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101.
    
The morphology of hybrid organic–inorganic perovskite films is known to strongly affect the performance of perovskite‐based solar cells. CH3NH3PbI3‐xClx (MAPbI3‐xClx) films have been previously fabricated with 100% surface coverage in glove boxes. In ambient air, fabrication generally relies on solvent engineering to obtain compact films. In contrast, this work explores the potential of altering the perovskites microstructure for solar cell engineering. This work starts with CH3NH3PbI3‐xClx, films with grain morphology carefully controlled by varying the deposition speed during the spin‐coating process to fabricate efficient and partially transparent solar cells. Devices produced with a CH3NH3PbI3‐xClx film and a compact thick top gold electrode reach a maximum efficiency of 10.2% but display a large photocurrent hysteresis. As it is demonstrated, the introduction of different concentrations of bromide in the precursor solution addresses the hysteresis issues and turns the film morphology into a partially transparent interconnected network of 1D microstructures. This approach leads to semitransparent solar cells with negligible hysteresis and efficiencies up to 7.2%, while allowing average transmission of 17% across the visible spectrum. This work demonstrates that the optimization of the perovskites composition can mitigate the hysteresis effects commonly attributed to the charge trapping within the perovskite film.  相似文献   
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103.
One of the most important spoilage factors of foods is molds. Therefore, it is important to determine the presence of mold in foods quickly because of the deterioration of aroma, flavor, appearance, and textural structure as well as the mycotoxins, which are toxic secondary metabolites of molds. Twenty-five percent of agricultural products worldwide are infected with mycotoxins directly or indirectly. With the global population increasingly rising, the need for access of safe and adequate food in the future has great importance. Quantification of ergosterol, a constituent of the membrane of molds and a precursor of vitamin D2, is a feasible method for determination of fungal contamination in foods. The aim of this review is to discuss the possibility of using ergosterol as an indicator of mold growth in foods.  相似文献   
104.
    
Electrical insulation is a major security problem in aerospace applications where temperature can reach relatively low values. Epoxy resins are well known as easily formable dielectric materials and can be used to prepare complex insulator parts. In this study, the electrical performance of bisphenol A/epichlorohydrin epoxy resin matrix‐based nanocomposites containing 1, 3, or 6 wt% titanium oxide (TiO2) or aluminium oxide (Al2O3) nanofillers are investigated. Composites are characterized with thermogravimetric analysis, scanning electron microscopy‐coupled electron dispersive spectroscopy, and confocal Raman spectroscopy. Furthermore, the role of additives and their ratio on the resistivity performance of the composites are evaluated from 77 to 500 K by applying a direct current voltage from 1 to 20 V. It is observed that the electrical properties of the matrix are directly influencing the insulation performance of the nanocomposite. For example, the abrupt decrease at 370 K of the positive temperature coefficient of the resin for all nanocomposites. It is found that the most resistive composite contains 3 wt% TiO2 nanoparticles with a value above 3.7.1010 Ω from 77 to 370 K at 20 V. As a result, this work gives information on to the choice of appropriate insulator materials in extreme working conditions.  相似文献   
105.
    
With the increasing ageing population worldwide, providing effective nursing care planning in nursing homes is important in meeting the expectations of elderly patients and in streamlining the healthcare information process, hence maintaining high‐quality services. Instead of the traditional manual nursing care planning formulation based on expert experience and subjective judgement, this paper describes an adaptive decision support system, namely, the cloud‐based nursing care planning system, to enable decision making in formulating nursing care strategies. By integrating cloud computing technology and the case‐based reasoning (CBR) technique, medical records and documents pertaining to the elderly can be captured in real time, whereas appropriate treatment plans based on past similar treatment records can be formulated. However, the current case adaptation processes in CBR rely on domain experts to modify retrieved cases, which may not satisfy the needs of the elderly. Therefore, text mining is integrated in the case adaptation process of CBR for extracting up‐to‐date medical information from the Internet so that its efficiency can be improved. By conducting a pilot study in a nursing home, it was shown that the time for formulating applicable treatment plans for elderly patients can be reduced, and the service satisfaction level can be enhanced.  相似文献   
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107.
Tryptophan (Trp) is an amino acid and an essential component of the human diet. It plays a crucial role in many metabolic functions. Clinicians can use Trp levels in the course of diagnosing various metabolic disorders and the symptoms associated with those diseases. Furthermore, supplementation with this amino acid is considered in the treatment of depression and sleep disorders, mainly due to the Trp relationship with the synthesis of serotonin (5-HT) and melatonin. It is also used in helping to resolve cognitive disorders, anxiety, or neurodegenerative diseases. Reduced secretion of serotonin is associated with autism spectrum disorder, obesity, anorexia and bulimia nervosa, and other diseases presenting peripherals symptoms. The literature strongly suggests that Trp has a significant role in the correct functionality of the brain-gut axis and immunology. This information leads to the consideration of Trp as an essential dietary component due to its role in the serotonin pathway. A reduced availability of Trp in diet and nutraceutical supplementation should be considered with greater concern than one might expect. This paper constitutes a review of the more salient aspects gleaned from the current knowledge base about the role of Trp in diseases, associated nutritional disorders, and food science, in general.  相似文献   
108.
    
