The Riverside and Berwyn experience: Contrasts in landscape structure, perceptions of the urban landscape, and their effects on people

Humans not only structure the landscape through their activities, but their perceptions of nature are affected by the spatial and temporal arrangements (structure) in the landscape. Our understanding of these interactions, however, is limited. We explored the relationship between landscape structure and peoples’ perceptions of nature in the Chicago, IL, USA, suburbs of Riverside and Berwyn because they offer contrasting paradigms of an urban landscape. Designed in the 1800s by Frederick Law Olmsted, Riverside has several unique design elements (curvilinear streets, ample setbacks, parkways of variable width with mowed grass and naturalistic groupings of trees) that define the structure and composition of this landscape. The urban forest was the keystone of Olmsted's desire to create a harmonious community characterized by “refined sylvan beauty”. In contrast, the adjacent community of Berwyn has right-angled streets with small lots and narrow setbacks for houses. Differences in landscape structure between the two communities produced differences in the diversity, size, and composition of woody vegetation. As measured by patch-size distribution, Riverside had greater diversity in landscape structure than Berwyn, and in turn, Riverside had greater diversity in the composition and size of the woody vegetation compared to Berwyn. Riverside tended toward a “natural” appearance with vegetation, while yards in Berwyn tended to be trimmed and edged. Significant differences between the mean ratings of Riverside and Berwyn respondents were found for six of seven community attribute categories. Riverside participants reported receiving greater benefit from the visual and nature-related features of the urban forest than did Berwyn respondents. Berwyn residents ranked social atmosphere for the community and locomotion (wayfinding) highest among the seven community attribute categories. Despite differences between the two communities, residents valued the green residential environment provided by vegetation. However, the more diverse urban landscape as measured by built structures, woody vegetation, and lot size and shape proved to be more satisfying to the residents of these two communities. The design concepts developed and implemented by Olmsted more than century ago in Riverside are still relevant to city planners striving to develop living environments that are satisfying to urban and suburban residents.     

R Curves and Crack-Stability Map: Application to Ce-TZP/Al2O3

The concept of a crack-stability map is developed by considering the interaction between the crack-driving force and the rising crack-growth resistance of a toughened ceramic. The map plots normalized transition crack length as function of the ratio of the crack-initiation fracture toughness and the plateau toughness to delineate regimes of stable and unstable crack growth. The plot is used to analyze R curves and fracture stresses of a transformation-toughened Ce-TZP/Al₂O₃. It is shown that the fracture stress and the small scatter measured for this ceramic are consistent with its R- curve behavior, which enables stable growth of surface cracks from flaws (pores and second-phase particles), leading to a flaw-insensitive ceramic.     

A new testing configuration for shrinkage cracking of shotcrete and fiber reinforced shotcrete

Shotcrete and fiber reinforced shotcrete are commonly employed to produce layers or linings with large surface area versus volume ratios. Restrained shrinkage cracking is hence an important concern. The common test set-up used for shrinkage cracking of concrete, with a ring specimen cast around a stiff steel form, is not applicable to shotcrete. A new testing configuration, consisting of a shotcrete specimen bonded to a steel I-section and angles, is therefore proposed. In this investigation, a finite element analysis was first performed to identify member sizes that provide a good compromise between the effectiveness of constraint and weight of steel members. Restrained shrinkage tests using this new configuration were performed for plain and fiber reinforced shotcrete. Despite the simplifying assumptions in the finite element analysis, the predicted degree of restraint is in reasonable agreement with test results. From the results, the proposed set-up is shown to be a practical and viable approach for investigating the shrinkage cracking behavior of shotcrete and fiber reinforced shotcrete.     

Two-degree-of-freedom output feedback controllers for discrete-time nonlinear systems

A discrete-time, model-based output feedback control structure for nonlinear processes is developed in the present work. The structure makes use of a closed-loop observer, while at the same time it guarantees that the overall feedback controller possesses integral action. An algebraic transformation is applied on the observer states to insure that the input/output gain of the observer matches the model upon which the static state feedback control law is based. The resulting control algorithm is a two-degree-of-freedom control law, in the sense that the output and the set point are processed in different ways. The control structure is shown not only to have the same properties as the standard model-state feedback structure, but also that it emerges from a model algorithmic control framework. Finally, a simulation example using an exothermic CSTR operating at an open-loop unstable steady state is used to evaluate the closed-loop performance of the proposed method.     

