Malic acid complex method for preparation of LiNiVO4 nano-crystallites

LiNiVO₄ nano-crystallites were prepared by the polymerized complex method using Li₂CO₃, Ni(CH₃COO)₂·4H₂O and NH₄VO₃ as starting reagents and malic acid as a complexing agent. With the subsequent calcination at 450 °C, the powder analyzed by XRD, FTIR, Raman, electron diffraction, SEM and TEM techniques was found to be inverse spinel LiNiVO₄ with ∼20 nm in diameter. TGA shows continuous weight loss at 40–450 °C due to the evaporation and decomposition processes. Above 450 °C, weight percent tended to be constant. In addition, formation mechanism of the purified LiNiVO₄ was proposed to relate with the experimental results.     

Determination of Optimum Velocity for Various Nanofluids Flowing in a Double-Pipe Heat Exchanger

Piping is one of the most important issues in the cost of process factories. It is known that 80% of bought equipment cost or 20% of overhead capital can belong to piping cost in a fluid-process factory. Pipe diameter and therefore flow velocity strongly affect the existing value of the factory regarding the consumed electric energy and fitting cost of pipes, pumps, and valves. We give a detailed cost analysis model for the pure fluids of water, motor oil, glycerin, ammonia, methanol, ethanol, ethylene glycol, and propane and their nanofluid mixtures with Ti and TiO₂ particles in liquid phase flowing in the tube side of a double-pipe heat exchanger. Pressure drop and pumping power values increase with flow velocity but total cost values show an arc with it. The clear outcome is that there is a minimum cost value as a result of the analyses for each investigated fluids. Moreover, validation of the model is performed by plotting the calculated items in figures such as total heat transfer coefficient versus Reynolds number, pressure drop versus Reynolds number, and friction factor versus mass flow rate. Characteristics of the trend lines in these figures are seen as they should be.     

Effect of fin pitches on the optimum heat transfer performance of crimped spiral fin-and-tube heat exchangers

This study conducted experiments on the optimized fin pitch for crimped spiral fin-and-tube heat exchangers. The experiments covered a size range of 2.4–6.5 mm, which is the manufacturing limitation for this kind of fin. The water-flow arrangement used in this experiment combined the parallel cross-flow and the counter cross-flow in a two-row configuration. Ambient air was used as the working fluid on the air-side, and hot water was used on the tube-side. The effects of fin pitches on the heat transfer coefficient and pressure drop characteristics were studied. The results clearly showed that the convective heat transfer coefficient (h_o) for a fin pitch of 2.4 mm is relatively low compared with that of other fin pitches with the same air frontal velocity. Using larger fin pitches (i.e., 4.2, 6.2, and 6.5 mm) resulted in negligible differences in the pressure drop. Moreover, this work introduces the parameter of three performances indexes, which can be expressed as the ratio of the desired output to the required input, for optimization purposes. Due to the difference in optimum fin pitch obtained by these performance indexes, an intersection analysis was conducted. The results indicated that the optimum fin pitch is 4.2 mm for this work, which could be valuable for the effective design for industrial thermal-system applications.     

Sulfur- and water-tolerance of Pt/KL aromatization catalysts promoted with Ce and Yb

Different Pt/KL catalysts containing rare earth (RE; Ce and Yb) promoters were prepared by two techniques, incipient wetness impregnation (IWI) and vapor phase impregnation (VPI). The catalysts were tested for the activity and the selectivity of n-hexane aromatization to benzene under clean, sulfur-containing, and water-containing feeds at 500 °C. It was observed that the catalysts prepared by the VPI technique exhibited much higher activity and selectivity than those prepared by IWI. It was also found that although under clean conditions, the addition of Ce or Yb caused a decrease in activity, in the presence of sulfur the addition of Ce and to a lesser extent Yb, significantly inhibited catalyst deactivation.

The influence of water in the feed was investigated by contacting the catalysts for 1 h to a feed containing 3 mol.% water. After this treatment, all the catalysts exhibited a significant activity loss. This loss was more pronounced for the catalyst prepared by the VPI method. The catalyst prepared by IWI already had suffered a significant deactivation before the water treatment, so the activity drop was not so pronounced. The sample prepared by VPI not only showed a drop in activity immediately after the water treatment but it became more susceptible to deactivation afterwards. By contrast, the Ce-promoted catalyst showed a more stable activity after the water treatment.

All catalysts were characterized before and after reaction by a number of techniques. In agreement with previous studies, FT-IR of adsorbed CO and chemisorption results indicated that the VPI method resulted in higher Pt dispersion than that obtained by the IWI method. After reaction in the presence of sulfur, the Ce-promoted Pt/KL catalyst showed a higher resistance to metal agglomeration and a lower rate of coke formation than the unpromoted Pt/KL. On all the catalysts, the amount of carbon deposits was greater in the presence of sulfur and after exposure to water vapor than under the reaction with clean feeds. This difference is explained in terms of metal particle growth and location in the zeolite.     

