PVC新型改性剂AS的合成与应用

本文主要介绍ＰＶＣ新型改性剂ＡＳ树脂的合成方法、产品性能及其在ＰＶＣ异型材、管材、注射、压延片等加工领域中的应用。实验结果证明：该产品完全可以代替ＡＣＲ加工助剂，并有很好的经济效益。     

Catalytic reduction of no over perovskite-type catalysts

In the present work, we have investigated the reduction of NO by propane over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxides. In addition, the reaction conditions, such as temperature, O₂ concentration, and space velocity have been varied to understand their effects on the catalytic performance. In the LaCoO₃ type catalyst, the partial substitution of Ba and Sr into A site enhanced the catalytic activity in the reduction of NO. For the La_0.6Ba (Sr)_o.4 Co_1−x Fe_xO₃ (x=0-1.0) catalyst, the partial substitution of Fe into B site enhanced the conversion of NO, but excess amount of Fe decreased the conversion of NO. The surface area and catalytic activity of perovskite catalysts prepared by malic acid method showed higher values than those of solid reaction method. The conversion of NO increased with increasing O₂ concentration and contact time. The introduction of water into reactant feed decreased the catalytic activity but the deactivation was shown to be reversible over La_0.6Ba_0.4Co_1−x ,Fe_xO₃ catalyst.     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

在文明寨地区的高精度地震资料处理实践

文明寨地区构造复杂，断块多，岩性变化大，一些地质问题不明，需要高精度三维资料处理来提高资料的纵、横向分辨率^[1][2]及为储层、油藏研究提供精确的依据。针对东濮文明寨地区高精度处理过程中的关键技术进行了大量分析试验，形成了一套适合东濮地区的较为完整的3D高精度地震资料处理流程。实际资料处理表明效果较好。     

SDBS的表面张力对天然气水合物生成的影响

利用德国KRUSS公司生产的界面张力仪K11中的板法测定十二烷基苯磺酸钠在不同温度(5,10,20,30,35℃)和不同浓度下(100,400,800,1200,1600,2000 mg/L)的表面张力,确定有利于天然气水合物合成的最佳浓度为1 200 mg/L,这在工业应用中有着重要的参考价值,同时分析了表面活性剂加速天然气水合物生成的机理。     

脲醛树脂微胶囊稳定性研究

用原位聚合法设计L9（3^4）正交实验制备脲醛树脂微胶囊，讨论了助剂用量和乳化速度对微胶囊水悬浮液稳定性的影响，得到了制备稳定性较好的脲醛树脂微胶囊的工艺参数。     

冷冻交联制备ZM-CSt-PVA复合凝胶及吸附Cu2+性能

以两性离子单体二甲氨基丙基丙烯酰胺-1-羧酸(ZM)、木薯淀粉(CSt)和聚乙烯醇(PVA)为主要原料,采用"一锅法",通过冷冻交联制备ZM接枝共聚CSt-PVA互穿网络复合凝胶(ZPG2)。使用FTIR、TGA、POM、SEM-EDS对ZPG2进行了表征,评价了ZPG2对Cu~(2+)的静态吸附效果。结果表明:300℃以下,ZPG2的热稳定性良好;ZM的存在可产生反聚电解质效应和化学配位效应,显著提高凝胶吸附能力;在吸附温度25℃、ZPG20.1 g、Cu~(2+)质量浓度2×10~3 mg/L、溶液体积100 mL时,饱和吸附量为199 mg/g;吸附过程符合Langmuir等温吸附模型和准二级动力学模型。     

生物制剂在SBR中的工业化试验

在处理炼油废水的SBR装置中加入一种生物促进剂和毒性缓冲剂,在投加量均为7mg/L的条件下,与未投加生物促进剂时相比,出水COD的去除率增加约50%,挥发酚由20mg/L降至4.9mg/L,污泥浓度由3.9g/L提高到4.9g/L,污泥絮体增大,结构紧密。     

Effects of the Addition of Different Types of Fillers on the Properties of BaO–ZnO–B2O3–SiO2 Glass Composites for Application to Barrier Ribs of Plasma Display Panels

Various types of crystalline ceramic fillers (TiO₂, ZrO₂, Al₂O₃, MgO, and cordierite) were added to BaO–ZnO–B₂O₃–SiO₂ (BZBS) glass (5–20 wt%), and the resultant dielectric constant, coefficient of thermal expansion (CTE), and optical reflectance were investigated for the application of the composites to the barrier ribs in plasma display panels. All the investigated fillers were partially dissolved into the glass at the fabrication temperature (575°C), and the residual fillers were aligned along the boundaries of sintered glass frits. By considering all aspects of the properties, the addition of TiO₂ fillers of about 10 wt% to BZBS glass was the most desirable of the types of fillers investigated. The addition of TiO₂ filler (10 wt%) yielded 61% in optical reflectance, 8.3 × 10⁻⁶ K^–1 in coefficient of thermal expansion, and 15.5 in dielectric constant, which were properties comparable with the currently used Pb-based barrier ribs.     

薄壁内压容器静强度的模糊可靠度与安全系数

应用基于模糊数学与常规可靠性理论相结合的模糊可靠性设计方法,讨论钢制薄壁内压容器模糊静强度在不同工况时,有关标准可接受的模糊可靠度范围;对钢制薄壁内压容器静强度的模糊可靠度范围与安全系数的关系进行研究。分析认为容器静强度在满足最小模糊可靠度要求的前提下,可取屈服安全系数ns≥1.55与抗拉安全系数nb≥1.95。