Palladium(II) extraction from concentrated chloride media: Reactions involving thioamide derivatives

This work focuses on the detailed study of the palladium(II) extraction reactions by N-methyl-N-phenyl-octanthioamide (MPHTA) and N-methyl-N-cyclohexyl-octanthioamide (MCHTA) in toluene, since their ability to efficiently and selectively recover Pd(II) from a wide range of HCl concentrations is already known. Equilibrium data are presented and discussed, and further complemented by information depicted from UV–visible and NMR spectra. The determined apparent molar volumes show that MPHTA is monomeric, and MCHTA exhibits a slight tendency to aggregate. The Pd(II) extraction reactions by MPHTA and MCHTA are equivalent until 4.5 M HCl, passing through the formation of inner-sphere complexes with the metal ion.     

Automatic categorisation of comments in social news websites

The use of the social web has brought a series of changes in the way how content is created. In particular, social news sites link stories and the different users can comment them. In this paper, we propose a new method based on different features extracted from the text able to categorise the comments. To this end, we use a combination of statistical, syntactic and opinion features and machine-learning classifiers to classify a comment within three different categorisation types: the focus of the comment, the type of information contained in the comment and the controversy level of the comment. We validate our approach with data from ‘Menéame’, a popular Spanish social news site.     

Preliminary Developments of Miniplate-Type Fuel of U-2.5Zr-7.5Nb Alloy Dispersed and Cladded in Zircaloy

Nuclear fuel based on uranium metal alloys is utilized in research and test reactors. For the purpose of the reduction of fuel enrichment, high densities of uranium-235 in this kind of fuel are needed. This can be achieved when uranium alloys are used containing elements such as Zr, Mo and Nb. The construction of fuel element with high-uranium density requires materials with low cross sections for neutron absorption, stability under irradiation and absence of the chemical interactions between the fuel and cladding elements. In case of U-Zr-Nb alloys, Zry （zircaloy） cladding is a better option due to the fact that they have a higher chemical compatibility when compared with the use of aluminum alloys. This study aims to develop plate type nuclear fuel using the U-2.5Zr-7.5Nb alloy dispersed in Zry. Powders of this uranium based alloy and Zry were obtained by hydriding-dehydriding process. These powders were homogenized, compacted in pellet that was sandwiched in plates and frame of Zry. This assembly was hot rolled forming the dispersion fuel miniplate.     

Different ratios of carbon sources in the fermentation of cheese whey and glucose as substrates for hydrogen and ethanol production in continuous reactors

The fermentation of glucose, cheese whey and the mixture of glucose and cheese whey were evaluated in this study from two inocula sources (sludge from a UASB reactor for swine wastewater treatment and poultry slaughterhouse) for hydrogen production in continuous anaerobic fluidized bed reactors (AFBR). For all fermentations, a hydraulic retention time (HRT) of 6 h and a substrate concentration of 5 g COD L⁻¹ were used. In glucose fermentation, the maximum hydrogen yield (HY) was 1.37 mmol H₂ g⁻¹ COD. The co-fermentation of the cheese whey and glucose mixture was favorable for the concomitant production of hydrogen and ethanol, with yields of up to 1.7 mmol H₂ g⁻¹ COD and 3.45 mol EtOH g⁻¹ COD in AFBR2. The utilization of cheese whey as a sole substrate resulted in an HY of 1.9 mmol H₂ g⁻¹ COD. Throughout the study, ethanol fermentation was evident.     

A survey on nonlinear analog-to-digital converters

This paper presents a survey on Nonlinear Analog-to-Digital converters (ADC). This class of converters is extremely relevant in applications where there is a need for non-uniform quantization characteristic, for example, some specific applications in the areas of light detection, hearing aid, nuclear physics, image acquisition, communication systems, etc. This survey outlines the state-of-the-art Nonlinear ADC topologies, such as, floating point, logarithmic, piecewise linear and oversampled nonlinear converters, and discusses their performance and advantages in terms of their applications.     