Congestion tracking control for wireless TCP/AQM network via immersion and invariance

This paper deals with an immersion and invariance (I&I) control design for wireless Transmission Control Protocol (TCP) network to solve Active Queue Management (AQM) problems. With the help of this strategy, the developed control law can be used to cope with congestion tracking problems for a nonlinear wireless network model. Besides, the nonlinear congestion control law is proposed to assure that the queue length is able to track the desired queue length despite having sudden changes. The developed control design is validated in the MATLAB environment. The effectiveness of the developed control is verified through a simulation and compared with integral backstepping design, backstepping design, sliding mode design, and synergetic control design. The simulation results demonstrated that the presented strategy is not only able to solve the desired congestion tracking control problem but also provide improved transient performances.     

Fuel consumption and emission comparison of conventional and hydrogen feed vehicles

Current environmental concerns on nitrogen oxides (NO_x) and particulate matter (PM) emissions caused by diesel engines have led researchers to be interested in investigating vehicles with alternative power sources. Because of this reason, vehicle models with SI engine were adopted in the conducted study. Firstly, as an initial step, 1-D SI engine models were created with use of AVL Boost software. A four-cylinder engine model was created for conventional vehicle model, while a two-cylinder downsized engine was adopted as a subsystem of hybrid vehicle model. The models were based on experimental data obtained from a laboratory test setup with a single-cylinder engine. Subsequently, detailed engine maps on emissions and fuel consumption were generated with the developed ANN model. The fuel consumption and emission data, which were gathered from NEDC and WLTC simulations, were compared for conventional ICE, PEM FC and PEM FC + ICE powered vehicles with the help of the vehicle model which was developed by using Matlab Simulink software. Based on the results, it was concluded that there might be sufficient improvement in fuel consumption and significant improvement in emissions with the use of PEM FC that a hybrid driving system (PEM FC + ICE) can be utilized, and that emissions can be at 0 with the sole use of PEM FC.     

Experimental and numerical studies on heat transfer enhancement for air conditioner condensers using a wavy fin with a rectangular winglet

Journal of Mechanical Science and Technology - The air side thermal performance of wavy fins with rectangular winglets are studied using experimental and numerical methods. The following parameters...     

Two-Phase Flow Across Small Sudden Expansions and Contractions

Two-phase flow approaching singularities such as abrupt expansions and sudden contractions is widely encountered in typical industrial and heat exchanging devices. There have been some studies concerning this subject but they mostly are applicable for larger channels. In this study, the first attempt is made to review the existing efforts concerning two-phase flow across sudden expansions/contractions and to examine the applicability of the existing correlations with respect to the recent data in small channels. The second part of this study presents some newly measured pressure drops and observed flow patterns pertaining to some special flow phenomena by expansion/contraction. For an abrupt expansion, it is found that the existing correlations all fail to provide a reasonably predictive capability against the newly collected data. Furthermore, a unique flow pattern called “liquid jet-like flow pattern” occurs at a very low quality region of total mass flux of 100 kg · m^?2· s^?1, and it raises a setback phenomenon of pressure drop. By contrast, an appreciable increase of pressure difference is seen when the liquid jet-like flow pattern is completely gone. A similar conclusion is drawn for the data of contractions. For the correlations/predictive models, the homogeneous model gives satisfactory prediction for conventional macro-channels but fails to do so when the channels become smaller. This is especially pronounced for a small-diameter tube with a Bond number being less than 1, in which the effect of surface tension dominates.     

Unconfined laminar nanofluid flow and heat transfer around a square cylinder

The momentum and forced convection heat transfer for a laminar and steady free stream flow of nanofluids past an isolated square cylinder have been studied numerically. Different nanofluids consisting of Al₂O₃ and CuO with base fluids of water and a 60:40 (by mass) ethylene glycol and water mixture were selected to evaluate their superiority over conventional fluids. Recent correlations for the thermal conductivity and viscosity of nanofluids, which are functions of particle volumetric concentration as well as temperature, have been employed in this paper. The simulations have been conducted for Pe = 25, 50, 100 and 200, with nanoparticle diameters of 30 and 100 nm and particle volumetric concentrations ranging from 0% to 4%. The results of heat transfer characteristics of nanofluid flow over a square cylinder showed marked improvement comparing with the base fluids. This improvement is more evident in flows with higher Peclet numbers and higher particle volume concentration, while the particle diameter imposes an adverse effect on the heat transfer characteristics. In addition, it was shown that for any given particle diameter there is an optimum value of particle concentration that results in the highest heat transfer coefficient.