气相法合成纳米颗粒的制备技术进展

本文综述了气相法合成纳米颗粒材料的主要制备技术，并介绍了制备方法的最新进展－化学气相冷凝技术制备纳米颗粒材料，提出了制备纳米颗粒技术研究中面临的问题及今后的发展方向。     

Synthesis of exfoliated PP/LDH nanocomposites via melt‐intercalation: Structure,thermal properties,and photo‐oxidative behavior in comparison with PP/MMT nanocomposites

Exfoliated polypropylene (PP)/layered double hydroxide (LDH) nanocomposites have been successfully synthesized via melt‐intercalation. Their structure, thermal properties, and photo‐oxidative behavior have been characterized by X‐ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), dynamic mechanical thermal analysis (DMA), X‐ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectrum. TGA and DMA data show that the PP/LDH nanocomposites have enhanced thermal stability compared with virgin PP and corresponding PP/montmorillonites (MMT) nanocomposites, especially in high temperature range during the thermal decomposition of the samples. XPS and FTIR results give positive evidence that the photo‐oxidation mechanism of PP in the PP/LDH materials is not modified compared with that of virgin PP. However, photo‐oxidation rate of PP/LDH materials is much lower than that of PP and PP/MMT samples, indicating that the PP/LDH nanocomposites have better UV‐stability. POLYM. ENG. SCI. 46:1153–1159, 2006. © 2006 Society of Plastics Engineers     

Surface morphology and nodule formation mechanism of cellulose acetate membranes by atomic force microscopy

By the use of atomic force microscopy (AFM), formation mechanism of nodular structure in cellulose acetate membranes was systematically investigated. Elementary factors affecting the nodule formation were delineated on the basis of both kinetic and thermodynamic considerations. It was shown that (1) the exact nature of nodular structure is thermodynamic equilibrium glassy state; nodular structure will vanish in the rubbery state; (2) the thermodynamic factor affecting nodule formation is the membrane formation temperature; with the membrane formation temperature decreasing, more chain segments are able to form nodular structures; (3) nodule formation is dependent on the segment rearrangement; variation of the solvent environment is the major kinetic factor affecting the segment rearrangement and nodule formation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1328–1335, 2003     

Building Technical Trading System with Genetic Programming: A New Method to Test the Efficiency of Chinese Stock Markets

Testing whether technical trading rules can beat buy-and-hold strategy is a common approach to study the efficiency of stock markets. Noticing that the common approach of evaluating popular technical trading rules’ profitability would result in the biases of data snooping and incomplete test, we build a technical trading system with genetic programming to test the efficiency of Chinese stock markets. This system takes historical prices and volumes as inputs, randomly generates treelike structured technical trading rules composed of basic functions, and optimizes the rules using genetic programming according to the inputs. Using daily prices and volumes of Shenzhen Stock Exchange 100 index from January 2, 2004 to March 12, 2010, we find out that the optimal technical trading rules generated by our technical trading system have statistically significant out-of-sample excess returns compared with buy-and-hold strategy considering realistic transaction costs. Therefore, we conclude that Chinese stock markets have not achieved weak-form efficiency.     

我国氢能产业发展和氢资源探讨

分析了我国氢能产业近期发展情况,我国氢能产业正步入快速发展机遇期。指出氢能是21世纪最具发展潜力的一种清洁二次能源,具有"清洁、高效、安全、可持续"四大特点,被誉为未来世界能源架构的核心。重点讨论了我国氢资源和绿色氢气制备问题,指出目前实际使用的氢气包括"灰氢""蓝氢"和"绿氢"三大类,显然"灰氢"不可取,"蓝氢"可以用,"废氢"可回收,"绿氢"是方向。讨论了加快氢能系统建设,建立发展氢气存储和运输系统及加氢站基础设施建设等问题。未来,我国氢能产业发展潜力巨大,但是在下决心大力发展氢能产业时,需要高度注意目前存在的实际情况和困难,要防范一系列的产业风险,做到有序发展,稳中有进,才能实施氢能产业的可持续发展。     

基于BACnet/IP的设备与实时数据库通信实现

针对不同厂商、不同系统的楼宇自控设备互操作、互通信的局限性,分析了BACnet/IP技术和实时数据库,设计开发了一种基于BACnet/IP技术的实时数据库DasRdb的设备驱动程序。该设备驱动程序采用UDP通信方式,通过调用每个BACnet/IP设备的标准接口函数来驱动实时数据库DasRdb分别进行写操作和读操作,能够有效地实现BACnet/IP设备与实时数据库DasRdb之间的通信,从而使楼控设备的互操作成为可能。现场工程应用表明,该程序的运行契合BACnet的一致性要求,具有简单、高效、精确度高、实时性好的特点。     

Study of nucleation activity and application of a nucleating agent to copolypropylene

The influences of nucleating agent content on crystallization peak temperature, crystallization curve shape, crystallization onset temperature, and crystallinity of a copolypropylene were studied in detail by differential scanning calorimetry. The results showed that crystallization onset temperature and crystallization peak temperature increased 17°C–22°C and 15°C–19°C, respectively, with increasing nucleating agent content. The behavior of the nucleating agent showed excellent efficiency. But the shape of the crystallization curve broadened with increasing nucleating agent content, and the crystallinity came to an extremum when the nucleating agent content was 0.2%. These results generally differed from those for crystallization of i‐PP by a nucleating agent. Modification of copolypropylene was studied by use of a nucleating agent, and the characteristics of the effects of the nucleating agent on copolypropylene were mastered. The results showed that the hardness of a copolypropylene improved observably. So the abrasion resistance of biaxially oriented polypropylene (BOPP) film for cigarette packaging was improved by adopting the modified copolypropylene as the skin‐layer heat‐seal material of BOPP film. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101:3915–3919, 2006     

高速高机动目标自适应IMM跟踪算法

针对目标运动过程中有转弯机动等复杂运动模式的高速高机动目标,设计了自适应两层IMM跟踪算法。该算法内层由改进的机动目标当前统计模型构成,把目标速度方向角作为伪测量值进行滤波,实时获得目标的角速度和角加速度;外层模型由常速模型和曲线模型构成,把内层模型得到的切向加速度和转弯角速度作为曲线模型参数,利用IMM算法进行滤波。仿真结果表明,该算法对高速高机动目标具有较高的跟踪精度,算法实现简单,具有一定的实际应用价值。     

基于改进卡方统计的微博特征提取方法

通过对微博文本特征信息的分析与研究,提出一种基于改进卡方统计的微博特征提取方法。扩充微博信息分类特征,在传统的卡方统计量的基础上,引入了频度等因素,改进特征选择方法;在传统的特征项权值计算的基础上,提出了新的改进卡方统计量的方法,改进权重计算效果。对上述方法利用经典KNN和SVM算法进行了测试,实验结果表明该方法提高了微博信息分类的准确率。