2000年以来发布的有关暖通空调专业的部分国家标准和行业标准

列出了2000年以来发布的部分供暖供热、空调制冷、节能、通风除尘、洁净技术、计算机及网络技术、防火排烟、给水排水、减振降噪、环境保护、室内空气品质、材料与设备等标准．以及有关设计、验收规范和一些综合类标准。     

Decomposition of hydriodic acid by electrolysis in the thermochemical water sulfur–iodine splitting cycle

Although several technologies, such as reactive distillation and catalytic membrane reactor, have been proposed to improve HI conversion efficiency, they still experience several challenges for the application in HI section. In this study, an electrochemical cell was employed for hydriodic acid decomposition under the presence of iodine. Several commercial proton-exchange membranes (PEMs), namely, Nafion 117 and Nafion 115, were used as separators for the electrochemical cell. Anodization of iodide anion occurred at the graphite electrode in the anode compartment. Hydrogen was generated by the reduction reaction of hydrogen cations, which migrated from anolyte to catholyte. In electrolysis experiments, PEM showed good performance in terms of high transport number of proton and low iodine permeation. Several parameters, such as operating temperature, HI molarity, and I₂ molarity in anolyte, which affected current efficiency, iodine permeance, and electric resistance of test cell, were investigated. High operating temperature and I₂ molarity in anolyte enhanced the permeability of iodine, which had several negative influences on electrochemical cell performance. Although current efficiency was negatively affected by increasing temperature and I₂ molarity, it still remained above 0.85 in the range of 30 °C–75 °C. Ohmic resistance, which is a component of cell resistance, offered by PEM was investigated with Nafion 117 and 115. Apart from graphite plates, activated carbon papers were adopted as electrodes to reduce the overpotentials due to their high specific surface characteristic.     

陶瓷涂层断裂韧性的表征

由于陶瓷本身的脆性,陶瓷涂层的应用受到了极大的制约。断裂韧性是反映材料抵抗裂纹失稳扩展能力的力学性能指标,陶瓷涂层因为脆性和低维特点,对其断裂韧性的表征存在较大困难,目前主要有临界应力强度因子KⅠC、临界裂纹扩展能量释放率GⅠC和裂纹密度β三种表征方法。本文对上述方法进行了总结、分析。     

Effect of carbonization temperature on the grindability of carbonaceous material produced from different coals

Carbonization experiments were conducted on four kinds of sub‐bituminous coal particles at a temperature range of 450–1200 °C. The effect of treating temperature on the grindability of produced carbonaceous materials was investigated, and its mechanism was analyzed through various means. Results show that the grindability of all coals, whether caking or slightly‐caking, exhibit the same variation trend with an increase in carbonization temperature. Moreover, the entire process can be divided into four stages. (1) After the most intense devolatilization stage, the grindability of carbonaceous material exhibited different degrees of increase compared with that of raw coal because of the development of a pore structure. (2) The first significant decrease in the grindability occurred from the plastic stage to the complete resolidification of the coal matrix. (3) After the aromatic polycondensation stage accompanied by a large amount of H₂ release, the coal molecular structure became compact, such that the grindability of semi‐coke considerably decreased again. (4) At high temperatures, the coal matrix underwent graphitization, which changed semi‐coke to coke. The molecular structure of coal became ordered, and the grindability decreased again. The analysis shows that a change in the internal chemical structure of carbonaceous material has a much more pronounced effect on grindability than a change in its pore structure, except in the first stage. The constant compaction and regularization of the coal molecular structure continued happening throughout the entire process and play a decisive role in the change in grindability.     

自交联型水性聚丙烯酸酯分散体的制备及其性能

以甲基丙烯酸甲酯(MMA)为硬单体、丙烯酸丁酯(BA)为软单体、丙烯酸(AA)为功能单体、甲基丙烯酸乙酰乙酰氧基乙酯(AAEM)为交联单体、过氧化苯甲酸叔丁酯为引发剂、乙二醇丁醚为溶剂,通过自由基溶液聚合经转相方式制备了自交联型丙烯酸酯分散体,该分散体在烘烤条件下不需要外加交联剂即可发生自交联反应.研究了丙烯酸、甲基丙...     

中条山胡—蓖型铜矿床成因新认识

讨论了剥离断层与成矿物质来源,矿体空间分布型式以及矿化特征等方面联系,从而提出胡-蓖型铜矿床是一个受剥离断层控制的“热液型(断)层状矿床”。     

油漆车间电泳灰粒控制及改进

从油漆车间电泳灰粒产生的源头着手,在白车身洁净度、前处理工艺和电泳工艺三方面对电泳灰粒潜在的影响进行分析。通过对电泳工艺段的主槽循环进行改进,调整出槽喷淋压力,以及改造湿打磨,有效控制了电泳成膜后的灰粒数量,使电泳打磨灰粒数量下降75%,油漆整体外观质量得到提高。     

Sm掺杂BaTiO3纳米粉体的制备与表征

以钛酸四丁酯与醋酸钡为钛酸钡前驱体,PEG为分散剂,硝酸钐为掺杂物种给体,采用溶胶-凝胶法制备改性的Sm掺杂BaTiO3纳米粉体。样品经X射线衍射(XRD)与差热-热重联用(DSC-TGA)的方法对其进行了表征。研究了煅烧温度与分散剂对BaTiO3粉体粒径与相的影响。结果表明:立方相在700～850℃生成,前驱体经950℃热处理制得后呈四方相BaTiO3。分散剂PEG可抑制BaTiO3晶粒增长;随煅烧温度升高,粉体粒径增大。适量Sm掺杂可以抑制杂质BaCO3相的形成。     

废旧橡胶再生的今天与明天

文中对近年来国内外废橡胶的再生方法进行了汇总,着重阐述了废橡胶的物理再生、化学再生、生物再生方法。