Forest biomass supply logistics for a power plant using the discrete-event simulation approach

This study investigates the logistics of supplying forest biomass to a potential power plant. Due to the complexities in such a supply logistics system, a simulation model based on the framework of Integrated Biomass Supply Analysis and Logistics (IBSAL) is developed in this study to evaluate the cost of delivered forest biomass, the equilibrium moisture content, and carbon emissions from the logistics operations. The model is applied to a proposed case of 300 MW power plant in Quesnel, BC, Canada. The results show that the biomass demand of the power plant would not be met every year. The weighted average cost of delivered biomass to the gate of the power plant is about C$ 90 per dry tonne. Estimates of equilibrium moisture content of delivered biomass and CO₂ emissions resulted from the processes are also provided.     

Water Management of Irrigation Dams Considering Climate Variation: Case Study of Zayandeh-rud Reservoir, Iran

Dependency of reservoir operation on the climate variation occurs especially in regions, where agricultural demand has a significant share of the total water demands. The variability between demands that are based on annual climate conditions may be larger than the uncertainty associated with other explanatory variables in long-term operation of an irrigation dam. This paper proposed a rule curves to the water managers of the Zayandeh-rud reservoir in Iran in long-lead reservoir operation. A regional optimal allocation of water among different crops and irrigation units is developed. The optimal allocation model is coupled with a reservoir operating model, which is developed based on the certain hedging that deals with the available water and the water demands mutually. This coupled model is able to activate restrictions on allocating water to agricultural demands considering variation of inflow to the reservoir, variation of demands and the economic value of allocating water among different crops and irrigation units. The resulted rule curve is presented with a number of tables for more details and accuracy and a simple curve, which is more useful for operational purpose.     

Monitoring and Evaluation Scheme using the Multiple-Criteria-Decision-Making Technique: Application to Irrigation Projects

The application of monitoring and evaluation (M&E) systems to assess agricultural projects has received some attention in recent years. These systems provide valuable information for managers and decision makers by analyzing the implementation process, the progress of trends, and the long-term and short-term effectiveness of these projects. An algorithm is developed to monitor and evaluate drip and pressure irrigation projects in Iran. Different indicators are identified and the framework of an integrated evaluation system is demonstrated using an analytical hierarchy process for multiple-criteria-decision making. There is much subjective information that is quantified and normalized in order to remove any bias in evaluators’ assessment of qualitative measures or sensitivity to linguistic expressions. The application of this system to rank projects in different regions (zones) in Iran is also presented in this paper. The results have shown the significant value of such systems in providing information and input for different decision-making levels.     

Monoclonal behavior of molecularly imprinted polymer nanoparticles in capillary electrochromatography

A new approach based on miniemulsion polymerization is demonstrated for synthesis of molecularly imprinted nanoparticles (MIP-NP; 30-150 nm) with "monoclonal" binding behavior. The performance of the MIP nanoparticles is characterized with partial filling capillary electrochromatography, for the analysis of rac-propranolol, where (S)-propranolol is used as a template. In contrast to previous HPLC and CEC methods based on the use of MIPs, there is no apparent tailing for the enantiomer peaks, and baseline separation with 25,000-60,000 plate number is achieved. These effects are attributed to reduction of the MIP site heterogeneity by means of peripheral location of the core cross-linked NP and to MIP-binding sites with the same ordered radial orientation. This new MIP approach is based on the substitution of the functional monomers with a surfactant monomer, sodium N-undecenoyl glycinate (SUG) for improved inclusion in the MIP-NP structure and to the use of a miniemulsion in the MIP-NP synthesis. The feasibility of working primarily with aqueous electrolytes (10 mM phosphate with a 20% acetonitrile at pH 7) is attributable to the micellar character of the MIP-NPs, provided by the inclusion of the SUG monomers in the structure. To our knowledge this is the first example of "monoclonal" MIP-NPs incorporated in CEC separations of drug enantiomers.     

