Forward osmosis (FO), as an emerging technology, is influenced by different factors such as operating conditions, module characteristics, and membrane properties. The general aim of this study was to develop a suitable (flexible, comprehensive, and convenient to use) computational tool which is able to simulate osmosis through an asymmetric membrane oriented in pressure retarded osmosis (PRO) mode in a wide variety of scenarios. For this purpose, an agent-based model was created in NetLogo platform, which is an easy-to-use application environment with graphical visualization abilities and well suited for modeling a complex system evolving over time. The simulation results were validated with empirical data obtained from literature and a great agreement was observed. The effect of various parameters on process performance was investigated in terms of temperature, cross-flow velocity, length of the module, pure water permeability coefficient, and structural parameter of the membrane. Results demonstrated that the increase in all parameters, except structural parameter of the membrane and the length of module led to the increase of average water flux. Moreover, nine different draw solutes were selected in order to assess the influence of net bulk osmotic pressure difference between the draw solution (DS) and feed solution (FS) (known as the driving force of FO process) on water flux. Based on the findings of this paper, the performance of FO process (PRO mode) can be efficiently evaluated using the NetLogo platform. 相似文献
Transport of copper ions through nanocomposite chitosan/polyvinyl alcohol thin adsorptive membranes has been mathematical y investigated in the current study. Unsteady-state diffusive transport model was coupled with the Freundlich isotherm to predict the concentration of the ions in dialysis permeation operation. Pristine model was not successful in predicting the experimental data based upon its low coefficients of determination (0.1﹤R2﹤0.65). Well-behaved polynomial and exponential functions were used to describe time-dependency of the inlet-concentration in the first extension of the model with a little improvement in the model adjustment (0.4﹤R2﹤0.69). Similar time-dependent functions were employed for tracking the ion diffusivity and then applied in combination with the optimized functions of inlet-concentration in the second extension of the model. A sensible enhancement was obtained in the adjustment of the second extended models as a result of this combination (0.73﹤R2﹤0.93). APRE, AAPRE, RSME, RMSE, STD and R-square statistical analyses were per-formed to verify the agreement of the models with the experimental results. Concentration distribution versus time and location (inside the membrane) was obtained as 3D plots with the help of the optimized models. Modeling results emphasized on the transiency of diffusivity and feed-side concentration in dialysis permeation through chitosan membranes. 相似文献
In this paper, we have produced carboxylic acids by the oxidation of various alcohols in the presence of CO2 using SBA-15/IL supported Cu(II) (SBA-15/IL/Cu(II)) as nanocatalyst. The obtained products showed to have excellent yields by taking into account of SBA-15/IL/Cu(II) nanocatalyst. In addition, the analysis of EDX, SEM, TGA, TEM, XPS, and FT-IR showed the heterogeneous structure of SBA-15/IL/Cu (II) catalyst. It is determined that, after using SBA-15 excess, the catalytic stability of the system was enhanced. Moreover, hot filtration provided a full vision in the heterogeneous catalyst nature. The recycling as well as reuse of the catalyst were studied in cases of coupling reactions many times. Moreover, we have studied the mechanism of the coupling reactions.
Despite good rigidity, braced frames have weak nonlinear behavior and inadequate distribution of ductility in stories, which cause significant structural damage. In this research, a seismic resistant system called coupled concentrically braced frame (CCBF) is developed to enhance the performance of braced frames by coupling them with a beam. In this case, the coupling beams are the primary source for ductility of the system, and after their yielding in more severe earthquakes, the structure continues to benefit from the ductility of the braces as the secondary source; therefore, the system has two-level behavior caused by different probable seismic excitations. In this case, in addition to maintaining the stiffness of the two concentrically braced frames, the coupling beams resist against the movement of the braced frames, and as a result, the stiffness of the system is increased. Therefore, lighter elements can be used to resist lateral loads. Linear and nonlinear analyses of CCBF, and its comparison with other braced frames, indicate that participation of the coupling beams provides an adequate stiffness and ductility. These frames have more stable nonlinear behavior than conventional ones and continue their nonlinear behavior even after fracture of coupling beams in severe earthquakes. 相似文献
Applying toxic chemical to the synthesis of stable gold nanoparticles is one of the limitations of gold nanoparticles for therapeutic applications such as photothermal therapy. Plant compounds such as apigenin (API) with therapeutic potential can be applied in the synthesis of gold nanoparticles. API‐coated gold nanoparticles (Api@AuNPs) with an average size of 19.1 nm and a surface charge of −4.3 mV have been synthesized by a simple and efficient technique. The stability of Api@AuNPs in the biological environment was verified through UV‐Vis spectroscopy. Based on Raman and FTIR spectroscopy analysis, chemical binding of API on the surface of Api@AuNPs through hydroxyl and carbonyl functional groups was found to be the main reason for the stability of the Api@AuNPs in comparison with citrate‐coated gold nanoparticles (Cit@AuNPs). The synthesized Api@AuNPs do not cause major toxic effects up to 128 ppm. Api@AuNP‐mediated photothermal therapy leads to the indiscriminate eradication of almost half of both mouse fibroblastic (L929) and colorectal cancer (CT26) cells. Flow‐cytometry analysis revealed that the cell death mechanism is mainly apoptosis. In the apoptosis triggered cell death in photothermal treatment, Api@AuNPs are preferred over commonly used gold nanoparticles in photothermal treatments which mostly trigger the necrosis cell death pathway. 相似文献
