Simultaneous Removal of Four Dye Pollutants in Mixture Using Amine Functionalized Kit-6 Silica Mesoporous Magnetic Nanocomposite

In this study, Kit-6 silica mesoporous was created on the surface of magnetite core having silica shell and functionalized by amine group to form Fe3O4@SiO     

The impact of connate water saturation and salinity on oil recovery and CO2 storage capacity during carbonated water injection in carbonate rock

Carbonated water injection (CWI) is known as an efficient technique for both CO₂ storage and enhanced oil recovery (EOR). During CWI process, CO₂ moves from the water phase into the oil phase and results in oil swelling. This mechanism is considered as a reason for EOR. Viscous fingering leading to early breakthrough and leaving a large proportion of reservoir un-swept is known as an unfavorable phenomenon during flooding trials. Generally, instability at the interface due to disturbances in porous medium promotes viscous fingering phenomenon. Connate water makes viscous fingers longer and more irregular consisting of large number of tributaries leading to the ultimate oil recovery reduction. Therefore, higher in-situ water content can worsen this condition. Besides, this water can play as a barrier between oil and gas phases and adversely affect the gas diffusion, which results in EOR reduction. On the other hand, from gas storage point of view, it should be noted that CO₂ solubility is not the same in the water and oil phases. In this study for a specified water salinity, the effects of different connate water saturations (S_wc) on the ultimate oil recovery and CO₂ storage capacity during secondary CWI are being presented using carbonate rock samples from one of Iranian carbonate oil reservoir. The results showed higher oil recovery and CO₂ storage in the case of lower connate water saturation, as 14% reduction of S_wc resulted in 20% and 16% higher oil recovery and CO₂ storage capacity, respectively.     

Polyamide 6 nanocomposites incorporating cellulose nanocrystals prepared by In situ ring‐opening polymerization: Viscoelasticity,creep behavior,and melt rheological properties

The creep behavior and solid and melt linear viscoelasticity of novel polyamide 6 (PA6) nanocomposites reinforced with cellulose nanocrystals (CNCs) prepared via in situ anionic ring‐opening polymerization (ROP) were investigated to accelerate research efforts to develop new polymeric materials with improved properties for lightweight, load‐bearing applications. The obtained results showed that incorporation of relatively small amounts of ≤ 2wt% CNCs into the PA6 thermoplastic matrix gave nanocomposite samples with significantly enhanced creep and viscoelastic materials functions of the PA6 as indicated by lower creep strain, lower creep compliance, improved elastic recovery after removal of load, and reduced Arrhenius activation energies for time‐dependent viscoplastic flow. The obtained results were analyzed and interpreted by theoretical equations for predicting the viscoelasticity and creep behavior of polymeric systems. The melt rheological properties showed enhanced melt strength and elasticity. The formation of a percolated network structure of CNC was revealed by morphological observations that were consistent with the dynamic structure break‐up and reformation rheological experiments. The stiffness, rigidity of the CNCs along with their special ROP‐facilitated intrinsic strong chemical interactions with the PA6 matrix is believed to be responsible for the observed superior creep and viscoelastic materials functions even with very little CNC concentration. POLYM. ENG. SCI. 56:1045–1060, 2016. © 2016 Society of Plastics Engineers     

Investigation of factors affecting dynamic modulus and phase angle of various asphalt concrete mixtures

