Lipid‐derived monomer and corresponding bio‐based nanocomposites

Fatty acid based monomer and corresponding hybrid polymer layered silicate nanocomposites have successfully been prepared by using in situ polymerizations. The hybrid materials were prepared by adding different ratios of nanoclay during free radical homopolymerization of 2‐(acryloyloxy)ethyl stearate (AOES) monomer and copolymerization of AOES with styrene. AOES monomer was synthesized by treating stearic acid with 2‐hydroxyethyl acrylate. The formation of AOES monomer, homopolymer and copolymer was confirmed by ¹H NMR spectroscopic analysis. Further analysis and characterization of the nanocomposites were carried out by XRD, transmission electron microscopy, AFM and attenuated total reflectance Fourier transform infrared spectroscopy. TGA of the polymer nanocomposites was also carried out to evaluate their thermal stability, while flammability tests were conducted to investigate the effect of layered silicate on flame retardancy. Nanofiller addition into the polymer matrix substantially improved the thermal properties and fire retardancy of the composites. © 2016 Society of Chemical Industry     

Development of a crack created by hydraulic fracturing in a compressed block structure rock

The authors estimated trajectory of a created crack in a block-structured rock mass during hydraulic fracturing, and analyzed effect of the parameters of the block medium and two-axis compression field on the main crack trajectory and on the opening of lineal segments of the crack.     

Wave propagation in the 2d periodical model of a block-structured medium. Part I: characteristics of waves under impulsive impact

The authors use a two-dimension plane model to analyze seismic wave propagation in block-structured media under impulse loading. Dynamics of the medium is described by means of pendulum approximation, where blocks are considered incompressible and deformation and displacement occur via compressible intermediate layers. The simplest calculation model of a square lattice composed of masses and springs connected in axial and diagonal directions is under discussion in the article.     

High purity pion beam at TRIUMF

An extension of the TRIUMF M13 low-energy pion channel designed to suppress positrons based on an energy-loss technique is described. A source of beam channel momentum calibration from the decay π⁺→e⁺ν is also described.     

Optimization of a Continuous Precipitation Process to Produce Nanoscale BaSO4

The effect of supersaturation, reaction temperature, and mixing intensity on particle size was investigated. Sterical stabilization of barium sulfate suspensions was applied to prevent formation of agglomerates. This allowed a reactant ratio of 1:1, thus maximizing product yield. The local supersaturation is strongly affected by the mixing intensity that can be characterized by Reynolds numbers. The significant decrease in particle size was observed by increasing the Reynolds number from 600 to 8000. A higher reactant concentration leads to a higher degree of supersaturation, and finer particles are precipitated. The particle size can be reduced with increasing reactant concentration. The degree of supersaturation increases with temperature reduction, i.e., the particle size will be reduced at low temperature. In addition, nucleation and growth kinetics are changed in a way that reduces the particle size. The optimized lab‐scale process is capable of producing over 1 kg h^–1 of nanoscaled BaSO₄ with a median diameter of 75 nm.     

The influence of general identity disturbance on reports of lifetime substance use disorders and related outcomes among sexual minority adults with a history of substance use.

Previous research has shown that sexual minority (i.e., nonheterosexual) individuals report increased problematic substance use involvement, compared with their sexual majority counterparts. We hypothesize that feelings of an unstable sense of self (i.e., identity disturbance) may potentially drive problematic substance use. The purpose of the current study is to examine identity disturbance among sexual minorities as a potential explanatory mechanism of increased sexual minority lifetime rates of substance dependence. Measures of identity disturbance and three indicators of sexual orientation from lifetime female (n = 16,629) and male (n = 13,553) alcohol/illicit drug users in Wave 2 of the National Epidemiologic Survey on Alcohol and Related Conditions (NESARC) were examined. Findings generally showed that the increased prevalence of alcohol dependence, illicit drug dependence, and combined alcohol/illicit drug dependence as well as a younger age of alcohol use initiation among sexual minority women was associated with elevated levels of identity disturbance. The results were consistent with a mediational role for identity disturbance in explaining the association between sexual minority status and substance dependence and were generally replicated among male sexual minority respondents. The current research suggests that identity disturbance, a predictor of substance use, may contribute to heightened risk for substance dependence among certain subgroups of sexual minority individuals. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A human-assisted knowledge extraction method for machining operations

This paper deals with a human-assisted knowledge extraction method to extract “if…then…” rules from a small set of machining data. The presented method utilizes both probabilistic reasoning and fuzzy logical reasoning to benefit from the machining data and from the judgment and preference of a machinist. Using the extracted rules, one can determine the values of operational parameters (feed, cutting velocity, etc.) to ensure the desired machining performance (keep surface roughness within the stipulated range (e.g., moderate)). Applying the presented method in a real-life machining knowledge extraction situation and comparing it with the inductive learning based knowledge extraction method (i.e., ID3), the usefulness of the method is demonstrated. As the concept of manufacturing automation is shifting toward “how to support humans by computers”, the presented method provides some valuable hints to the developers of futuristic computer integrated manufacturing systems.     

Bending Vibrations of Long Rod during Face Impact

The possibility is investigated for failure of long rods under face impact caused by the stability loss of longitudinal deformation. The formula is obtained for calculating the maximum tensile stress during bending under the action of prescribed duration and intensity.     

A clinical technique for temporization of teeth to receive porcelain laminate veneers

Temporization of teeth prepared for porcelain laminate veneers is sometimes necessary to preserve occlusal relationships, prevent sensitivity or maintain esthetics. The literature describes several techniques which satisfy different requirements for temporization. A modified technique is presented that satisfies at once: occlusion, sensitivity and esthetic needs. Clinical time spent with the patient is minimized by fabricating a matrix on a diagnostic cast prior to the preparation/ impression appointment.