Changes in the size and docosahexaenoic acid content of adipocytes during chick embryo development

The development of adipose tissue in the chick embryo was investigated using two groups of fertile eggs which differed by 1.7-fold in their initial yolk lipid levels. The triacylglycerol content of the subcutaneous adipose depot in both groups increased dramatically from day 12 of the 21-day embryonic period, attaining a maximal value just prior to hatching. During this period, the amount of triacylglycerol deposited in the adipose tissue was very highly correlated with the amount of lipid transferred from the yolk. The triacylglycerol content of the depot was also dependent on the initial yolk lipid content. During the hatching period, the amount of adipose triacylglycerol remained approximately constant in the group with the higher initial yolk lipid content but, in the case of the group with the lower initial yolk lipid levels, decreased by approximately 25%. The size distribution of adipocytes isolated from the tissue was determined by computerized image analysis microscopy. The mean adipocyte diameter increased from approximately 6 to 35 μm between days 12 and 19, irrespective of the initial yolk content, although development within the eggs with the lower initial yolk content resulted in a decrease in cell size over the hatching period. Both the triacylglycerol and phospholipid fractions of the isolated adipocytes contained substantial proportions (approximately 6%, w/w) of docosahexaenoic acid (DHA) at days 12 and 14, and lower levels of this fatty acid at the later stages. The amount (mg/depot) of DHA in adipose triacylglycerol decreased dramatically over the hatching period. The amount (mg/brain) of DHA in brain phospholipid increased by more than 5-fold between day 12 of development and hatching. A possible explanation for the data may be that DHA is preferentially mobilized from adipose tissue in order to deliver the fatty acid to the developing neural tissues in a form suitable for uptake.     

Review of failure criteria of fibrous composite materials

Composite materials exhibit various and complex failure behavior. Different formalisms have been used to predict failure. Improvement of old theories and new ones continue to be published. In this paper, the most recent and widely used models are presented. Failure criteria such as Tsai-Wu, parametric formulations, maximal stress and strain, Hashin criterion, Hart-Smith criterion, and the method based on kriging are presented. These failure theories may be classified in two categories, depending whether they integrate failure modes or not. The formalism of each theory is briefly described and their application to model failure of composite laminates is discussed by comparing the advantages and limitations of each method. The diversity of experimental failure envelopes, as reported in the literature on composites, is outlined and it is shown that most criteria permit modeling only particular failure properties of composite laminates.     

Transient adsorption studies of automotive hydrocarbon traps

A chromatographic adsorption unit was designed and built to study the adsorption of alkanes in zeolites for the hydrocarbon trap systems in three‐way catalysts, to assist in the selection of optimal materials for this application. The experimental apparatus used a zeolite bed in place of the column in an ordinary gas chromatograph and could be accurately modeled to determine the adsorption equilibrium constants for simple alkanes in MFI zeolites. The adsorption of iso‐pentane was studied in BEA zeolites with varying Si/Al₂ ratios, before and after ex situ zeolite aging simulating engine exhaust, and in the presence of water vapor. The elution times were shown to depend directly on the zeolite adsorption capacity. The primary effect of water was to decrease the iso‐pentane adsorption capacity by partial filling of the zeolite pores through adsorption of water at acid sites. Some implications of this work for choosing the best materials for hydrocarbon trapping are discussed. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2875–2881, 2014     