This study investigated the dynamic response of various asphalt concrete (AC) mixtures subjected to sinusoidal loading. Eight AC mixtures (four wearing and four base course) were selected including (but not limited to): superpave, asphalt institute manual series, and dense bituminous macadam. The uniaxial dynamic modulus (|E*|) test at various temperatures (4.4–54.4 °C) and frequencies (0.1–25 Hz) was conducted using asphalt mixture performance tester. Statistical analysis of two-level factorial was employed to regulate the factors affecting the AC mixtures. The results revealed that an increase in temperature (from 21.1 to 37.8 °C), translated into 45 and 43 % drop in |E*| values on average while 80 and 67 % decrease in |E*| values was attributed to the sweep of frequency (from 25 to 0.1 Hz) for wearing and base course mixes, respectively. Non-linear regression model was developed to express the dynamic modulus as a function of test temperature, loading frequency and mixture volumetric parameter. Furthermore, Witczak model of dynamic modulus prediction was evaluated and the results indicated a close fit with an average under prediction error of 0.20. The study characterized and ranked the representative AC mixtures that could help in selecting the material/gradation for mechanistic-empirical pavement design approach.     

Contact-Sorption Drying of Penicillium bilaii in a Fluidized Bed Dryer

A fluidized bed dryer and drying system have been designed, constructed and operated to produce a powdered formulation of the fungus Penicillium bilaii. The dryer includes an air-shear atomizer and rotatable air vibrator to produce particles which are evenly coated with P. bilaii. The drying system included a humidifier, oven, vacuum pump and instrumentation to ensure precise control of operating conditions. Instant skim milk powder was found to be the best particle source for fixing the spores due to its solubility in water, its highly porous nature and because its moisture isotherms were similar to those of the spores. The dryer was operated at 35°C to maximize the drying rate while still preventing thermal death of the spores. The fluidizing air was best provided at an RH of 30%, thereby producing skim milk/spore particles with just the right amount of moisture to ensure long term storage viability. Storage under refrigeration conditions showed little long term decline in spore viability after 3 months of tests. Room temperature storage demonstrated a small decline rate in spore viability with little significant change if held at room temperature for a few days. © 1997 SCI.     

Single fiber colorless symmetric WDM-PON architecture using time interleaved remodulation technique for mitigating Rayleigh backscattering resilience

A time interleaved differential phase shift keying (DPSK) remodulation technique is proposed to mitigate the effect of Rayleigh backscattering (RBS)-induced noise in a single fiber colorless wavelength-division-multiplexing passive optical network (WDM-PON). In order to achieve a cost effective optical network unit (ONU) solution without dedicated laser sources for upstream signals to provide optimum symmetric capacity in a colorless WDM-PON, remodulation becomes the core attraction. Also as the performance of colorless WDM-PON systems suffers from the transmission impairments due to RBS, it is mitigated by using this remodulation scheme. Simulation results show that downstream and upstream signals achieve the error-free performance at 10 Gbit/s with negligible penalty, and enhance the tolerance to RBS-induced noise over a 25 km single-mode fiber.     

Effect of melamine polyphosphate on thermal degradation of polyamides: a combined X-ray diffraction and solid-state NMR study

The effect of melamine polyphosphate (MpolyP) on the thermal degradation of both polyamide 66 (PA66) and polyamide 6 (PA6) was studied using a combination of solid-state techniques. The mixtures of MpolyP with polyamides were heated for different times at 350 and 450 °C. The residues were then analyzed by X-ray diffraction and both solid-state ¹³C NMR and ³¹P NMR. The chemical structures formed in these oven experiments were used to study the chemical changes that take place during a standard flammability test. The mixtures of MpolyP with polyamides were also characterized by frequency-dependent rheological experiments. It was shown that MpolyP could induce significant cross-linking in PA66 and leads to dramatic depolymerization of PA6. These results were used to explain the performance of MpolyP as a flame retardant in these polyamides.     

SIMULATION OF THERMAL AND DISINFESTATION CHARACTERISTICS OF A FORAGE DRYER

The thermal morality data for the cocoon stage of the insect Sitodiplosis mosellana (Gehin) were fitted to a normal distribution function and a probit viability equation was developed. The equation was included in a new tunnel dryer simulation program to compute the cumulative mortality of the insect during baled- forage drying. From the analysis it became clear that the temperature of dried forage remained at or above 60 C during drying and thus 99.99% kill of the insect was assured.