DNA promotes the activation of oxygen molecules by binuclear cobalt(II) compounds

We have observed that binuclear cobalt(II) compounds with H(HPTP), Co₂(HPTP)(CH₃COO)(ClO₄)₂ and Co₂(HPTP)Cl(ClO₄)₂, react with oxygen molecules when DNA is present in the solution, cleaving the DNA (H(HPTP) denotes N,N,N′,N′-tetrakis(2-pyridylmethyl)-1,3-diaminopropane-2- ol).     

Preparation of helical carbon and graphite films using morphology-retaining carbonization

Helical carbon and graphite films were prepared from iodine-doped helical polyacetylene (H-PA) film using currently developing morphology-retaining carbonization. It was found from scanning electron microscopy (SEM) observations that the hierarchical helical morphology of the H-PA film remains unchanged even after the carbonization at 800 °C. Besides, the weight loss of the film due to the carbonization was very small, which was only a few percent to the weight of the film before doping. Furthermore, the graphite film prepared by the subsequent heating at 2600 °C still retained the same morphology as those in the original H-PA film and in the helical carbon film prepared at 800 °C. X-ray diffraction (XRD) and Raman scattering measurements were then pursued. The results showed that graphitic crystallization proceeds in the carbon film through the heat treatment at 2600 °C. Transmission electron microscopy (TEM) image of a single helical graphitic fibril was also observed by ultrasonicating the graphite film in ethanol. Carbonization of the H-PA films by way of iodine doping was found to afford helical carbon and graphite films, where spiral morphologies and even helical fibril structures were completely preserved.     

Organic LED full-color passive-matrix display

Abstract— A full-color 5.2-inch 1/4-VGA passive-matrix organic LED display has been developed, adopting selective deposition for the different emitting materials. The display features 320 (×3) × 240 pixels with an equivalent pixel size of 0.33 × 0.33 mm, white peak luminance of over 150 cd/m², and power consumption of 6 W.     

Effect of polyacrylic acid (PAA) binder system on particle orientation during dry-pressing

Effect of polyacrylic acid (PAA) binder system on the development of particle orientation during uniaxial pressing is reported. Granules of different properties were compacted using uniaxial pressing at various pressure and their degree of particle orientation (DPO) was determined. The increment trend of DPO varies with granule strength and shows higher value for binder system of higher flexibility. Anisotropic shrinkage related to particle orientation is shown by compact of higher relative density (RD) and DPO; whereas anisotropic shrinkage related to non-uniform packing density is shown by compact of lower RD and DPO. Anisotropic shrinkage remains in the former compact while isotropic shrinkage was obtained for the latter compact at sintering temperature of 1600 °C. Subsequent cold isostatic pressing increases DPO and sintering shrinkage ratio of uniaxially pressed compacts.     

Chemical heat-pump system working at exhaust temperatures of high-temperature-gas-cooled reactor

A chemical heat-pump system using two hydrogen-absorbing alloys is proposed to utilize heat exhausted from a high-temperature source such as high-temperature-gas-cooled reactor, HTGR, which is designed to produce H₂ more efficiently. The overall system proposed here consists of HTGR, He gas turbines, chemical heat pumps and reaction vessels corresponding to the three-step decomposition reactions comprising the I–S process. A fundamental research is performed experimentally on heat generation in a single bed packed with a hydrogen-absorbing alloy that works at the H₂ production temperature. The hydrogen-absorbing alloy of Zr(V_1−xFe_x)₂ is selected as a material that has a proper plateau pressure for the heat-pump system operated between the input and output temperatures of HTGR. Temperature jump due to heat generated when the alloy absorbs H₂ proves that the alloy–H₂ system can heat up the exhaust gas even at 600 °C without any external mechanical force.     

Theoretical and Experimental Study of Water Transport in a Hollow Cylinder Applied to the Drying of Round Squid Mantle

ABSTRACT

Until now, attention has been focused solely in the drying of squid mantle from an experimental point of view, neglecting the transport phenomenon studies of water in squid muscle. This work studies the drying of squid mantle (Loligo brasiliensis), previously salted and smoked by liquid smoking (hickory extract), using a tubular dryer in closed cycle with a silicagel fixed bed in series. The mass transfer phenomenon during drying was studied, based on the Fick's second law, with the effective diffusivity supposed constant, which enabled an analytical solution to the problem. The drying curve calculated with the resulting equation was compared with experimental data. The model was applied to a hollow cylinder geometry (round squid mantle), with its internal surface isolated from the drying environment by a plastic film. The latter was given a tubular form and introduced inside the mantle cavity (impervious wall boundary condition).     

Study on sustainable redevelopment of a densely built-up area in Tokyo by introducing a distributed local energy supply system

“Distributed local energy systems” had been expected to rationalize the supply of energy to built-up areas, but until now very little research has been performed to estimate the effect of their application to actual cities. In this research, therefore, a future vision for the year 2030 in the Sancha Area (SANCHA VISION 2030), a typical densely built-up area in Tokyo, has been elaborated including a simulation to estimate benefits from the application of distributed energy systems in terms of reduced energy consumption and CO₂ emissions as well as mitigation of the heat-island phenomenon. As a result, it was demonstrated that a “distributed local energy system”, which provides a district with both electrical power and heat through an integrated distribution system, may contribute to a considerable improvement in energy efficiency for those areas. In addition, it may also provide other benefits, including enhancement of living amenity and urban security in times of emergency.     

A Microcomputer System for Spatiotemporal Visual Receptive Field Analysis

A microcomputer system was developed to measure visual spatiotemporal receptive fields. The system performs three functions: 1) generation of a binary spatiotemporal white-noise stimulus, 2) acquisition of spike discharges from retinal ganglion cells, and 3) extraction of the linear part of the spatiotemporal receptive flelds by cross correlating the input against the output. We have applied this system to the measurement of the spatiotemporal receptive fields of cat and catfish retinal ganglion cells.     

Reduction of return current noise by energy‐compensating active control

A newly proposed energy‐compensating active control is implemented to reduce the return current noise which is caused by inverter‐driven electric car systems. The energy‐compensating active control detects the energy charged at the filter capacitor, and reduces the energy and current of the noise frequency component by simple feedback loop incorporated with the conventional motor torque controller. No additional sensors or circuit arrangements are necessary; therefore, the return current can be attenuated effectively without any further cost. The return current with an inverter system is measured using a current probe and an FFT analyzer, and it is shown that the 25‐Hz noise current is reduced by up to 10 dB with the control. The results reveal that the low‐frequency return current noise can be attenuated with the simple control scheme, which would expectedly reduce the size of filter reactors and capacitors to meet the current limit level of the signaling system's track relays. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 165(4): 84–91, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20615