Prediction of asphaltene deposition during turbulent flow using heat transfer approach

In this study, asphaltene deposition from crude oil has been studied experimentally using a test loop and prediction using theoretical study under turbulent flow (Reynolds numbers below 5000). The effects of many parameters such as oil velocity, surface temperature and concentration of flocculated asphaltene on the asphaltene deposition were investigated. The results showed that asphaltene deposition thickness increases with increasing both surface temperature and concentration of flocculated asphaltene and decreasing oil velocity. Thermal approach was used to describe the mechanisms involved in this process and the results of data fitting showed that there are good agreements between the results of the proposed model and the measured asphaltene deposition rates.     

Amino acid bound surfactants: a new synthetic family of polymeric monoliths opening up possibilities for chiral separations in capillary electrochromatography

By combining a novel chiral amino-acid surfactant containing an acryloyl amide tail, a carbamate linker, and a leucine headgroup of different chain lengths with a conventional cross-linker and a polymerization technique, a new "one-pot" synthesis for the generation of amino-acid based polymeric monolith is realized. The method promises to open up the discovery of an amino-acid based polymeric monolith for chiral separations in capillary electrochromatography (CEC). The possibility of enhanced chemoselectivity for simultaneous separation of ephedrine and pseudoephedrine containing multiple chiral centers and the potential use of this amino-acid surfactant bound column for CEC and CEC coupled to mass spectrometric detection are demonstrated.     

Soil Moisture Information And Thermal Microwave Emission

This paper presents theoretical and experimental results that demonstrate the depth to which soil moisture can be directly measured using microwave radiometers. The experimental results also document the effect of uniform surface roughness on the response of thermal microwave emission to soil moisture. Experimental measurements were executed in July 1980 at the Texas A&M University Research Farm near College Station, TX. Thermal microwave emission measurements were made at 1.4, 4.9, and 10.7 GHz at both vertical and horizontal polarization at off nadir angles from 0 to 50°. It has been demonstrated that passive microwave measurements at frequencies down to 1.4 GHz can only measure soil moisture directly to very shallow soil depths, approximately 2 cm. This is due to the fact that the soil moisture dependence of the transmission coefficient across the air-soil interface predominates over the soil moisture dependence of the total energy originating within the soil volume. It also has been demonstrated that the combination of low incident angle and measurement frequency in the C-band range does not minimize the effect of surface roughness for passive microwave measurements. This result is significant in view of the fact that this combination of frequency and incident angle has been described as the optimum combination for minimizing the effect of surface roughness on the response of radar-backscatter measurements to soil moisture.     

Maximum SiO2 layer thickness by utilizing polyethylene glycol as the surfactant in synthesis of core/shell structured TiO2–SiO2 nano-composites

TiO₂–SiO₂ nano-composites with the core/shell structure have been prepared by means of a technique based on an extension of well-known Stöber process. In this way, the silica coating of TiO₂ nano-particles in the presence of various commercially available surfactants of cationic, anionic and nonionic has been conducted with the aim to increase barrier properties against UV (UV blocking) radiation, in order to optimize photo-killing ability of the TiO₂ nano-particles and decline of the high photo-catalytic property of titania. The influences of varying coating parameters such as time and temperature on the silica content of nano-composites have been studied and optimum conditions for attaining a thick layer of SiO₂ have been determined. Electro-phoretic mobility measurements indicated that the silica coating shifted the iso-electric point of titania toward that of a typical pure colloidal silica. Surface elemental composition of core/shell structured TiO₂–SiO₂ nano-composites was verified by using energy dispersive X-ray analysis. It was found that maximum silica shell thickness can be obtained in the presence of polyethylene glycol as a nonionic surfactant at 80 °C for 360 min. The photo-catalytic activities were evaluated by the degradation of an aqueous solution of methylene blue under UV light irradiation. In addition, the resultant optimum nano-composites have been characterized by FESEM, TEM, BET, FTIR and UV–Vis spectroscopy.     

Application of Magnetic ordered mesoporous carbon Nanocomposite for the Removal of Ponceau 4R Using Factorial Experimental Design

Silicon - Nanocomposites of ordered mesoporous carbon with silica coated magnetite nanoparticles (Fe3O4@SiO2-CMK-8, MNCs) were synthesized by carbonizing sucrose inside the pores of the Kit-6...