Synthesis of novel bisphenol containing phthalazinone and azomethine moieties and thermal properties of cured diamine/bisphenol/DGEBA polymers

A novel bisphenol(1,2-dihydro-2-(4-((4-hydroxy)phenyliminomethylidene)phenyl)-4-(4-((4-(4-hydroxy)phenyliminomethylidene)phenoxy)phenyl)(2H)phthalazin-1-one, DPP) and a diamine(1,2-dihydro-2-(4-aminophenyl)-4-(4-(4-aminophenoxy)phenyl)(2H)phthalazin-1-one, DAP) were synthesized and characterized. The novel epoxy polymers containing phthalazinone and/or azomethine moieties were prepared by binary polymerization of DAP (or DPP) with diglycidyl ether of biphenyl A (DGEBA) and ternary polymerization of hybrid curing agents, DAP/DPP (DAP and DPP under different molar ratios) with DGEBA. The cure behaviors of these new epoxy systems were studied by dynamic differential scanning calorimeter (DSC) and Infrared (IR) scans. Especially, the activation energy of DAP/DGEBA calculated by Kissinger and Ozawa methods were 73.8 and 77.4 kJ/mol, respectively. For ternary epoxy system, it was found that hybrid curing agents of DAP/DPP exhibited significant associated effect on their reactivity towards the oxirane group. Glass transition temperatures (T_g's) of these new epoxy polymers were all above 150 °C from the results of DSC, and the initial thermal decomposition temperatures (T_d,5%'s) and integral procedure decomposition temperatures (IPDT's) of these new epoxy polymers are above 350 and 850 °C, respectively from results of thermogravimetric analyses (TGA). These results show that new epoxy polymers containing phthalazinone and/or azomethine moieties exhibited excellent thermal properties. Especially, thermal properties of the ternary epoxy polymers could be modified by changing the content of DAP and DPP. The linear relationships between char yield (Y_c,wt%) and the structural compositions of these new polymers (weight percentage of phthalazinone, azomethine and nitrogen, C/H weight ratio) were built.     

A porous mixed-valent iron MOF exhibiting the acs net: Synthesis, characterization and sorption behavior of Fe3O(F4BDC)3(H2O)3·(DMF)3.5

A new mixed-valent iron MOF, formulated as Fe₃O(F₄BDC)₃(H₂O)₃·(DMF)_3.5 (1), has been synthesized by using a perfluorinated linear dicarboxylate to link trigonal prismatic Fe₃(μ³-O)(O₂C–)₆ clusters. The structure refinement based on single crystal X-ray diffraction data collected from 1 reveals the material exhibits the acs topology with large channels along the crystallographic c-axis. Due to the presence of fluorine atoms the organic link, 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate (F₄BDC), has a 63° torsion angle between the carboxylate and aromatic planes, resulting in larger channels compared to those in the isoreticular material MOF-235. While few iron-based MOFs have demonstrated porosity, nitrogen and hydrogen sorption experiments carried out at 77 K proved the porosity of outgassed 1, which has a Langmuir surface are of 635 m²/g and a gravimetric capacity of 0.9 wt% of hydrogen at 1 bar.     

提高轻苯产率和降低洗油消耗的措施

通过对粗苯装置设备的改造和优化操作,既解决了设备能力与生产负荷不匹配的问题,又提高了轻苯收率和降低了洗油消耗。     

面向云存储的多副本文件完整性验证方案

文件完整性验证是云存储服务的一项重要安全需求.研究者已经提出多项针对云存储文件完整性验证的机制,例如数据持有性验证(prove of data possession,PDP)或者数据可恢复证明(proof of retrievability,POR)机制.但是,现有方案只能够证明远程云存储持有一份正确的数据,不能检验其是否保存多份冗余存储.在云存储场景中,用户需要验证云存储确实持有一定副本数的正确文件,以防止部分文件意外损坏时无法通过正确的副本进行恢复.提出的多副本文件完整性验证方案,能够帮助用户确定服务器正确持有的文件副本数目,并能够定位出错的文件块位置,从而指导用户进行数据恢复.实验证明,充分利用了多服务器分布式计算的优势,在验证效率上优于单副本验证方案.     

