Thermodynamic measurement and modeling of hydrate dissociation for CO2/refrigerant + sucrose/fructose/glucose solutions

Hydrate dissociation conditions were studied for the CO₂/refrigerant + sucrose/fructose/glucose solution systems as a continuation of previous work into alternate separation technologies for the sugar manufacturing industries. Experimental data were measured following the isochoric pressure method for the CO₂ + sucrose/fructose solution systems. The refrigerants studied for the modeling purpose were R410a, R507, R134a, and R22 using literature data. The pressure and temperature ranges for the experimental data measured here were (1.80–4.10) MPa and (276.6–282.6) K, respectively, with solutions measured in the composition range between 0 to 0.40 mass fraction sucrose and fructose. Several models following the Van der Waals–Platteeuw solid solution theory were developed to predict the hydrate dissociation conditions of CO₂/fluorinated refrigerant in the presence of sucrose/fructose/glucose solutions. The modeling results provide a satisfactory representation of the experimental data, with AARD(P) % model errors in the overall range between 0.03% and 4.40%.     

Intracycle RPM control for vertical axis wind turbines

The wind energy market is currently dominated by horizontal axis wind turbines (HAWTs); however, vertical axis wind turbines (VAWTs) are emerging as a design alternative, especially for deep-water offshore siting due to their low center of gravity, ease of access to drivetrain components, and overall simplicity. Due to the absence of a pitch mechanism in large-scale Darrieus VAWTs, stall control has often been used to manage power and loads. Introducing a pitching mechanism in H-type VAWTs has been studied, but this diminishes the mechanical simplicity advantage, and the use of a pitching mechanism in a large-scale Darrieus-type VAWT is not practical. This work examines an innovative, alternative method to control the rotor dynamics of a large-scale 5 MW VAWT to maximize power while constraining loads without introducing any new or complex mechanical elements. This control strategy is termed intracycle revolution per minute (RPM) control, where the rotational speed of the turbine is allowed to vary in an optimal fashion with the azimuthal location of blades as opposed to typical constant RPM operation. An optimization framework is formulated for an open-loop optimal control problem and solved to maximize power subject to constraints on aerodynamic design loads. Results are presented to demonstrate the benefits and the performance limits of intracycle RPM control for large-scale 5 MW Darrieus VAWTs, namely, (1) power production (quantified in terms of AEP) that can be increased subject to baseline load limits and (2) opportunities to significantly increase AEP or decrease loads via intracycle RPM control that are examined for both two-bladed and three-bladed VAWTs.     

Structural and magnetic properties of NiFe2−xBixO4 (x = 0, 0.1, 0.15) nanoparticles prepared via sol-gel method

NiFe_2−xBi_xO₄ (x = 0, 0.1, 0.15) nanopowders were synthesized via sol-gel method. The precursor gels were calcined at 773 K in air for 1 h to obtain the pure nanostructured NiFe_2−xBi_xO₄ spinel phase. The crystal structure and magnetic properties of the substituted spinel series of NiFe_2−xBi_xO₄ have been investigated by means of ⁵⁷Fe Mössbauer spectroscopy, transmission electron microscopy and alternating gradient force magnetometry. Mössbauer spectroscopic measurements revealed that Bi³⁺ cations tend to occupy octahedral positions in the structure of the substituted ferrite, i.e., the crystal-chemical formula of the as-prepared nanoparticles may be written as: (Fe)[NiFe_1−xBi_x]O₄ (x = 0, 0.1, 0.15), where parentheses and square brackets enclose cations on sites of tetrahedral and octahedral coordination, respectively. Selective area electron diffraction studies provided evidence that the samples of the NiFe_2−xBi_xO₄ series, independently of x, exhibit the cubic spinel structure. The values of the saturation magnetization and the coercive field of NiFe_2−xBi_xO₄ nanoparticles were found to decrease with increasing degree of bismuth substitution.     

Dark oxidation of dissolved and liquid elemental mercury in aquatic environments

Elemental mercury (Hg0) can be found in liquid or dissolved forms in aquatic systems. Whereas dissolved Hg0 is measured in virtually all aquatic systems, liquid Hg0 droplets are mainly observed at poorly lit sediment/water interfaces of ecosystems with local point sources such as hydro-thermal vents, gold extraction sites, and near industrial facilities. Here, we report that, in the dark, liquid and dissolved forms of Hg behave differently with respect to their oxidation. Liquid Hg0 is rapidly oxidized in oxygenated solution in the presence of chloride. Liquid Hg0 oxidation rates are positively correlated with chloride concentrations and droplet surface area. When liquid Hg is removed from solution, the oxidation stops even though the solution is still saturated with dissolved Hg0. Liquid Hg0 droplets in oxygenated marine or brackish environments should be oxidized and release Hg2+ to solution. In freshwaters or anoxic seawater, liquid Hg will dissolve releasing Hg(aq)0 which, itself, will slowly oxidize.     

