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21.
摘 要:目的 了解六六六(hexachlorocyclohexanes,HCHs)与滴滴涕(dichloro diphenyl trichloroethanes,DDTs)在杭州湾南岸滩涂沉积物中的污染现状。方法 于2018年4月,采集杭州湾南岸地区4个采样点不同深度(0~80 cm)滩涂沉积物,利用气相色谱-串联质谱法(gas chromatography tandem mass spectrometry, GC-MS/MS)测定了该区域中HCHs与DDTs的含量,对其分布规律进行分析,使用共识沉积物质量基准法对其生态学风险进行了评估。结果 所有样品中均检出,HCHs与DDTs含量分别为4.20~6.24 μg/kg与3.37~4.73 μg/kg,主要以β-HCH、δ-HCH以及DDE为主,其污染主要来源于历史性工业品,整体污染处于较低水平;20.3%的沉积物样品中DDEs含量以及28.1%的样品DDTs总量介于阈值效应浓度(threshold concentration, TECs) 和可能效应浓度(probable effect concentration, PECs)之间。结论 杭州湾南岸沉积物中HCHs与DDTs的污染处于较低水平,具有较小的生态学风险。 相似文献
22.
Scientometrics - Due to the development of academic, more and more attentions are paid to citation recommendation. To solve the citation recommendation problem, researchers begin to focus on the... 相似文献
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豫西熊耳山雷门沟钼矿床位于东秦岭多金属成矿带东段,是已探明的超大型斑岩型钼矿,前人研究程度高、地质成果丰硕,但对矿床开采技术条件方面研究较少。本次通过地质调查工程、水文地质试验等方法,从水文地质角度,对雷门沟钼矿床水文地质条件进行研究,填补了该方面的空白,丰富了研究成果;采用水文地质比拟法预测未来矿坑最大排水量2613 m3/d,经实践检验结果较为可靠;总结的采坑排水量预测方法、含水层特点、矿床充水因素以及防治水措施,以期对该区域水文地质工作具有参考价值。 相似文献
25.
In this work,the ionospheric variability is analyzed by applying the wavelet decomposition technique to the noontime fo F2,F10.7,interplanetary magnetic field(IMF)Bz,Ap,and lower thermospheric temperature at pressure of 10?4 h Pa in 2002.Results show that the variance of periodic oscillations in the ionosphere is largest in the 2–4-day period and declines with the increase of the period.The maximum variance of the periodic oscillations in solar irradiation is in the 16–32-day period.For geomagnetic activities,most of the variance is about equally distributed on intervals of periods shorter than 32 days.Variance distributions of IMF Bz and lower thermospheric temperature are similar to those of the ionosphere.They show the maximum in the 2–4-day period and decline with the increase of the period.By analyzing the distributions of the variances,the potential connections between the ionosphere and the external sources are discussed. 相似文献
26.
四川盆地作为国内页岩气开发的重点区域,通过近几年的不断攻关和实践,机械钻速得到了提高,但由于受地层复杂、可钻性差、非均质性强等地质因素的影响,导致井下钻柱系统不良振动剧烈,容易出现钻头损坏严重、钻速较低等问题,严重影响了钻井时效。为了解决上述难题,以该盆地涪陵工区上二叠统龙潭组—中二叠统茅口组为例,采用井下振动高频测量工具的实测手段,测量了钻头—钻柱系统的动态振动加速度参数,结合地层的岩性和矿物组分分析,研究钻头失效原因与对策,并开展了现场试验。研究结果表明:①在非均质地层中钻进的钻头—钻柱系统产生了大于40 m/s~2的高幅值瞬时冲击振动,高幅值的瞬时冲击是导致钻头先期失效的主要原因;②提出了抑制高幅值的瞬时冲击振动采用"减振+增压"工具组合和避免井下工具共振的钻井参数;③采用钻井新参数的试验井比邻井的高幅值瞬时振动降低了17%,单只钻头进尺增加24%,钻头工作环境得到了较大的改善,钻头使用数量减少。结论认为,该研究成果能够有效地改善钻头—钻柱系统的振动状态,有利于达成延长钻头使用寿命的目标。 相似文献
27.
Changwei Dun Guoxi Xi Ye Zhang Tingting Zhao Yumin Liu Xiaoying Heng Lu Yao 《Ceramics International》2018,44(17):20984-20991
In this study, we investigated the effects of substituting Li+ for Co2+ at the B sites of the spinel lattice on the structural, magnetic and magnetostrictive properties of cobalt ferrites. The Li+ substituted cobalt ferrites, Co1-xLixFe2O4, with x varying from 0 to 0.7 in 0.1 increments, were synthesized with a sol-gel auto-combustion method using the cathode materials of spent Li-ion batteries. X-ray diffraction analysis revealed that all the Co1-xLixFe2O4 nanopowders had a single-phase spinel structure and the lattice parameters decreased with increasing Li+ content, which can be proved by slight shifts towards higher diffraction angle values of the (311) peak. Field emission scanning electron microscopy was used to observe the fractured inner surface of the sintered cylindrical rods and the increased porosity resulted in a decreased magnetostriction. The oxidation states of Co and Fe in the cobalt ferrite samples were examined by X-ray photoelectron spectroscopy. High resolution transmission electron microscopy micrographs showed that most particles were roughly spherical and with sizes of 25–35?nm. Li+ substitution had a strong effect on the saturation magnetization and coercivity, which were characterized with a vibrating sample magnetometer. The Curie temperature was reduced due to the decrease in magnetic cations and the weakening of the exchange interactions. The magnetostrictive properties were influenced by the incorporation of Li+ at the B sites of the spinel structure and correlated with the changes in porosity, magnetocrystalline anisotropy and the cation distribution. 相似文献
28.
Linlin Zhu Liyuan Zhang Xi Li Xiaoqi Jin Tiejun Shi 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(7):551-560
AbstractGraphene oxide (GO) was functionalized by polyether amine (PEA) via two methods which were one-pot modification in acetone (GON) and two steps with the intermediate product of GOCO-Cl generated (GONS). There were more PEA successfully grafted onto GO for GONS than GON. The onset polymerization temperatures of the benzoxazine (Bz) composites decreased by the inclusion of 1?wt% of GO, GON or GONS. Thermal stability of the polybenzoxazine (PBz) composites was significantly improved indicated from the increase of weight loss temperature. T10, T20 and T50 values of the composites with GONS were higher than that of the others. Toughness of PBzs may be enhanced by the incorporation of nanofillers, and GONS had stronger interfacial interaction with PBz matrix than GON. 相似文献
29.
Xi Shen Li-Peng Cao Jian-Fa Zhao Wei-Peng Wang Qing-Qing Liu Yuan Yao Jun-Jie Li Chang-Zhi Gu Ming-Wei Chen Chang-Qing Jin Ri-Cheng Yu 《Journal of the American Ceramic Society》2019,102(11):6469-6474
We propose the question of the modulated structures of copper oxide is caused by the [CuO2] in-plane oxygen vacancy or apical oxygen vacancy. Sr2CuO3+δ single-crystal samples were prepared using high-temperature and high-pressure methods. The major phase of Sr2CuO3+δ (δ = 0.4) single-crystal system is found to be constituted by the 5 a modulated structure with the Fmmm space group, which originates from the [CuO2] in-plane oxygen vacancy appearing in octahedral Cu-O. Besides, the presence of the [CuO2] in-plane oxygen vacancy may obliterate the superconductivity of the system. Experimental results deduce that the oxygen vacancy may appear in the apical oxygen sites in high-temperature copper oxide superconductors. 相似文献
30.