充分发挥橡胶协会的行业自律作用规范复合橡胶进口规范协调市场秩序

随着我国橡胶消耗量的不断增加,天然橡胶价位屡创新高,加上国家对天然橡胶实行高关税等政策因素,使得复合橡胶进口量逐年递增.另一方面,由于缺乏进口复合橡胶质量监控手段,造成复合橡胶品质不一,优劣共存.中国橡胶工业协会为了维护橡胶工业的健康发展,及时组织了行业相关人员,对复合橡胶行业自律进行了研讨,进而制定了"复合橡胶自律规范",并展开对复合橡胶生产和贸易公司进行质量授信、品牌推介等行业自律工作,得到了上下游企业的关注和支持.     

基于CUDA的并行粒子群优化算法研究及实现

应用图形处理器(GPU)来加速粒子群优化(PSO)算法并行计算时,为突出其加速性能,经常有文献以恶化CPU端PSO算法性能为代价。为了科学比较GPU-PSO算法和CPU-PSO算法的性能,提出用"有效加速比"作为算法的性能指标。文中给出的评价方法不需要CPU和GPU端粒子数相同,将GPU并行算法与最优CPU串行算法的性能作比较,以加速收敛到目标精度为准则,在统一计算设备架构(CUDA)下对多个基准测试函数进行了数值仿真实验。结果表明,在GPU上大幅增加粒子数能够加速PSO算法收敛到目标精度,与CPU-PSO相比,获得了10倍以上的"有效加速比"。     

一种新的基于最大边缘准则的监督流形学习方法

在深入研究局部样条嵌入算法(LSE)的基础上,引入明确的线性映射关系,构建平移缩放模型和正交化特征子空间,提出了一种正交局部样条判别投影算法(O-LSDP),有效解决了原始LSE算法存在的两个主要问题:样本外点学习问题和无监督模式学习问题。该算法能够应用于模式分类问题并显著改善算法的分类识别能力。在标准人脸数据库上进行的实验比较分析验证了该算法的有效性与可行性。     

Web交互模型的形式化验证研究

Web交互模型的形式化验证是对Web事件属性进行校验的十分可信的方法。通过一系列的系统模型建立、系统行为分析以及对于模型中关心属性的相关验证,能够让交互模型在设计阶段就能使形式化模型暴露出其所存在的缺陷,而不至于让缺陷保留到编码阶段或者更后面才能被真正地暴露出来,这样使系统模型的生存能力更加强大,同时避免了因后期缺陷暴露而出现的大代价修复。通过对Web系统的交互应用服务的过程模型化的体系进行研究,通过模型本身具有的属性进行相关正确性的校验,主要通过使用数学推理实现系统逻辑上的服务交互进程,从而进行过程的推演,并对系统服务的正确性进行过程的形式化验证,从而使系统服务模块的属性正确性可以通过逻辑上的演进来发现服务问题的存在,而不再是系统通过编码实现后才发现。对Web交互模型的形式化验证是基于IMWSC模型语义形成的IMWSC模型的验证机制。     

具有不同代理群的多代理多签名方案

目前在大多数多代理多签名(multi-proxy multi-signature,MPMS)方案中,所有的原始签名人指定同一个代理群生成代理签名。然而在很多实际应用中,每个原始签名人经常需要在自己所在的组织中选择代理群,从而导致各个原始签名人需要选择不同的代理群,代表自己生成代理签名。现有的多代理多签名方案中还没有考虑这方面的需求。提出一个可以指定不同代理群的MPMS方案。在该方案中,可以指定一个多人的验证群合作验证最终签名的合法性。为证明方案的安全性,对现有的安全模型进行改进,在计算Diffie-Hellman假设的基础上,验证所提方案是安全的。与已有方案相比,本方案更加安全和有效。     

15%恶霉灵防治水稻立枯病药效试验

田间试验表明，15％恶霉灵水剂6～8ml／m^2，对水稻立枯病的防效可达82.3％，病指防效可达89.4％，明显好于对照药剂。而且对水稻安全，能够提高秧苗素质。