Periodic orbits of oval billiards on surfaces of constant curvature

In this paper, we define and study the billiard problem on bounded regions on surfaces of constant curvature. We show that this problem defines a two-dimensional conservative and reversible dynamical system, defined by a Twist diffeomorphism, if the boundary of the region is an oval. Using these properties and defining good perturbations for billiards, we show that having only a finite number of nondegenerate periodic orbits for each fixed period is an open property for billiards on surfaces of constant curvature and a dense one on the hyperbolic plane. We finish this paper studying the stability of these nondegenerate orbits.     

Laboratory tests on the elimination of the pinewood nematode (Bursaphelenchus xylophilus) in Pinus pinaster wood by high pressure

The efficacy of high pressure processing, a non-thermal phytosanitary treatment, to eliminate Bursaphelenchus xylophilus in Pinus pinaster wood was evaluated. Infected wood sections and chips were exposed to high pressure processing for 5 min at 5, 15 and 30 MPa. Live nematodes were observed in wood sections and chips treated at 5 and 15 MPa but at 30 MPa no nematodes were detected. The results revealed that high pressure processing was successful in eliminating B. xylophilus from wood materials.     

Analysis of Grain Boundary Character in a Fine-Grained Nickel-Based Superalloy 718

In the current work, sheets of superalloy 718 were processed via thermomechanical route by hot and cold rolling, followed by annealing below the δ phase solvus temperature and precipitation hardening to optimum strength. Grain boundary character distribution throughout the processing was mapped via EBSD and its evolution discussed. The results show that it is possible to process the alloy to a fine grain size obtaining concomitantly a considerably high proportion of special boundaries Σ3, Σ9, and Σ27. The precipitation of δ phase presented a strong grain refining role, without significantly impairing the twinning mechanism and, consequently, the Σ3, Σ9, and Σ27 boundary formations.     

Analysis of the indoor GPS system as feedback for the robotic alignment of fuselages using laser radar measurements as comparison

The alignment of aircraft fuselages in the aerospace sector is currently done either manually or by complex, expensive automated systems. The manual process introduces a significant production delay and the automated systems are purpose-built and have limited flexibility, apart from its financial drawback. This work proposes a low-cost, high-flexibility system and, as part of it, evaluates the performance of a Rotary-Laser Automatic Theodolite (R-LAT) as a feedback source for the adaptive robot control of an anthropomorphic manipulator. In the proposed solution the robot carries a fuselage barrel and aligns it with respect to a second barrel. A high accuracy, frequency-modulated laser equipment is used to generate the reference system for the procedure. The measurements of the R-LAT are then verified with the frequency-modulated laser equipment in order to determine the linear and angular alignment tolerances achieved by the robot/R-LAT closed loop in a predefined work envelope. A throughout, step-by-step analysis of the measuring procedure is carried out to allow the recognition of error sources and thus the determination of an optimized method. These results identify the operation boundaries of the R-LAT within the process and yield its best configuration for the intended purpose. Using the EN ISO 9283 robot evaluation standard, the closed loop system was found to attain the nominal position with an average accuracy of 0.38 mm and 0.01°, contrasting with an average accuracy of 4.53 mm and 0.21° when the robot was operating in an open loop configuration.     

Real time algorithms for digital pulse processing applied to gamma-ray and hard X-ray spectroscopy

The duration of a single plasma discharge in the next generation of fusion experiments will be much longer than in the present devices. Storing all raw data acquired in each discharge will be more difficult and the high rates achieved by the new digitizers are already contributing to storage overload. This gap can be mitigated by real time (RT) analysis and compression, using devices such as field programmable gate arrays (FPGAs) capable to transfer and process data on the fly. However, to ensure a correct RT analysis, the FPGA algorithm must be adapted to the signal to be acquired. Since minor changes in signal shape may require significant algorithm modifications, it is important to know in advance the signal attributes. For that reason, the availability of more than one RT algorithm, especially during commissioning of new sub-systems and during campaigns with relevant changes in diagnostic conditions, is advantageous. This paper presents an implementation using two RT algorithms processing simultaneously, developed for the gamma-ray and hard X-ray diagnostics of the Joint European Torus (JET). Both algorithms perform pulse height analysis with pile-up rejection. While the first algorithm is suitable for Gaussian shaped pulses, the second is suitable for exponential signals. The algorithms are selectable by the user, during discharge configuration. Tests with radioactive sources made in JET are presented.