Bestimmung der Abtragungsraten von Zirconium,Tantal und der Legierung Tantal-40Niob in fluoridhaltiger azeotroper Salpetersäure mit Hilfe der Radiotracer-Methode

The radiotracer technique as a means to investigate the corrosion of zirconium, tantalum, and a Ta-40Nb alloy in fluoride containing azeotropic nitric acid Zirconium and tantalum as well as the tantalum 40% niobium alloy are of considerable technical importance due to their high corrosion resistance against numerous corrosive media. With respect to corrosion testing in analytically pure azeotropic nitric acid in the temperature range between 20 and 121°C, corrosion rates were determined for zirconium: 7 · 10^?6 to 5 · 10^?4 mm/y, for tantalum: 10^?8 to 4 · 10^?6 mm/y, and for the Ta-40Nb alloy: 2 · 10^?7 to 8 · 10^?6 mm/y [1]. These corrosion rates will be markedly increased by adding small amounts of fluorides or by fluoride impurities. The radiotracer method after neutron activation was applied to determine the corrosion rates in azeotropic fluoride containing nitric acid. Even minute additions of fluorides strongly affect the corrosion resistance of zirconium. In the range between 0.15 and 10 ppm F^? and at a temperature of 108°C, corrosion rates between 5.3 · 10^?3 and 3.1 mm/y were measured. It was impossible to establish a limit for the fluoride concentration, below which the corrosion rate of zirconium will not be adversely influenced. The corrosion rates of tantalum and the Ta-40Nb alloy are considerably increasing above a fluoride concentration of 10 ppm. The highest corrosion rates measured were between 8.4 · 10^?3 mm/y at 50°C/280 ppm F^? and 1.4 · 10^?2 mm/y at 110°C/320 ppm F^?. Within the range of this investigation, the corrosion resistance of tantalum was higher than that of the Ta-40Nb alloy by one order of magnitude. The corrosion resistance of zirconium and tantalum was not influenced by any treatment of the samples before testing.     

A multiple-switch high-voltage DC-DC converter

Series connection of power devices has evolved into a mature technique and is widely applied in HV DC power systems. Static and dynamic voltage balance is ensured by shunting individual devices with dissipative snubbers. The snubber losses become pronounced for increased operating frequencies and adversely affect power density. Capacitive snubbers do not exhibit these disadvantages, but they require a zero-voltage switching mode. Super-resonant power converters facilitate the principle of zero-voltage switching. A high-voltage DC-DC power converter with multiple series-connected devices is proposed. It allows the application of nondissipating snubbers to assist the voltage sharing between the multiple series-connected devices and lowers turnoff losses. Simulation results obtained with a circuit simulator are validated in an experimental power converter operating with two series-connected devices. The behavior of the series connection is examined for MOSFETs and IGBTs by both experimental work with a 2 kW prototype and computer simulation. Applications can be found in traction and heavy industry, where the soft-switching power converter is directly powered from a high-voltage source     

Software-Defined Radio Prospects for Multistandard Mobile Phones

A multitude of existing and evolving cell phone standards, coupled with the need to react quickly to market requirements, is radically changing the system architect's task.Two alternative approaches to classic ASIC-centered and DSP-assisted designs have emerged: reconfigurable architectures and DSP-centered and accelerator-assisted architectures.     

Mixed-Cation Oxide Powders via Resin Intermediates Derived from a Water-Soluble Polymer

Submicrometer powders of complex oxides were prepared via resin intermediates based on a starch type of organic precursor. A commercially available water-soluble starch derivative was (for the first time) used as the organic base for solution synthesis of ceramic powders. Calcination of the charred, fluffy, amorphous resins at a temperature below 600°C for 4 h yielded perovskite powders of Sr-doped LaMnO₃ and Sr-doped La(Fe,Co)O₃. Sr-doped LaCrO₃ needed to be calcined above 750°C to ensure phase purity and to remove organic residue. Due to the low cost of starch derivatives, the process has the potential of being more economical than the commonly used Pechini's type process, which utilizes citric acid and ethylene glycol.     

Vision assistance in scenes with extreme contrast

The performance and architecture of a high dynamic range camera (HDRC) chip and the conceptional advantages for its adaptation to image processing systems in traffic environments are discussed. The HDRC chip was developed with 64×64 pixels using a standard digital 1.2-μm CMOS technology. It is shown that the implementation proves the functionality and indicates the system performance of a highly dynamic range camera is feasible     

Anaemia in juvenile chronic arthritis

Brush border myosin-I (BBMI) is a single-headed unconventional myosin found in the microvilli of intestinal epithelial cells, where it links the core bundle of actin filaments to the plasma membrane. An association of BBMI with anionic phospholipids has been shown to be mediated by a carboxy-terminal domain which is rich in basic amino acids. We have exploited this natural affinity of BBMI for negatively charged lipids to form two-dimensional (2D) crystals of this protein which are suitable for structural analysis by electron crystallographic techniques. The 2D crystals which we have obtained belong to one of two space groups, p22121 or p2. We present here projection maps calculated from images of negatively stained crystals for each of these crystal types to a resolution of 20 A and show that the asymmetric unit is the same in both crystal types.     

Evaluation of hot hardness and creep of a 350 grade commercial maraging steel

The hardening response and the indentation creep of a 350 grade commercial maraging steel were evaluated using a hot hardness tester. The hardness versus temperature plot exhibited three distinct regions. Hardness response was noted between 500–800 K. The unusually high values of activation energy and stress exponent obtained during the creep experiment could be rationalized by a novel concept of introducing a back stress term in the indentation creep relation. The corrected value of the activation energy was found to be reasonably in agreement with the activation energy for diffusion of Ni in iron. Results are supplemented with microstructural observation.     

Using two factor structures of the Mental Adjustment to Cancer (MAC) scale for assessing adaptation to breast cancer

The validity and reliability of two factor structures of the Mental Adjustment to Cancer (MAC) scale for assessing coping style was assessed by examining the relationship between the subscales, psychological distress, and quality of life (QOL) among Stage II and Stage IV breast cancer patients in four phases. First, MANOVAs assessed differences in coping, distress, and QOL across disease stages. Second, for each MAC factor structure, canonical correlation analyses assessed the relationship between coping styles, distress, and QOL, for each disease-stage group separately. Third, structural equation modeling (SEM) assessed the relationship among coping styles, distress, and QOL for all participants. Finally, the internal consistency of both MAC factor structures was assessed using Chronbach's alpha. The results were as follows: (1) significant differences across disease stages were found for coping styles using either the Watson or the Schwartz MAC subscales, but there were no differences in levels of distress or QOL; (2) for both MAC factor structures, coping style was found to be highly related to emotional distress and QOL, however, the strengths of the correlations between individual coping styles and distress/QOL indicators varied across disease stages; (3) SEM indicated that coping style was significantly related to distress and QOL when stage of disease was not considered, and that coping style and indicators of distress/QOL are separate, but highly correlated factors, as opposed to a single latent construct; and, (4) the Watson MAC subscales showed slightly better internal consistency than the Schwartz MAC subscales. Taken together, these findings highlight: (i) the validity of both MAC factor structures for clinical and research use with American breast cancer patients; (ii) the role of coping style as a mediator between disease stage and psychological distress and QOL; and, (iii) the need for refinement of certain Watson and Schwartz subscales.