Hydrogel Encapsulation of Mesenchymal Stem Cells and Their Derived Exosomes for Tissue Engineering

Tissue engineering has been an inveterate area in the field of regenerative medicine for several decades. However, there remains limitations to engineer and regenerate tissues. Targeted therapies using cell-encapsulated hydrogels, such as mesenchymal stem cells (MSCs), are capable of reducing inflammation and increasing the regenerative potential in several tissues. In addition, the use of MSC-derived nano-scale secretions (i.e., exosomes) has been promising. Exosomes originate from the multivesicular division of cells and have high therapeutic potential, yet neither self-replicate nor cause auto-immune reactions to the host. To maintain their biological activity and allow a controlled release, these paracrine factors can be encapsulated in biomaterials. Among the different types of biomaterials in which exosome infusion is exploited, hydrogels have proven to be the most user-friendly, economical, and accessible material. In this paper, we highlight the importance of MSCs and MSC-derived exosomes in tissue engineering and the different biomaterial strategies used in fabricating exosome-based biomaterials, to facilitate hard and soft tissue engineering.     

Surface Structure Formation in Direct Chill (DC) Casting of Al Alloys

The aim of this study is to increase the understanding of the surface zone formation during direct chill (DC) casting of aluminum billets produced by the air slip technology. The depth of the shell zone, with compositions deviating from the bulk, is of large importance for the subsequent extrusion productivity and quality of final products. The surface microstructures of 6060 and 6005 aluminum alloys in three different surface appearances—defect free, wavy surface, and spot defects—were studied. The surface microstructures and outer appearance, segregation depth, and phase formation were investigated for the mentioned cases. The results were discussed and explained based on the exudation of liquid metal through the mushy zone and the fact that the exudated liquid is contained within a surface oxide skin. Outward solidification in the surface layer was quantitatively analyzed, and the oxide skin movements explained meniscus line formation. Phases forming at different positions in the segregation zone were analyzed and coupled to a cellular solidification in the exudated layer.     

The non-stationary response of flexible pavements to moving loads

In this paper, the pavement surface deterioration is investigated based on field measurements of surface roughness profiles obtained in Sweden. A predictive function for surface deterioration, based on average gradient of yearly measurements of the road surface profile in Swedish road network, is proposed. In order to characterise the dynamic loads induced on the pavement by moving traffic a quarter car model is used. Afterwards a non-stationary stochastic approach is used to obtain the yearly response of the pavement to moving loads. The solution is in frequency–wavenumber domain and is given for a non-stationary random case as the pavement surface deteriorates in pavement service life thus influencing the magnitude of the dynamic loads induced by the vehicles. The effect of pavement surface evolution on the stress state induced in the pavement by moving traffic is examined for a specific case of quarter car model and pavement structure. The results showed approximately a 100% increase in the dynamic component of stresses induced in the pavement.     

Navigation your way: from spontaneous independent exploration to dynamic social journeys

In this article, we describe a novel approach to pedestrian navigation using bearing-based haptic feedback. People are guided in the general direction of their destination via a minimal directional cue, but additional exploration is stimulated by varying feedback based on the potential for taking alternative routes. This extreme navigation method removes the complexities of maps and direction following, concentrating on allowing pedestrians to actively explore their surroundings, rather than offering perfect, but passive, turn-by-turn guidance. We simulate and build two mobile prototypes to examine the possible benefits of this approach, then further extend its impact by considering how social media might be incorporated to provide a real-time, dynamically evolving map of physical locations. The successful use of our mobile prototypes is demonstrated in a realistic field trial, and we discuss the results and interesting participant behaviours that were recorded, validating the predictions from their earlier simulation. We continue by simulating the use of publicly posted status updates and pictures as a proxy for location mapping, showing how these methods can produce comparable navigation results to real-world field trials, highlighting their potential as tools for real-world social journeys.     

Performance Evaluation of Agricultural Surface Water Distribution Systems Based on Water-food-energy Nexus and Using AHP-Entropy-WASPAS Technique

This study aimed to quantitatively evaluate the performance of practical alternatives in modernization projects of water distribution in irrigation networks based on the water-food-energy nexus using the AHP-Entropy-WASPAS technique. Three methods of improved manual operation, decentralized automatic operation, and centralized automatic operation were developed under normal and water shortage operation scenarios and modeling the current status of water distribution in the main canal of the Rudasht irrigation network as a case study. Water-based, energy-based and food-based indicators were used to develop the nexus evaluation framework. The results showed that the average values of the water-food-energy nexus index in the manual operation method were estimated at 0.49 and 0.16 under normal and water shortage operation scenarios, respectively. These average values were estimated at 0.53 and 0.17 under normal and water shortage operation scenarios, respectively, by improving the method to the improved manual operation method. The decentralized automatic operation method improved these average values to 0.82 and 0.39 under normal and water shortage operation scenarios. Finally, using the centralized automatic operation method, these average values were 0.94 and 0.35 under normal and water shortage operation scenarios. Since the downstream secondary off-takes of the irrigation network receive no water even by upgrading the surface water distribution system to the decentralized automatic operation method under the water shortage operation scenario, it can be said that the performance of the centralized automatic operation method is more efficient than the decentralized automatic operation method due to the fair and uniform distribution of water in both normal and water shortage scenarios.