Today, the development of urbanization and increasing the number of vehicles has resulted in displeased consequences like traffic congestion and vehicle queuing. The vast majority of countries in the world encounter the challenge of the explosive rise in traffic demand. In this regard, it is necessary to meet traffic demand in transport networks, especially in metropolitans. In traffic management and shortening the trip duration, traffic lights on the signalized intersections play an essential role in urban pathways. This work provides a multi-criteria decision-making method for optimum traffic light control in an isolated corner. The main idea involves establishing a set of sub-optimal solutions for traffic light timing and selecting the best one among the diverse solutions. We have mathematically modelled the problem as an optimization problem to achieve an optimal solution with less waiting time for vehicles in intersections and the lowest cost. Genetic algorithm (GA) and Teaching-Learning-based Optimization (TLBO) are utilized for each phase to create a set of suitable timing scenarios. The Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) method is used to identify the best scenario, considering both waiting vehicles and traffic capacity as decision criteria. Its efficiency has been demonstrated over three different traffic volumes. Also, in a real-world implementation, its practical capability has been approved at a crossroads in Mashhad, Iran. The simulations indicate the improvement in the number of vehicles waiting behind the crossroad and the traffic capacity by 10% and 6.76% compared to the existing signal timing of the studied intersection, respectively. 相似文献
During disasters, swiftly and efficiently evacuating populations in hazardous situations is crucial to minimize losses. This study proposes a novel framework to address dynamic population evacuation (DPE) problems, which includes planning and online evacuation management phases facilitated by vehicular communication. In the planning phase, a shelter allocation problem (SAP) is solved dynamically for destination choice and a dynamic traffic assignment (DTA) for path choice toward the chosen destinations to obtain an initial evacuation plan. The initial plan is then enhanced by employing a vehicular ad hoc network (VANET) within the vehicular edge computing (VEC) architecture. This enhancement enables communication among evacuees, allowing them to revise their vehicle's route choice and planned destination. These revisions take into account the changing risk and traffic conditions. The proposed online DPE framework is applied to the real evacuation scenario of Mill Valley City, CA. The proposed model is evaluated with different VANET architectures, including vehicular cloud computing (VCC) and VEC. The results show that the VEC framework outperforms other configurations and improves the evacuation process compared to the scenario with an initial plan by more than 30% in network clearance time. Additionally, a performance analysis is carried out for evacuation scenarios with different penetration rates of connected vehicles in VANET. 相似文献
A four-phase program to improve the specific energy absorbed by axially crushed composite collapsible tubular energy absorber devices was undertaken. In the first phase, examining of the crushing behaviour of non-triggered tubes was carried out. The second phase is aimed at obtaining the best position for the triggered wall. The third phase focuses on the effects of material sizing in order to understand the influence of triggered wall length on the responses of composite circular tubes to the axial crushing load. The results of these three phases of the study contribute to the fourth whose objective is to optimize the shape geometry of the cross-section area to further improving in tube energy absorption capability. The experimental results demonstrated the strong potential benefits of optimizing the material distribution. The sizing and shape optimization of composite collapsible tubes exhibited a pronounced effect on their capability to absorb high specific energy under axial compressive load. 相似文献
In this research, the centrifugal compressor of a turbocharger is investigated experimentally and numerically. Performance characteristics of the compressor were obtained experimentally by measurements of rotor speed and flow parameters at the inlet and outlet of the compressor. Three dimensional flow field in the impeller and dif- fuser was analyzed numerically using a full Navier-Stokes program with SST turbulence model. The performance characteristics of the compressor were obtained numerically, which were then compared with the experimental results. The comparison shows good agreement. Furthermore, the effect of area ratio and tip clearance on the performance parameters and flow field was stud- ied numerically. The impeller area ratio was changed by cutting the impeller exit axial width from an initial value of 4.1 mm to a final value of 5.1 mm, resulting in an area ratio from 0.792 to 0.965. For the rotor with exit axial width of 4.6 mm, performance was investigated for tip clearance of 0.0, 0.5 and 1.0 mm. Results of this simula- tion at design point showed that the compressor pressure ratio peaked at an area ratio of 0.792 while the effi- ciency peaked at a higher value of area ratio of 0.878. Also the increment of the tip clearance from 0 to 1 mm resulted in 20 percent efficiency decrease. 相似文献