Coil coating is a continuous strip coating technology, which enjoyed rapid growth. It provides a cost-effective method of applying a coating to a metal substrate with a low solvent emission, and nowadays paints of different nature are applied this way on a range of metal substrates, for a large variety of products and uses.
Coil coatings can be more or less degraded by high UV radiation. However, differences in distribution of light intensity as a function of wavelength between exposure environments, can lead to significant differences in the degradation results, depending on coating nature. In this work, the behaviour of polyester and silicone polyester coatings exposed in three different high UV environments (natural atmosphere and two accelerated UV tests), was studied. Coatings of two different colours (blue and brown) were considered for each paint system. Colour change, gloss and chalking measurements and, visual inspections of coating defects were carried out. In order to explain their corresponding performance, chemical changes on coil coated exposed surfaces were studied by to Fourier transform infrared spectroscopy equipped with a photoacustic detector (PAS/FTIR). 相似文献
We present a new text-to-image re-ranking approach for improving the relevancy rate in searches. In particular, we focus on the fundamental semantic gap that exists between the low-level visual features of the image and high-level textual queries by dynamically maintaining a connected hierarchy in the form of a concept database. For each textual query, we take the results from popular search engines as an initial retrieval, followed by a semantic analysis to map the textual query to higher level concepts. In order to do this, we design a two-layer scoring system which can identify the relationship between the query and the concepts automatically. We then calculate the image feature vectors and compare them with the classifier for each related concept. An image is relevant only when it is related to the query both semantically and content-wise. The second feature of this work is that we loosen the requirement for query accuracy from the user, which makes it possible to perform well on users’ queries containing less relevant information. Thirdly, the concept database can be dynamically maintained to satisfy the variations in user queries, which eliminates the need for human labor in building a sophisticated initial concept database. We designed our experiment using complex queries (based on five scenarios) to demonstrate how our retrieval results are a significant improvement over those obtained from current state-of-the-art image search engines. 相似文献
In this paper we present a robust and lightweight method for the automatic fitting of deformable 3D face models on facial images. Popular fitting techniques such as those based on statistical models of shape and appearance require a training stage based on a set of facial images and their corresponding facial landmarks, which have to be manually labeled. Therefore, new images in which to fit the model cannot differ too much in shape and appearance (including illumination variation, facial hair, wrinkles, etc.) from those used for training. By contrast, our approach can fit a generic face model in two steps: (1) the detection of facial features based on local image gradient analysis and (2) the backprojection of a deformable 3D face model through the optimization of its deformation parameters. The proposed approach can retain the advantages of both learning-free and learning-based approaches. Thus, we can estimate the position, orientation, shape and actions of faces, and initialize user-specific face tracking approaches, such as Online Appearance Models (OAMs), which have shown to be more robust than generic user tracking approaches. Experimental results show that our method outperforms other fitting alternatives under challenging illumination conditions and with a computational cost that allows its implementation in devices with low hardware specifications, such as smartphones and tablets. Our proposed approach lends itself nicely to many frameworks addressing semantic inference in face images and videos. 相似文献
A previous investigation of the chlorobenzene combustion activity of VOx/TiO2, VOx–WOx/TiO2 and VOx–MoOx/TiO2 catalysts in the presence of NO pointed out the activation effect of NO. The suggested three-step mechanism based on catalytic performances data only was: (1) chlorobenzene is oxidized on the surface of the VOx phase (as described by Mars–van Krevelen), (2) NO gets oxidized to NO2, mainly on WOx and MoOx, and (3) the in situ produced NO2 assists O2 in the reoxidation of the VOx phase thus speeding up the oxidation step of the Mars–van Krevelen mechanism. The latter effect macroscopically corresponds to the observed increase of chlorobenzene conversion. This contribution aims at validating this hypothetical mechanism by pointing out the favourable occurrence of an oxidation