A 1-V integrated current-mode boost converter in standard 3.3/5-V CMOS technologies

A 1-V integrated CMOS current-mode boost converter implemented in a standard 3.3/5-V 0.6-/spl mu/m CMOS technology (V/sub TH//spl ap/0.85 V), providing power-conversion efficiency of higher than 85% at 100-mA output current, is presented in this paper. The high-performance boost converter is successfully developed due to three proposed low-voltage circuit structures, including an inductor-current sensing circuit for current-mode operation with accuracy of higher than 94%, a precision V-I converter for compensation-ramp generation in current-mode control, and a VCO providing supply-independent clock and ramp signals. Moreover, a proposed startup circuit enables proper converter startup within a sub-1-V supply condition.     

Product-centered processing: Manufacture of chemical-based consumer products

A systematic framework for product-centered processing is useful particularly in developing chemical-based consumer product manufacturing processes. The objective is to provide directions and guidelines toward the development of a process for manufacturing a product with the desired performance in reduced time and effort. The product performance, represented by several quality factors, is related to product ingredients and structural attributes, as well as the process flowsheet and operating conditions. The procedure consists of five steps. First, the product functionality, form, and packaging are defined. Second, relevant quality factors are identified. Third, necessary ingredients are selected and product microstructure is determined. Fourth, the manufacturing process is designed in light of the desired product properties. Limitations on achievable product quality are also identified. Finally, the product and process are evaluated with the help of experimental data. The framework is illustrated using industrial examples, including the production of dry toner, laundry detergent, shampoo, and cosmetic lotion.     

Visualization of high-dimensional phase diagrams of molecular and ionic mixtures

A general method for visualizing high-dimensional phase diagrams of systems containing a mixture of molecular and ionic species is presented. Based on geometric modeling with homogeneous coordinates, canonical coordinates are developed to represent cuts and projections, which, being reaction-invariant, do not depend on the degree of ionization. Examples are provided to illustrate the application of this method for identifying useful transforms with potential applications in separation system synthesis.     

Literatur

European Food Research and Technology -     

Impact of Solvent Additive on Carrier Transport in Polymer:Fullerene Bulk Heterojunction Photovoltaic Cells

The effects of a solvent additive, 1,8‐diiodooctane (DIO), on both hole and electron transport are investigated in a state‐of‐the‐art bulk‐heterojunction (BHJ) system, namely PTB7:PC₇₁BM. For a polymer:fullerene weight ratio of 1:1.5, the electron mobility in the blend film increases by two orders of magnitude with the DIO concentration while almost no change is found in the hole mobility. For lower DIO concentrations, the electron mobility is suppressed because of large, but poorly connected PC₇₁BM domains. For higher concentrations of DIO, the electron mobility is improved progressively and the hole mobility becomes the limiting factor. Between 1 and 5 vol%, the electron and hole mobilities are balanced. Using the Gaussian disorder model (GDM), we found that the DIO concentration modifies fundamentally the average hopping distances of the electrons. In addition, there exist alternative donor–acceptor ratios to achieve optimized PTB7:PC₇₁BM based solar cells. It is demonstrated that the fullerene content of the BHJ film can be significantly reduced from 1:1.5 to 1:1 while the optimized performance can still be preserved.     

Predicting Marangoni convection caused by transient gas diffusion in liquids

The onset of convection driven by surface tension during gas diffusion in a liquid is investigated. Gas diffusion at the gas-liquid interface results in the variation of concentration of the solute that may cause an increase in surface tension leading to Marangoni convection. The onset of convection for unsteady-state gas desorption can be predicted from the maximum transient Ma_t, which is here derived by analogy with its equivalent in thermal convection. It is a function of the transient Biot number (Bi_D) for interfacial gas diffusion, which depends strongly on the state of vapour-liquid equilibrium at the interface. The transient Marangoni numbers, critical times for stable mass diffusion and the critical sizes of convection cells have been formulated. The desorption of ethyl-ether from chloro-benzene in L.M. Blair’s [The onset of cellular convection in a fluid layer with time-dependent density gradients, PhD thesis, University of Illinois, Urbana, 1968] experiments is liquid phase-controlled, hence, the highly soluble system is characterized by Bi_D = 0. Therefore, his experiments that were initiated with a step-change in pressure cannot be analyzed by a step-function boundary that is characterized by Bi_D = ∞. The surface concentration may change very slowly, it has been approximated to be about 0.1% of the initial pressure change at the point of onset of convection. The average critical Marangoni number for this condition was estimated to be 53.3, which is fairly close to the theoretical value of 67 for an interface with a Biot number of 0. Therefore, the high value of 3100 calculated by I.F. Davenport and C.J. King [The initiation of natural convection caused by time-dependent profiles, Lawrence Berkeley Lab, Report NBR LBL-600, 1972] is wrong, who wrongly assumed a fixed surface-concentration boundary that is applicable only to a sparingly soluble solute. The critical sizes of convection cells predicted by theory are generally less than 1 mm for reported critical times of less than 20 s, they would be difficult to measure.     

Study of rotational temperature of oxygen molecules in H and T forms of DC glow discharge sustained in pure oxygen

The active DC glow discharge sustained in pure oxygen has been studied in a Silica discharge tube by means of optical emission spectroscopy and double-probe diagnostics for pressures 600, 750 and 1000 Pa and for discharge currents up to 40 mA. Two different forms of positive column of the discharge (high-gradient H form and low-gradient T form) were observed. Our investigation was focused on the variations of the rotational temperature T_rot determined from emission spectra of molecular oxygen (atmospheric A-band at 760 nm) in the dependence on the discharge current and on the pressure with respect to the existence of the two forms of the discharge. An increase of the rotational temperature with increasing discharge current has been observed. Moreover, higher values of T_rot were found in the H form compared with the T form.     

Intracellularly Degradable Hydrogen‐Bonded Polymer Capsules

The assembly of low‐fouling polymer capsules with redox‐responsive behavior and intracellular degradability is reported. Thiol‐containing poly(2‐ethyl‐2‐oxazoline) (PEtOxMA_SH) brushes are synthesized by atom transfer radical polymerization (ATRP) of oligo(2‐ethyl‐2‐oxazoline)methacrylate and glycidyl methacrylate (GMA) and subsequent ring‐opening reaction of the GMA. Sequential deposition of PEtOxMA_SH/poly(methacrylic acid) (PMA) multilayers onto silica (SiO₂) particle templates and crosslinking through disulfide formation yield stable capsules after the removal of the SiO₂ templates by buffered hydrofluoric acid (HF). The redox‐responsive nature of the disulfide crosslinking groups enables the degradation of these capsules under simulated intracellular conditions at pH 5.9 and 5 mm glutathione (GSH). Furthermore, capsule degradation is observed after incubation with dendritic (JAWS II) cells. Even at high capsule‐to‐cell ratios, PEtOxMA_SH capsules show only negligible cytotoxicity. Quartz crystal microgravimetry (QCM) studies, using 100% human serum, reveal that films prepared from PEtOxMA_SH exhibit low‐fouling properties. The degradation and low‐fouling properties are promising for application of PEtOxMA_SH films/capsules for the delivery and triggered release of therapeutics.     

An object-oriented framework for developing distributed manufacturing architectures

Management of complexity, changes and disturbances is one of the key issues of production today. Distributed, agent-based structures represent viable alternatives to hierarchical systems provided with reactive/proactive capabilities. In the paper, approaches to distributed manufacturing architectures are surveyed, and their fundamental features are highlighted, together with the main questions to be answered while designing new structures. Moreover, an object-oriented simulation framework for development and evaluation of multi-agent manufacturing architectures is introduced.