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41.
Victor V. Ivanov Sergei D. Kirik Alexander А. Shubin Irina A. Blokhina Victor M. Denisov Lilya А. Irtugo 《Ceramics International》2013,39(4):3843-3848
A saturated acidic aluminum chloride solution with a total composition of AlCl3·HCl·12H2O was obtained, and its behavior under thermal treatments was studied using thermogravimetry, differential scanning calorimetry and mass spectrometry techniques. The thermolysis solid products were characterized with XRD and SEM. Four stages of the thermolysis could be distinguished. Initially, the solution lost free water molecules, and an amorphous precipitate with an approximate composition AlCl3·HCl·12 H2O was obtained as a product. The precipitate released eight water molecules in the temperature range 390–425 K. Then, all chlorine atoms in the form of HCl and two water molecules were outgassed at 425–485 K. The product completely lost water up to 650 K. The crystallization of the solid begins with appearance of the phase γ-Al2O3 at 1073 K, and the final product, α-Al2O3, is observed at 1323 K. The application of the saturated trichloride solutions as a binder and a promoter for activated sintering of composite ceramics on the base of alumina was examined. 相似文献
42.
James A. Kimber Sergei G. Kazarian František Štěpánek 《Chemical engineering science》2012,69(1):394-403
This work presents a novel use of the Discrete Element Method (DEM) combined with inter-particle mass transfer in order to simulate polymer swelling and dissolution. Each particle can absorb water and swell, pushing on its neighbours and causing an overall expansion. Once the disentanglement threshold is reached, the polymer dissolves and the particle reduces in size. This paper applies DEM to simulate the radial swelling and dissolution of cylindrical tablets. The method was validated against exact numerical solution of the same system to assess the accuracy of the DEM simulations for different DEM particle sizes. Parametric studies were done to assess the impact of physical parameters – namely the concentration-dependent diffusion coefficient of water through the polymer, the dissolution rate constant of the polymer and the disentanglement threshold of the polymer – on the radial expansion of the tablet. It was found that different settings of the concentration-dependent water diffusion coefficient function could produce similar radial expansion curves but with different internal concentration profiles. Increasing the dissolution rate constant or decreasing the disentanglement threshold of the polymer caused a reduction in the maximum radius of tablet. Lastly, ATR-FTIR spectroscopic imaging was used to obtain chemical images of a pure hydroxy-propyl methylcellulose (HPMC) tablet swelling and dissolving. The model was optimised to match both the HPMC tablet radius and the concentration profiles over time. 相似文献
43.
Sergei Alexandrov 《Engineering Fracture Mechanics》2010,77(16):3368-3371
A new plane strain upper bound solution for highly undermatched welded tensile panels with a crack is proposed. A distinguished feature of this solution is that the crack is arbitrarily located within the weld and its shape is also arbitrary, though some restrictions do apply. The latter are explained in detail such that the class of structures for which the solution is applicable is precisely specified. The solution is given in a very simple closed form. 相似文献
44.
A numerical THD model is developed to investigate the effect of lining compliance on the bearing characteristics. The analysis shows increased load carrying capacity, significantly reduced peak pressures and thicker oil film in the loaded zone compared to a white metal bearing. Slightly thinner oil films are predicted at the bearing edges. Temperature and power loss are found to be similar for some load-speed combinations but higher for other operating conditions. It is also shown that load carrying capacity is more sensitive to thermal expansion while pressure and oil film thickness profiles are more sensitive to elastic deformation. 相似文献
45.
The cationic polymerization of cyclopentadiene (CPD) with 1-(4-methoxyphenyl)ethanol (1)/BF3OEt2 initiating system in CH2Cl2:CH3CN 4:1 (v/v) mixture at room temperature and in the presence of water ([H2O]/[BF3OEt2] up to 8) is reported. The number-average molecular weights of obtained polymers increased in direct proportion to monomer
conversion or initial monomer concentration (M
n ≤ 4,000 g mol−1) in agreement with calculated values, and were inversely proportional to initiator concentration. Polymer MWDs were relatively
narrow (M
w/M
n = 1.4–1.7) up to 60% of monomer conversion. It was also shown that regioselectivity of CPD polymerization with 1/BF3OEt2 initiating system did not depend significantly on water, monomer, or initiator concentration (1,4-structures content was
nearly 60% in all cases). 相似文献
46.
Sergei F. Burlatsky Vadim V. Atrazhev Mallika Gummalla Dave A. Condit Fuqiang Liu 《Journal of power sources》2009,190(2):485-492
Proper water management in a hydrogen-fueled polymer electrolyte membrane (PEM) fuel cell is critical for performance and durability. A mathematical model has been developed to elucidate the effect of thermal conductivity and water vapor diffusion coefficient in the gas diffusion layers (GDLs). The fraction of product water removed in the vapor phase through the GDL as a function of GDL properties/set of material and component parameters and operating conditions has been calculated. The current model enables identification of conditions wherein condensation occurs in each GDL component. The model predicts the temperature gradient across various components of a PEM fuel cell, providing insight into the overall mechanism of water transport in a given cell design. The water condensation conditions and transport mode in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDLs and water transport scenarios are defined in this work, based on water condensation in the GDL and fraction of water that the GDL removes through the vapor phase, respectively. 相似文献
47.
A wavelength-independent method for optical gating, based on the optical Kerr effect, has been demonstrated. Using this method, we produced 100-ps, 10-kW, two-wavelength pulses (10.3 and 10.6 microm) with a signal-to-background ratio contrast of 10(5) by slicing a long CO2 pulse. The capability of gating consecutive pulses separated on a picosecond time scale with this method is also shown. 相似文献
48.
49.
50.
Sergei V. Kostjuk Alexei Yu. Dubovik Irina V. Vasilenkol Vyacheslav P. Mardykin Ludmila V. Gaponik Fyodor N. Kaputsky Lev M. Antipin 《Polymer Bulletin》2004,52(3-4):227-234
Summary
Quasiliving cationic polymerization of styrene was obtained in the system 2-phenyl-2-propano-/AlCl3·OBu2/Bu2O in a mixture of 1,2-dichloroethane and n-hexane (55:45 viv) at -15 °C. The molecular weights of the polymers (Mn) increased in direct proportion to the monomer conversion. However, the experimental Mns are essentially higher than theoretical ones, indicating that slow initiation relative to propagation takes place. The molecular weight distributions were broad (Mw/Mn2.5), probably due to the slow initiation and slow exchange between reversibly terminated and propagating species. 相似文献