussed. Flakes of biaxially oriented polystyrene, high-impact polystyrene, polypropylene, polyamide or polypropylene spheres were dry-blended with polyethylene. The viscosity was determined by means of a slit or a capillary rheometer. The quenched extrudate was annealed and its die swell was measured. Flakes of biaxially oriented polystyrene shrunk into rod-like form during heating, but other plastics retained the flake-form. The relative viscosity and the swell ratio of the suspensions depended on the type of plastic and operating conditions. The rheological behavior of suspensions qualitatively suggested that polypropylene flakes deformed or crowded (including stacking), polyamide flakes deformed slightly, and polystyrene flakes were difficult to buckle, but crowded slightly. The thickness of extrudates can be controlled easily by flake addition due to decreased die swell, while the output would be reduced to some extent. 相似文献
A poly(vinyl alcohol) (PVA) fiber support incorporating various aminoacetal functional groups has been developed for immobilizing enzymes. The aminated PVA fiber seems to adsorb enzymes with electrostatic force of attraction; thus the immobilization procedure is simple. By the use of this fiber having immobilized enzymes, the reaction between enzymes and substrates is nearly independent of the size of subtstrates. This newly developed type of fiber, which is formed by a mass superfine fibers (SFF), each measuring 1 μm or less in diameter, permits much more increased surface area than the conventional enzyme immobilization supports. Our studies of the properties of the fiber for immobilization of enzymes show the following results: (1) SFF has a greater ability for the immobilization of invertase than ordinary fibers; (2) dimethyl-aminated SFF has the best performance for the immobilization of invertase. From these results, it is concluded that the dimethyl-aminated SFF is an excellent support for the immobilization of invertase. 相似文献
Anatase-type TiO2 powder containing sulfur with absorption in the visible region was directly formed as particles with crystallite in the range 15–88 nm by thermal hydrolysis of titanium(III) sulfate (Ti2(SO4)3) solution at 100°–240°C. Because of the presence of ammonium peroxodisulfate ((NH4)2S2O8), the yield of anatase-type TiO2 from Ti2(SO4)3 solution was accelerated, and anatase with fine crystallite was formed. Anatase-type TiO2 doped with ZrO2 up to 9.8 mol% was directly precipitated as nanometer-sized particles from the acidic precursor solutions of Ti2(SO4)3 and zirconium sulfate in the presence and the absence of (NH4)2S2O8 by simultaneous hydrolysis under hydrothermal conditions at 200°C. By doping ZrO2 into TiO2 and with increasing ZrO2 content, the crystallite size of anatase was decreased, and the anatase-to-rutile phase transformation was retarded as much as 200°C. The anatase-type structure of ZrO2-doped TiO2 was maintained after heating at 1000°C for 1 h. The favorable effect of doping ZrO2 to anatase-type TiO2 on the photocatalytic activity was observed. 相似文献