Operation stability remains the key hurdle for the best‐performing non‐fullerene small molecule acceptor (SMA)‐based organic photovoltaic (OPV) devices. Among all SMAs, the ITIC‐derivative is the most promising OPV cell using ITIC‐derivative acceptors with a power conversion efficiency > 15%. However, the operation stability of SMA‐based devices under illumination is relatively inferior when compared to bulk‐heterojunction (BHJ) cells that employ polymeric acceptors. Here, a polymer acceptor N2200 is used as the ternary component to study the device performance of ITIC‐derivative‐based PBDB‐T:ITIC‐M and PBDB‐T‐2F:IT‐4F BHJ solar cells, which currently are the representative state‐of‐the‐art high‐performance OPV devices. The ternary solar cells with low N2200 loading enjoy significantly improved operation stability, while maintaining a high power conversion efficiency. A comprehensive mechanism study is conducted on the ternary OPV systems in i) electronic and ii) thermal aspects. For i), the ternary BHJs show remarkably improved electron transport. For ii), the thermal diffusivity D of the ternary BHJ exhibits almost an order of magnitude improvement in D values, indicating that heat can be more effectively transferred out of such films than binary counterpart. The results show that N2200 ternary loading facilitates an improved network for both electron transport and heat dissipation, leading to improved photostability.  相似文献   
109.
    
To date, thousands of publications have reported chemical vapor deposition growth of “single layer” graphene, but none of them has described truly single layer graphene over large area because a fraction of the area has adlayers. It is found that the amount of subsurface carbon (leading to additional nuclei) in Cu foils directly correlates with the extent of adlayer growth. Annealing in hydrogen gas atmosphere depletes the subsurface carbon in the Cu foil. Adlayer‐free single crystal and polycrystalline single layer graphene films are grown on Cu(111) and polycrystalline Cu foils containing no subsurface carbon, respectively. This single crystal graphene contains parallel, centimeter‐long ≈100 nm wide “folds,” separated by 20 to 50 µm, while folds (and wrinkles) are distributed quasi‐randomly in the polycrystalline graphene film. High‐performance field‐effect transistors are readily fabricated in the large regions between adjacent parallel folds in the adlayer‐free single crystal graphene film.  相似文献   
110.
The objective of this study was to evaluate the effectiveness of sodium benzoate as an inhibitor to slow down or prevent atmospheric corrosion/discoloration of the local mild steel during storage in the Arabian Gulf region. Test specimens were prepared from locally produced reinforcing steel products. The inhibitor solution was applied on steel specimens at a concentration of 100 mM for 1 day at room temperature. Wooden exposure racks were used to hold as-received and inhibitor-treated specimens during atmospheric exposure for different periods. Corrosion was evaluated through weight loss determination and electrochemical technique. As expected, the Arabian Gulf atmosphere was corrosive on the as-received local mild steel. On the other hand, treatment of steel with sodium benzoate lowered its corrosion rate during initial days of its exposure to atmosphere. However, atmospheric corrosion inhibition performance of sodium benzoate deteriorated with exposure time after 30 or more days of atmospheric exposure, and the corrosion rates of sodium benzoate-treated specimens reached that of the unprotected specimens at the end of 90 days of atmospheric exposure.  相似文献   
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