Effect of Fiber Length on Carbon Nanotube-Induced Fibrogenesis

Given their extremely small size and light weight, carbon nanotubes (CNTs) can be readily inhaled by human lungs resulting in increased rates of pulmonary disorders, particularly fibrosis. Although the fibrogenic potential of CNTs is well established, there is a lack of consensus regarding the contribution of physicochemical attributes of CNTs on the underlying fibrotic outcome. We designed an experimentally validated in vitro fibroblast culture model aimed at investigating the effect of fiber length on single-walled CNT (SWCNT)-induced pulmonary fibrosis. The fibrogenic response to short and long SWCNTs was assessed via oxidative stress generation, collagen expression and transforming growth factor-beta (TGF-β) production as potential fibrosis biomarkers. Long SWCNTs were significantly more potent than short SWCNTs in terms of reactive oxygen species (ROS) response, collagen production and TGF-β release. Furthermore, our finding on the length-dependent in vitro fibrogenic response was validated by the in vivo lung fibrosis outcome, thus supporting the predictive value of the in vitro model. Our results also demonstrated the key role of ROS in SWCNT-induced collagen expression and TGF-β activation, indicating the potential mechanisms of length-dependent SWCNT-induced fibrosis. Together, our study provides new evidence for the role of fiber length in SWCNT-induced lung fibrosis and offers a rapid cell-based assay for fibrogenicity testing of nanomaterials with the ability to predict pulmonary fibrogenic response in vivo.     

Curcumin-Induced Heme Oxygenase-1 Expression Prevents H2O2-Induced Cell Death in Wild Type and Heme Oxygenase-2 Knockout Adipose-Derived Mesenchymal Stem Cells

Mesenchymal stem cell (MSC) administration is a promising adjuvant therapy to treat tissue injury. However, MSC survival after administration is often hampered by oxidative stress at the site of injury. Heme oxygenase (HO) generates the cytoprotective effector molecules biliverdin/bilirubin, carbon monoxide (CO) and iron/ferritin by breaking down heme. Since HO-activity mediates anti-apoptotic, anti-inflammatory, and anti-oxidative effects, we hypothesized that modulation of the HO-system affects MSC survival. Adipose-derived MSCs (ASCs) from wild type (WT) and HO-2 knockout (KO) mice were isolated and characterized with respect to ASC marker expression. In order to analyze potential modulatory effects of the HO-system on ASC survival, WT and HO-2 KO ASCs were pre-treated with HO-activity modulators, or downstream effector molecules biliverdin, bilirubin, and CO before co-exposure of ASCs to a toxic dose of H₂O₂. Surprisingly, sensitivity to H₂O₂-mediated cell death was similar in WT and HO-2 KO ASCs. However, pre-induction of HO-1 expression using curcumin increased ASC survival after H₂O₂ exposure in both WT and HO-2 KO ASCs. Simultaneous inhibition of HO-activity resulted in loss of curcumin-mediated protection. Co-treatment with glutathione precursor N-Acetylcysteine promoted ASC survival. However, co-incubation with HO-effector molecules bilirubin and biliverdin did not rescue from H₂O₂-mediated cell death, whereas co-exposure to CO-releasing molecules-2 (CORM-2) significantly increased cell survival, independently from HO-2 expression. Summarizing, our results show that curcumin protects via an HO-1 dependent mechanism against H₂O₂-mediated apoptosis, and likely through the generation of CO. HO-1 pre-induction or administration of CORMs may thus form an attractive strategy to improve MSC therapy.     

Acetals as nucleating agents for polypropylene

Nucleating agents increase the impact strength, tensile strength, and tensile elasticity modulus of semicrystalline polymers. Nucleating agents also decrease product cycle times, resulting in a cost savings per product unit. We have synthesized and tested 15 compounds as nucleactors for polypropylene. Of these, trinapthylidene sorbitol, tri-(4-methyl-1-naphthylidene)sorbitol, tri-(4-methoxy-1-naphthylidene) sorbitol, and dibenzylidene xylitol are efficient nucleators of polypropylene. Trinaphthylidene sorbitol (tns) has two major diastereomers: The “S” diastereomer yields a faster crystallization rate for polypropylene than does the commercial nucleator dibenzylidene sorbitol (Millad 3905). Crystallization rates are 208 and 88, respectively (t min^?1 × 1000). The “R” diastereomer, however, is a poor nucleator and interferes with the nucleating activity of the “S” diastereomer. A 52/48 mixture of diastereomers does not nucleate polypropylene, even at twice the concentration. This is first time that the importance of stereochemistry has been demonstrated in the nucleating action. © 1994 John Wiley & Sons, Inc.