单塔精馏生产优级品乙酸的研究

用理论计算与实验相结合的办法 ,采用单塔精馏生产优级品乙酸 ,以降低能耗 ,减少物料损失 ,提高产品收率 ,缩短生产周期 ,避免了双塔精馏所造成的设备与能源的浪费。在国内首次成功研究了单塔精馏生产优级品乙酸的生产工艺。     

利用钾盐混合物提高玻璃制品的强度

本文介绍了一种利用钾盐混合物并通过改变钾盐的比例来提高玻璃制品强度的方法。     

微生物转化法合成L-酪氨酸

以对羟基苯甲醛、海因、氢氧化钠为原料 ,化学合成底物对羟基苯丙酮酸。采用来自大肠杆菌的天冬氨酸转氨酶对对羟基苯丙酮酸进行生物转化 ,并对转化条件进行了初步的研究 ,最终得到L-酪氨酸 ,转化率 75 %。     

Electrical properties of (Bi3.5La0.5)Ti3O12 thin-films prepared by liquid source misted chemical deposition

The ((Bi_3.5La_0.5)Ti₃O₁₂(BLT) thin-films used in this study were fabricated on a Pt(111)/SiO₂/Si(100) substrate by a Liquid Source Misted Chemical Deposition (LSMCD) technique. X-ray diffraction patterns showed that the BLT films were crystallized and no other phases were observed when annealed above 650 ‡C. Grain size and remnant polarizations increased with increase in the annealing temperature, while leakage current densities decreased. The remnant polarizations (Pr) increased from 2.0 to 4.8 and 19.0 μC/cm2 with increase in the annealing temperature from 650 to 700 and 750 ‡C, respectively. The BLT films annealed at 700 ‡C in O₂ showed a good fatigue resistance of reduced polarization by 10% after 10⁹ switching cycles when 9 V of bipolar voltage was applied at a frequency of 40 kHz.     

用于确定双吸离心泵Suter曲线的三维内特性法研究

水泵Suter曲线是泵站水锤分析的必备条件之一。现有用于获取双吸离心泵Suter曲线的实测法具有难度大、成本高的特点,而间接插值估算法的精度又比较低,本文提出了一种通过水泵流场三维数值计算确定双吸离心泵Suter曲线的新方法,简称三维内特性法。该方法采用计算流体力学(CFD)技术,对双吸离心泵的水力模型进行三维造型、工况离散、流场计算及结果转化,以快速、准确地获取双吸离心泵Suter曲线,在正水泵工况、正水轮机工况、反水轮机工况、反水泵工况等工况下,计算出相应流量、转速、扬程和转矩关系。定量分析表明,相比于间接插值估算法,采用三维内特性法获得的Suter曲线中,Wh(x)的计算精度平均提高了39.2%,Wb(x)的计算精度平均提高了26.3%;在将采用该方法获得的双吸离心泵Suter曲线用于事故停泵工况水锤分析时,计算得到的系统最大压力降低了15.0%,管线发生汽化压力的范围缩减了81.4%,双吸离心泵的最大倒流量增大了11.9%,最大倒转速降低了6.1%,与实际测试结果更为接近。该方法为提高双吸离心泵站水锤分析精度提供了一种新技术途径。     

涤纶短纤维生产现状及发展趋势

对目前国内外涤纶短纤维生产的企业规模和工艺技术现状进行了分析比较，并论述了涤纶短纤维生产的经济规模和今后的发展趋势。     

聚四氟乙烯改性剂的制备及性能

介绍了隔膜法氯碱所用的聚四氟乙烯改性剂，即聚四氟乙烯乳液、聚四氟乙烯纤维（SM-1）、聚四氟乙烯类纤维（SM-2）的制造原理、制造方法以及在隔膜法氯碱上的应用效果。     

催化剂单螺杆挤条机的设计

为适应催化剂的成型生产,设计了专用的单螺杆挤条机,并阐述该机的工作原理、总体结构、主要零部件的设计及注意事项。     

Measurement and modeling solubility of bioactive coumarin and its derivatives in supercritical carbon dioxide

To design a supercritical fluid extraction process for the separation of bioactive substances from natural products, a quantitative knowledge of phase equilibria between target biosolutes and solvent is necessary. How-ever, mostly no such information is available in literature to date. Thus in the present study, illustratively the solubility of bioactive coumarin and its various derivatives (i.e., hydroxy-, methyl-, and methoxy-derivatives) in supercritical CO₂ were measured at 308.15–328.15 K and 10–30 MPa. Also, the pure physical properties such as normal boiling point, critical constants, acentric factor, molar volume and standard vapor pressure for coumarin and its derivatives were estimated. By these estimated information, the measured solubilities were quantitatively correlated by an approximate lattice equation of state proposed recently by the present authors.     

SMAS/AM/淀粉抗温接枝共聚物的研究

研究了甲基丙烯磺酸钠(SMAS)、丙烯酰胺(AM)与淀粉接枝共聚物的合成方法，接枝反应的影响因素和热稳定性。实验结果表明，该接枝反应基本符合自由基反应的一般规律，并且其聚合产物具有明显的抗高温能力。