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991.
通过Mo丝高温电阻炉采用正交实验法研究了LF精炼渣系(/%:28.75~58.05CaO、12.50~32.43Al2O3、0~15BaO、8~20SiO2、6MgO、10CaF2)的成分对高碳铬轴承钢GCr15(/%:0.99C、1.45Cr、0.034S)脱硫的影响。结果表明,当(CaO)/(Al2O3)=2.5,(SiO2)=14%,(BaO)由0增至8%时,精炼渣对钢液的脱硫率增加,(BaO)由8%增至15%时脱硫率降低;当(BaO)=7.5%,(SiO2)=14%时,随(CaO)/(Al2O3)增加,精炼渣的脱硫率增加;当(BaO)=7.5%,(CaO)/(Al2O3)=2.5时,随(SiO2)增加,精炼渣的脱硫率降低。钢液最佳脱硫效果的LF精炼渣组成为:6%~10%(BaO),3.5~4.0(CaO)/(Al2O3),8%~12%SiO2。 相似文献
992.
993.
This paper presents a novel method for fabricating an ordered array of metallic nanoshells with a controllable shape by a combination of a porous polymer template and a nanocrystal-seeded electroless plating technique. The morphology of hollow particles has a strong dependence on the seed-deposition time onto the surfaces of the original colloidal template. Using this method, ordered Pt nanobowls (bowl-shaped shells) and, alternatively, nanocups (cup-shaped shells) are prepared. These materials show some intriguing properties: (i) reduced symmetry of the building blocks; (ii) a well-ordered structure; and (iii) a high ratio of surface area to volume, all of which are useful in many areas such as catalysts, sensors, and photonic crystals. 相似文献
994.
A simple, productive and low-cost route has been developed to synthesize multi-armed CdTe nanorods using myristic acid (MA) as a complex agent. The yield of this approach can reach 75%. The dimension of the multi-armed nanorods can be controlled by tuning the molar ratios of Cd/Te and Cd/MA; the diameter can be changed from 2 to?7?nm while the length from 15 to 60?nm. The hexagonal structure was confirmed in x-ray diffraction analysis. However, it was assumed that one crystal is composed of the dominant hexagonal structure along with a cubic structure in the core. 相似文献
995.
This work considers the propagation of shear horizontal (SH) waves in a bilayer system consisting of a piezoelectric (PE) layer and a piezomagnetic (PM) substrate. The interface between the PE layer and the PM substrate is imperfectly bonded. The surfaces of the bilayer system are free of traction, electrically shorted or open and magnetically open or shorted. The exact dispersion equations are derived. The numerical examples are given to illustrate the effects of the electromagnetic boundary conditions, the imperfect interface, the different PE layers and the thickness ratio on the dispersion behaviors. It is found that (a) the electrical boundary conditions dominate the propagation characteristics of SH waves; (b) the imperfect bonding lowers the phase velocities; (c) the thickness ratio and the properties of PE layers have a significant effect on the dispersion behaviors. The obtained results provide a predictable and theoretical basis for applications of PE–PM composites to acoustic wave devices. 相似文献
996.
Gong Q Wang J Ahmad KM Csordas AT Zhou J Nie J Stewart R Thomson JA Rossi JJ Soh HT 《Analytical chemistry》2012,84(12):5365-5371
Many analytical techniques benefit greatly from the use of affinity reagent pairs, wherein each reagent recognizes a discrete binding site on a target. For example, antibody pairs have been widely used to dramatically increase the specificity of enzyme linked immunosorbent assays (ELISA). Nucleic acid-based aptamers offer many advantageous features relative to protein-based affinity reagents, including well-established chemical synthesis, thermostability, and low production cost. However, the generation of suitable aptamer pairs has posed a significant challenge, and few such pairs have been reported to date. To address this important challenge, we present multivalent aptamer isolation systematic evolution of ligands by exponential enrichment (MAI-SELEX), a technique designed for the efficient selection of aptamer pairs. In contrast to conventional selection methods, our method utilizes two selection modules to generate separate aptamer pools that recognize distinct binding sites on a single target. Using MAI-SELEX, we have isolated two groups of 2'-fluoro-modified RNA aptamers that specifically recognize the αV or β3 subunits of integrin αVβ3. These aptamers exhibit low nanomolar affinities for their targets, with minimal cross-reactivity to other closely related integrin homologues. Moreover, we show that these aptamer pairs do not interfere with each other's binding and effectively detect the target even in complex mixtures such as undiluted serum. 相似文献
997.
