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排序方式: 共有624条查询结果,搜索用时 15 毫秒
551.
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553.
Angeloclaudio Nale Michele Catti Elisa Gil Bardají Maximilian Fichtner 《International Journal of Hydrogen Energy》2011,36(21):13676-13682
The dehydrogenation reaction of the 0.6LiBH4-0.4Mg(BH4)2 eutectic system was investigated by Temperature-Programmed-Desorption and Pressure-Composition-Isotherm methods, in the range of 25–540 °C and 0.1–150 bar of p(H2). A sequence of four decomposition steps was found by TPD measurements; they occur at 235, 315, 365 and 460 °C for p(H2) = 3 bar, with a clear T decrease with respect to pure LiBH4 and Mg(BH4)2. In the PCI experiments, the first two steps could not be resolved but appeared merged in a single process. The amounts of H2 release at each step and the ΔrH and ΔrS values derived from van’t Hoff plots were analyzed and compared with known results for relevant possible reactions. A scheme of interpretation was then proposed for all four processes. In particular, a fraction of LiBH4 and Mg(BH4)2 would react together in the range of 300–350 °C according to 2LiBH4 + Mg(BH4)2 → 2B + 2LiH + MgB2 + 7H2, thus explaining the quite large H2 yield therein observed. The first and fourth steps correspond to decompositions of pure remaining Mg(BH4)2 and LiBH4, respectively, and the third one to dehydrogenation of MgH2 produced in the first step. 相似文献
554.
Raju Prakash Clemens WallAjay Kumar Mishra Christian KübelMohammad Ghafari Horst HahnMaximilian Fichtner 《Journal of power sources》2011,196(14):5936-5944
In an attempt to enhance the energy storage capacity and discharge voltage, a new cathode material based on ferrocene and LiF for lithium-ion batteries has been explored [Fe/LiF/C] nanocomposite (1) has been synthesized by pyrolysis of a ferrocene/LiF mixture at 700 °C using a rotating quartz tube setup in a furnace. The structure and morphology of the composite were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), Brunauer-Emmer-Teller (BET) analysis, Raman, and Mössbauer spectroscopy. The nanocomposite is composed of well-defined nanotubes which are interlinked by graphitic shell-type structures containing uniformly distribution of Fe, Fe-C, and LiF nanoparticles. The binder-free nanocomposite cathode showed enhanced electrochemical performance with the reversible specific capacity of 230 mAh g−1 (1.3-4.3 V) at 20.8 mA g−1 at room temperature. It exhibited a remarkable cyclic stability and good rate capability performances. The morphology of 1 was changed by ball milling, and the resulting nanocomposite 2 did not show any cyclic stability as a cathode. Thus, the cyclic stability and rate capability performances of 1 were attributed to its structure and morphology. 相似文献
555.
On negative differential resistance in hydrodynamic simulation of partially depleted SOI transistors
Polsky B. Penzin O. Sayed K.E. Schenk A. Wettstein A. Fichtner W. 《Electron Devices, IEEE Transactions on》2005,52(4):500-506
We show that the negative differential resistance in the I/sub d/-V/sub ds/ characteristics observed in hydrodynamic transport simulations of partially depleted silicon-on-insulator MOSFETs disappears if the nonlocality of tunneling effects are properly accounted for in the recombination-generation process. 相似文献
556.
An attempt to model the human body as a communication channel 总被引:2,自引:0,他引:2
Wegmueller MS Kuhn A Froehlich J Oberle M Felber N Kuster N Fichtner W 《IEEE transactions on bio-medical engineering》2007,54(10):1851-1857
Using the human body as a transmission medium for electrical signals offers novel data communication in biomedical monitoring systems. In this paper, galvanic coupling is presented as a promising approach for wireless intra-body communication between on-body sensors. The human body is characterized as a transmission medium for electrical current by means of numerical simulations and measurements. Properties of dedicated tissue layers and geometrical body variations are investigated, and different electrodes are compared. The new intra-body communication technology has shown its feasibility in clinical trials. Excellent transmission was achieved between locations on the thorax with a typical signal-to-noise ratio (SNR) of 20 dB while the attenuation increased along the extremities. 相似文献
557.
The dependence of the strain-induced on-current improvement in n-MOSFETs on scaling and the crystallographic orientation of the channel is investigated by self-consistent full-band Monte Carlo simulation. For a channel orientation along the <110> direction, the enhancement decreases weakly from almost 40% to 30% as the effective gate length is reduced from 75 to 25 nm. For the <100> direction, the improvement is about 10% higher. The anisotropy of the drain current, which vanishes for small drain voltages, is attributed to the different band curvatures above 100 meV. This feature appears to be crucial for quasi-ballistic transport of the electrons in the high longitudinal field as they enter the source-side of the channel. 相似文献
558.
Duc Tho Thieu Mohammed Hammad Fawey Harshita Bhatia Thomas Diemant Venkata Sai Kiran Chakravadhanula Rolf Jürgen Behm Christian Kübel Maximilian Fichtner 《Advanced functional materials》2017,27(31)
In the search for novel battery systems with high energy density and low cost, fluoride ion batteries have recently emerged as a further option to store electricity with very high volumetric energy densities. Among metal fluorides, CuF2 is an intriguing candidate for cathode materials due to its high specific capacity and high theoretical conversion potential. Here, the reversibility of CuF2 as a cathode material in the fluoride ion battery system employing a high F? conducting tysonite‐type La0.9Ba0.1F2.9 as an electrolyte and a metallic La as an anode is investigated. For the first time, the reversible conversion mechanism of CuF2 with the corresponding variation in fluorine content is reported on the basis of X‐ray photoelectron spectroscopy measurements and cathode/electrolyte interfacial studies by transmission electron microscopy. Investigation of the anode/electrolyte interface reveals structural variation upon cycling with the formation of intermediate layers consisting of i) hexagonal LaF3 and monoclinic La2O3 phases in the pristine interface; ii) two main phases of distorted orthorhombic LaF3 and monoclinic La2O3 after discharging; and iii) a tetragonal lanthanum oxyfluoride (LaOF) phase after charging. The fading mechanism of the cell capacity upon cycling can be explained by Cu diffusion into the electrolyte and side reactions due to the formation of the LaOF compound. 相似文献
559.
560.
Reducing net cooling demand due to night ventilation through windows. The legal requirements for energy efficiency of buildings are continuously increasing due to climate protection. To meet these requirements, on the one hand, economically feasible efficiency measures are necessary. On the other hand, the improvement of energy efficiency by these measures has to be quantifiable by using standardised methods. This article presents an approach to calculate the reduction of cooling net energy demand in non‐residential buildings due to night ventilation through windows. The calculation procedure can be integrated into the energy balance calculations according to DIN V 18599. Presented are a simplified as well as a variable method. The simplified method is particularly suitable for the legal proof of energy efficiency, since the additional input effort for the user is low. The variable method makes it possible to calculate the energy savings by night ventilation through windows for variable boundary conditions. The calculations are more complex and the input effort for the users is higher, hence this method is particularly suitable for energy consulting or building planning. 相似文献