Effect of surface-modifying macromolecules and solvent evaporation time on the performance of polyethersulfone membranes for the separation of chloroform/water mixtures by pervaporation

Polyethersulfone (PES) membranes using different evaporation periods were fabricated by the phase-inversion method. Pervaporation experiments were conducted for chloroform/water mixtures to determine the selectivity of the PES membranes. It was found that chloroform could be concentrated in the permeate from chloroform/water binary feed mixtures by PES membranes prepared using longer evaporation periods, and that the selectivity of PES membranes in pervaporation could be reversed by shorter evaporation periods. This study also showed that by adding surface-modifying macromolecules (SMM) up to 1 wt % into the casting solution, chloroform enrichment in the permeate could be increased by 50%. Chloroform enrichment increased with increasing SMM concentration until an optimal value, after which the enrichment decreased. © 1994 John Wiley & Sons, Inc.     

Affect intensity and cardiac arousal.

Investigated in 3 experiments the relationships between affect intensity and basal, evoked, and perceived cardiac arousal. Affect intensity was assessed using R. J. Larsen and E. Diener's (1987) Affect Intensity Measure (AIM). Cardiac arousal was evoked with exercise in the 1st study and with mental arithmetic in the 2nd and 3rd. Perceived cardiac arousal was measured under optimal conditions using a standard heartbeat discrimination procedure. Women as a group scored higher on the AIM. Affect intensity was unrelated to basal or evoked cardiac arousal and was negatively related to perceived cardiac arousal in all 3 studies. Data suggest that affect intensity, although unrelated to actual physiological arousal, is negatively related to the accuracy with which individuals perceive their own arousal. Results are discussed within the context of an expanded arousal-regulation model (J. Blascovich, 1990). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The effect of aromatics on paraffin mild hydrocracking reactions (WNiPd/CeY–Al2O3)

The conversion of heavy paraffin and aromatics into a high-quality diesel fraction was performed in a microplant using a WNiPd/CeY-alumina catalyst. The effects of aromatics and naphtheno-aromatics on mild hydrocracking of hexadecane were studied at different concentrations. Two catalysts, with and without Pd and thermal treatment, were characterized by FTIR, XPS, and TPD of ammonia and ammonia plus naphthalene to complement previous study about the surface composition. The hydrocracking activity and selectivity were tested using different amounts and types of aromatics. This study demonstrated the presence of two acid strengths that contribute in different ways to paraffin and aromatics isomerization, ring opening, and cracking reactions. The product distribution obtained by mild hydrocracking of n-C₁₆ is between amorphous (SiO₂Al₂O₃) and Y-zeolite type of support. The aromatic adsorption on acid sites reduces the cracking rate and improves the survival of di- and tri-branched paraffin. A model for the path of reaction is discussed to explain the results.     

走进虚拟的视界——图解显卡

随着电脑3D图形应用的日益普及,显卡在PC中的地位也日益提高。下面以图解方式说说显卡的基本结构与功能。     

General relativity and quantum mechanics: towards a generalization of the Lambert W function A Generalization of the Lambert W Function

We present a canonical form for a natural and necessary generalization of the Lambert W function, natural in that it requires minimal mathematical definitions for this generalization, and necessary in that it provides a means of expressing solutions to a number of physical problems of fundamental nature. This generalization expresses the exact solutions for general-relativistic self-gravitating N-body systems in one spatial and one time dimension, and a previously unknown mathematical link between the (1+1) gravity problem and the Schrödinger wave equation.     

Mesomorphic behavior of polydiethylphosphazenes as described by13C,14N,and2H NMR

The existence of mesomorphism in polydiethylphosphazene was recently established by MAS NMR and X-ray diffraction characterization. In the present work the mechanism of motion of the ethyl side groups in the high-temperature polymorph tabove 45 C) is identified and compared to the arrangement of side groups in the low-temperature polymorph. For this purpose a few NMR active nuclei (¹³C,¹⁴N, and²H) were exploited to define the side-chain motions occurring at transition. Experiments performed at varying temperatures close to the onset of solid transition suggest the presence of jumps between two conformations in the pretransition state. Rotor-synchronized triple-resonance NMR of the high-temperature phase determined the average distances between the carbons and the nitrogens in the polymorphs. The theoretical prediction of the dipolar interaction between the nuclei supports the hypothesis that ethyl groups can undergo a complete rotation about the P CH₂ bond by jumping across a conformational barrier. The mechanism of motion of the ethyl groups must be cooperative and the collapse of the rigid shell around the main chain is described at the transition.     

Incremental wrapper-based gene selection from microarray data for cancer classification

Gene expression microarray is a rapidly maturing technology that provides the opportunity to assay the expression levels of thousands or tens of thousands of genes in a single experiment. We present a new heuristic to select relevant gene subsets in order to further use them for the classification task. Our method is based on the statistical significance of adding a gene from a ranked-list to the final subset. The efficiency and effectiveness of our technique is demonstrated through extensive comparisons with other representative heuristics. Our approach shows an excellent performance, not only at identifying relevant genes, but also with respect to the computational cost.     

Accurate Depth of Field Simulation in Real Time

We present a new post processing method of simulating depth of field based on accurate calculations of circles of confusion. Compared to previous work, our method derives actual scene depth information directly from the existing depth buffer, requires no specialized rendering passes, and allows easy integration into existing rendering applications. Our implementation uses an adaptive, two‐pass filter, producing a high quality depth of field effect that can be executed entirely on the GPU, taking advantage of the parallelism of modern graphics cards and permitting real time performance when applied to large numbers of pixels.