In this study, we have used PEO (plasma electrolytic oxidation) for the production of oxide coatings on a Ti–6Al–4V alloy at two different current modes, namely pulsed unipolar and bipolar. Optical emission spectroscopy (OES) in the visible and near UV band (280–800 nm) was used to characterize the PEO plasma. The emission spectra were recorded and the plasma temperature profile versus processing time was constructed using a line intensity ratios method. The aim of this work was to study the effect of the process parameters, including current mode and pulse duration time, on the plasma characteristics, surface morphology and microstructure and corrosion resistance of oxides grown on Ti–6Al–4V by PEO process. Scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDS) and X-ray diffraction (XRD) were used to study the coating microstructure, morphology and phase composition. The corrosion resistance of the coated and uncoated samples was examined by potentiodynamic polarization in a 3.5% NaCl solution. It was found that the plasma temperature profiles are significantly influenced by changing the current mode from unipolar to bipolar. The strongest discharges that are initiated at the interface between the substrate and the coating can be reduced or eliminated by using a bipolar current mode. This produces a thinner, denser and more corrosion-resistant coating. 相似文献
998.
M. Guo X. Wang H.M. Zhou L. Li F.L. Nie Y. Cheng Y.F. Zheng 《Materials science & engineering. C, Materials for biological applications》2012,32(4):909-915
Porous silver scaffolds, with the porosity ranging from 68% to 81% and the apparent density ranging from 0.4 to 1 g?cm? 3 were prepared by electroplating method using cellular carbon skeleton as the substrate. The microstructure, mechanical property, cytotoxicity and antibacterial activity of the prepared porous silver scaffold were studied. The present porous silver scaffolds had a highly three-dimensional trabecular porous structure with the porosity and the apparent density close to that of the cancellous bone. Furthermore, the mechanical property such as elastic modulus and yield strength of the porous silver scaffolds were lower than that of commercial available porous Ti and porous Ti alloys but much closer to that of the cancellous bone and porous Ta. In addition, study of in vitro behavior showed that the porous silver scaffold possessed significant antibacterial capability of inhibition of bacterial proliferation and adherence against Staphylococcus aureus and Staphylococcus epidermidis, and little cytotoxicity to Mg-63 cell line and NIH-3T3 cell line. Consequently, the porous silver scaffolds prepared by electrodeposition possess a promising application for bone implants. 相似文献
999.
Songlin Nie Jiandong Wen Yongping Li Xionghui Tang Guohe Huang 《Optimization and Engineering》2012,13(2):319-347
A fuzzy robust nonlinear programming model is developed for the assessment of filter allocation and replacement strategies in hydraulic systems under uncertainty. It integrates the methods of fuzzy mathematic programming (FMP) and robust programming (RP) within the mixed integer nonlinear programming framework, and can facilitate dynamic analysis and optimization of filters allocation and replacement planning where the uncertainties are expressed as fuzzy membership functions. In modeling formulation, theory of contamination wear of typical hydraulic components is introduced to strengthen the presentation of relationship between system contamination and work performance. The fuzzy decision space is delimited into a more robust one by specifying the uncertainties through dimensional enlargement of the original fuzzy constraints. The piecewise linearization approach is employed to handle the nonlinearities of problem. The developed method has been applied to a case of planning filter allocation and replacement strategies under uncertainty and the generated optimal solution will help to reduce the total system cost and failure-risk level of the FPS. 相似文献
1000.
Han S Liu Y Nie X Xu Q Jiao F Li W Zhao Y Wu Y Chen C 《Small (Weinheim an der Bergstrasse, Germany)》2012,8(10):1596-1606
The use of biodegradable polymeric nanoparticles (NPs) for controlled drug delivery has shown significant therapeutic potential. Polyaspartic acid and polylactic acid are the most intensively studied biodegradable polymers. In the present study, novel amphiphilic biodegradable co-polymer NPs, poly(L-aspartic acid-co-lactic acid) with 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine (DPPE) (poly(AA-co-LA)/DPPE) is synthesized and subsequently used to encapsulate an antitumor drug doxorubicin (DOX). The formulation parameters of the NPs are optimized to improve encapsulation efficiency. The resulting drug-loaded NPs possess better size homogeneity (polydispersity) and exhibit pH-responsive drug release profiles. Cellular viability assays indicate that the poly(AA-co-LA)/DPPE NPs did not induce cell death, whereas doxorubicin encapsulated NPs were cytotoxic to various types of tumor cells. In addition, the free NPs could not enter the cell nuclei after internalized in tumor cells. The DOX-loaded NPs exhibit efficient intracellular delivery in tumor cells with co-localization in lysosome and delay entering into the nucleus, which suggests a time- and pH-dependent drug release profile within cells. When applied to deliver chemotherapeutics to a mouse xenograft model of human lung adenocarcinoma, DOX-loaded NPs have a comparable antitumor activity with free DOX, and greatly reduce systemic toxicity and mortality. The delivery of cytotoxic drugs directly to the nucleus specifically within tumor cells is of great interest. These results demonstrate the feasibility of the application of the amphiphilic polyaspartic acid derivative, poly(AA-co-LA)/DPPE, as a nanocarrier for cell nuclear delivery of potent antitumor drugs. 相似文献