of NO to NO2 on the WOx and MoOx phases and by pointing out the higher efficiency of NO2 than O2 to reoxidize the reduced VOx sites. In addition, the present contribution clearly demonstrates that, in the absence of NO, the chlorobenzene total oxidation occurred following the Mars–van Krevelen mechanism. Moreover, a thorough characterization of the oxidation state of the vanadium proving that the improvement of the catalyst activity brought by the simultaneous presence of NO and O2 is linked to the stronger reoxidation of the VOx active phase. Furthermore, plotting all the catalytic activity data versus the mean vanadium oxidation level clearly depicts, for the first time, the strong dependence between them. Under a mean vanadium oxidation level of 4.82 the catalyst is inactive while above 4.87 the activity is stabilized at a high level of conversion independent of the vanadium oxidation level. 相似文献
Deuterium (δD) and oxygen (δ18O) isotope data from the Rio Capim kaolin, northern Brazil, were combined with optical studies in order to better understand the genesis and evolution of the kaolinites. The results show that δ18O values from a lower soft kaolin unit range from 6.0‰ to 19.2‰ for Ka (size ranging from 1 to 3 μm) and Kb (size ranging from 10 to 30 μm) kaolinites, and from 15.4‰ to 24.9‰ for Kc (size < 200 nm) kaolinites. The δD values range from − 63.1‰ to 79.5‰ for the Ka + Kb kaolinites, and from − 68.8‰ to − 244.35‰ for the Kc kaolinites. An upper semi flint kaolin unit, dominated by Kc kaolinites, displays δ18O and δD values ranging from 15.1‰ to 21.8‰, and − 71.3‰ to − 87.4‰, respectively. Based on these data, and on the δ18O and δD values obtained for the surface meteoric water and groundwater, it can be concluded that the kaolinites are not in equilibrium with the modern weathering environment, but they reflect isotopic compositions of the formation time, probably due to the interaction with fossil groundwater. However, mineralogical contaminations derived from replacements of framework grains also had great influence in the isotopic composition of these kaolinites. In addition, the isotope values of the Kc kaolinites from the semi-flint kaolin unit is variable, which is due to the presence of Kc kaolinites of different origins, including kaolinites derived from the underlying soft kaolin unit, kaolinites formed during different phases of paleoweathering, as well as later phases of coarse-grained kaolinites formed along fractures. Due to these complexities, binary diagrams contrasting δ18O and δD values, worldwide applied for distinguishing supergenic from hypogenic kaolinites, as well as those formed under weathering conditions, can not be applied to interpret the origin of the kaolinites in the Rio Capim Kaolin. 相似文献
A fluidized bed reactor has been used to investigate the partial oxidation of methane to syngas over a NiO/NiAl2O4 catalyst. The axial concentration profiles of the different species along the bed have been determined and related to the observed temperature profiles. The amount of carbon deposited on the catalyst under different operating conditions has also been determined. The results show that under suitable conditions, the bubbling fluidization regime gives a stable reactor performance with high conversion and selectivity, and a limited amount of carbon formation. 相似文献
Business Process Management (BPM) has gained a lot of popularity in the last two decades, since it allows organizations to manage and optimize their business processes. However, purchasing a BPM system can be an expensive investment for a company, since not only the software itself needs to be purchased, but also hardware is required on which the process engine should run, and personnel need to be hired or allocated for setting up and maintaining the hardware and the software. Cloud computing gives its users the opportunity of using computing resources in a pay-per-use manner, and perceiving these resources as unlimited. Therefore, the application of cloud computing technologies to BPM can be extremely beneficial specially for small and middle-size companies. Nevertheless, the fear of losing or exposing sensitive data by placing these data in the cloud is one of the biggest obstacles to the deployment of cloud-based solutions in organizations nowadays. In this paper we introduce a transformation-based approach that allows companies to control the parts of their business processes that should be allocated to their own premises and to the cloud, to avoid unwanted exposure of confidential data and to profit from the high performance of cloud environments. In our approach, the user annotates activities and data that should be placed in the cloud or on-premise, and an automated transformation generates the process fragments for cloud and on-premise deployment. The paper discusses the challenges of developing the transformation and presents a case study that demonstrates the applicability of the approach. 相似文献