Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

Neue Entwicklungen beim Hohlkatoden‐Gasflusssputtern. New Developments in Hollow Cathode Gas Flow Sputtering

The gas flow sputter technique was invented a few years ago particularly for the inexpensive fabrication of sophisticated ceramic layers. Meanwhile, it has matured and become increasingly powerful. Today it is on the verge of being applied in industrial fabrication processes. The present article gives an overview over the method, its characteristics and the numerous applications.     

超高摩尔质量聚乙烯内衬复合管应用前景展望

通过对超高摩尔质量聚乙烯内衬复合管的技术特点及国内外现场试验效果的阐述；证明了超高摩尔质量聚乙烯内衬复合管自身的各种物理特性。对延长旧管使用寿命,减少杆管偏磨,延长油井清蜡周期具有良好的效果。     

俄气南供与天然气利用规划

介绍了俄气南供的供气方案，讨论了天然气的市场调查和价格的确定等问题。     

三元催化转化器中的现象分析与研究

在介绍和分析国内外研究现状的基础上，论述了三元催化转化器中的传递现象及化学反应动力学．探讨了三元催化转化器在暖机过程中有害物质的催化转化模型，并建议采用数学模型的方法对催化器在发动机所有工况下的工作过程进行模拟。     

块状镁基金属玻璃的研究进展

介绍了块状镁基金属玻璃的发展过程及最新的研究进展,着重阐述了块状镁基金属玻璃的几种制备方法及其性能,最后指出了今后块状镁基金属玻璃的研究重点.     

高等级公路桥头跳车的原因与技术处理

对高等级公路产生桥头跳车的原因作了分析 ,从地基土地质、台背填料、路面渗水等方面进行了论述 ,提出技术处理措施 ,并指出只有公路建设、设计、监理部门的严格把关 ,才能有效地避免桥头跳车。     

Novel blood-compatible waterborne polyurethane using chitosan as an extender

A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, M_n = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (M_n = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Comparison of physical characteristics and cell culture test of hydroxyapatite/collagen composite coating on NiTi SMA: electrochemical deposition and chemically biomimetic growth

A hydroxyapatite (HA)/collagen (COL) composite coating on NiTi shape memory alloy (SMA) was prepared by eletrochemical deposition (ELD) in modified simulated body fluid (MSBF). To draw comparisons of physical characteristics and bioactivity of the composite coating, the HA/COL composite coating was also prepared by chemically biomimetic growth (BG) and the ELD coating was re-soaked in MSBF again for further biomimetic growth (called EBG method in this paper). It was indicated that the c-axis of HA crystals was oriented parallel to the longitudinal direction of the COL fibril in BG and EBG coating, which could not found in ELD coating. The EBG method could induce a denser, thicker and better crystallized HA/COL coating. The cell culture test indicated that the BG coating presented better cell biocompatibility.     

黄河西霞院工程地震薄层反射问题的探讨

该文通过黄河西霞院夹砂层勘察存在的问题，引出了地层薄层地震反射同相轴出现的理论依据，从而计算出在本地区探测地层薄层厚度的分辨率。