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91.
Conclusions The change in some properties of polyvinyl fluoride during the process of fibre spinning has been investigated.It has been found that during the process of converting PVF powder into fibre, the degree of polymer crystallinity plus its resistance to thermal and thermooxidative degradation is increased; depending on the spinning regime, the densities and physicomechanical properties of PVF fibres are different.Translated from Khimicheskie Volokna, No. 4, pp. 34–35, July–August, 1984. 相似文献
92.
N. N. Belov Yu. A. Biryukov A. T. Roslyak N. T. Yugov S. A. Afanas’eva 《Theoretical Foundations of Chemical Engineering》2005,39(3):307-312
A new circulation pneumatic crusher capable of producing submicron powders of refractory materials is presented. A mathematical model is constructed for the dynamic breaking of ceramic macroparticles. This model allows the basic laws of shock-wave crushing in the circulation pneumatic apparatus to be analyzed.__________Translated from Teoreticheskie Osnovy Khimicheskoi Tekhnologii, Vol. 39, No. 3, 2005, pp. 327–333.Original Russian Text Copyright © 2005 by Belov, Biryukov, Roslyak, Yugov, Afanas’ev. 相似文献
93.
A new phenomenon accompanying the electrolysis of salts has been observed, whereby an ordered composite is formed under certain conditions (electrolyte composition, current density). The composite comprises an inorganic salt crystal penetrated by metal nano- and microwires. This phenomenon can serve as a basis for the technology of oriented and ordered nanowire array synthesis. 相似文献
94.
S. V. Ivanova 《Materials Science》2007,43(5):718-724
We have established that technological defects (cracks) in zirconium articles can develop in the course of long-term storage
prior to their mounting in a reactor, which is caused by the action of residual stresses and hydrogen. We have considered
the conditions of after-operation storage of zirconium articles of the fuel core of thermal reactors in water of the cooling
ponds of reactors and in spent-fuel storehouses. The possibility of subsequent hydrogenation of these articles during their
storage has been shown. Finally, we have studied the effect of hydrogen, absorbed in the course of storage, on the crack resistance
of zirconium articles and the development of defects in them due to delayed hydride cracking.
__________
Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 5, pp. 105–109, September–October, 2007. 相似文献
95.
Jonathan P. Belnoue Giang D. Nguyen Alexander M. Korsunsky 《International Journal of Fracture》2007,144(1):53-60
This paper presents a new 1-D non-local damage-plasticity deformation model for ductile materials. It uses the thermodynamic
framework described in Houlsby and Puzrin (2000) and holds, nevertheless, some similarities with Lemaitre’s (1971) approach.
A 1D finite element (FE) model of a bar fixed at one end and loaded in tension at the other end is introduced. This simple
model demonstrates how the approach can be implemented within the finite element framework, and that it is capable of capturing
both the pre-peak hardening and post-peak softening (generally responsible for models instability) due to damage-induced stiffness
and strength reduction characteristic of ductile materials. It is also shown that the approach has further advantages of achieving
some degree of mesh independence, and of being able to capture deformation size effects. Finally, it is illustrated how the
model permits the calculation of essential work of rupture (EWR), i.e. the specific energy per unit cross-sectional area that
is needed to cause tensile failure of a specimen. 相似文献
96.
The polycrystalline samples of Dy
x
Bi1−x
FeO3 (x = 1, 0.8, 0.6, 0.4 and 0.2) were synthesized by standard solid state reaction technique. The samples synthesized were characterized
by X-ray diffraction (XRD) technique. Further the samples were characterized by infrared (IR) spectroscopic technique. The
dielectric measurements were carried out as a function of frequency in the range 100 Hz to 1 MHz at room temperature. Also
the dielectric measurements were carried out as a function of temperature at certain fixed frequencies. The ac and dc resistivity
measurements were carried out using two probe method. Also temperature dependence of ac and dc resistivity was noted. These
measurements suggest polaron conduction in the samples. Finally, the data from XRD, IR, dielectric measurements were correlated. 相似文献
97.
A phenomenological model is developed for describing the kinetics of the crystallite size refinement process of Cu powder
under mechanical treatment conditions. Based on the evidence that collisions represent the elementary events of energy transfer,
the rate of crystallite size decrease is related on a statistical basis to the amount of powder trapped at each collision,
to the number of collisions and to the collision energy. The mathematical approach allows for identifying the approximate
functional form of the kinetic curves obtained at largely different impact energies. The values of the apparent kinetic constants
and of the model parameters involved can be thus estimated by fitting the model curves to the experimental data. The results
obtained provide a deeper insight into the details of the crystallite size refinement process. 相似文献
98.
The equilibrium shape and dihedral angles at the solid–liquid–vapor tri-junctions of two-phase alloy small particles containing
a cusp-oriented interface were modeled as a function of phase fraction, surface energy and the interfacial energy. The calculation
was applied to different combinations of surface and/or interfacial energies to demonstrate the various possible particle
shapes and dihedral angles that result for two-phase particles. The dihedral angles at the tri-junction vary with the phase
fraction, due to the coupling between the relative amounts of each phase, interfacial energy relative to the two surface energies
and the equilibrium conditions at the tri-junction. These features can be used to find the ratio of the interfacial energy
to the surface energies of two-phase particles for any state of matter. 相似文献
99.
Reaction models are proposed to quantify the hydration products and to determine the composition of C–S–H from alkali-activated
slags (AAS). Products of the slag hydration are first summarized from observations in literature. The main hydration products
include C–S–H, hydrotalcite, hydrogarnet, AFm phases (C4AH13 and C2ASH8) and ettringite. Then, three stoichiometric reaction models are established correlating the mineral composition of slag (the
glass part) with the hydration products. Using the proposed models, quantities of hydration products and composition of C–S–H
are determined. The models are validated with a number of experimental investigations reported in literature, yielding good
agreement, i.e., these models can successfully predict the hydration reaction of AAS. The models are furthermore applied to
calculate the retained water in the hydration products of AAS in different hydration states and a general hydration equation
of AAS is derived. As an illustration to one of the model applications, chemical shrinkage of the AAS cement paste in different
hydration states are predicted. The chemical shrinkage of AAS is shown to be remarkably higher than OPC. Furthermore, phase
distribution in the hardened AAS paste and the porosity are calculated. 相似文献
100.
The effect of varying normalising and hardening temperatures on the prior austenite grain size in a low alloy Cr–Mo–Ni–V steel
has been examined. An initial relative insensitivity of grain size to increasing austenitising temperature was observed followed
by a sudden growth of grains at approximately 1000 °C. A detailed study of the precipitates in the steel showed the presence
of a bimodal size distribution of vanadium carbides. The grain size increase is attributed to a decrease in volume fraction
and an increase in size of V4C3 particles with increasing temperature. 相似文献