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A comparison of partially acetylated nanocellulose,nanocrystalline cellulose,and nanoclay as fillers for high‐performance polylactide nanocomposites 下载免费PDF全文
Jon Trifol David Plackett Cecile Sillard Ole Hassager Anders Egede Daugaard Julien Bras Peter Szabo 《应用聚合物科学杂志》2016,133(14)
Partially acetylated cellulose nanofibers (CNF) were chemically extracted from sisal fibers and the performance of those CNF as nanofillers for polylactide (PLA) for food packaging applications was evaluated. Three PLA nanocomposites; PLA/CNF (cellulose nanofibers), PLA/CNC (nanocrystalline cellulose), and PLA/C30B (CloisiteTM 30B, an organically modified montmorillonite clay) were prepared and their properties were evaluated. It was found that CNF reinforced composites showed a larger decrease on oxygen transmission rate (OTR) than the clay‐based composites; (PLA/CNF 1% nanocomposite showed a 63% of reduction at 23°C and 50% RH while PLA/C30B 1% showed a 26% decrease) and similar behavior on terms of water vapor barrier properties with 46 and 43%, respectively of decrease on water vapor transmission rate at 23°C and 50% RH (relative humidity). In terms of mechanical and thermomechanical properties, CNF‐based nanocomposites showed better performance than clay‐based composites without affecting significantly the optical transparency. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43257. 相似文献
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采用熔融共混法制备了尼龙6/苯乙烯-马来酸酐共聚物/N-苯基马来酰亚胺共混物(PA6/SMA/N-PMI),并利用DSC、TGA及力学性能测试等手段研究了SMA用量对PA6/SMA/N-PMI共混物熔融结晶行为、热学性能以及力学性能的影响。结果表明,共混物的最大分解温度较纯PA6有较大提高;SMA用量的增加,共混物的结晶温度、结晶度以及熔融焓均先降低再升高;当SMA用量为5份时,共混物的弯曲强度、弯曲模量以及热变形温度均达到最大值,分别为113.8、3 053 MPa及61.3℃,较纯PA6分别提高了25.1%、28.0%及19.0%;拉伸强度在SMA用量为7.5份时达到最大值81.4 MPa,较纯PA6提高了17.1%。 相似文献
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Robust identification with FIR models fails to be successful when the number of coefficients to be estimated becomes large, caused by lightly damped modes of the plant or poles very close to the unit circle. The paper presents a two-stage algorithm to obtain a low-order approximate model in frequency domain in a generalized orthonormal basis with guaranteed H∞ error bound for deterministic linear time-invariant stable systems, the first stage being an L∞ rational approximation and the second nonlinear step being an H ∞ rational approximation 相似文献
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Evolutionary multiobjective optimization for base station transmitter placement with frequency assignment 总被引:2,自引:0,他引:2
Weicker N. Szabo G. Weicker K. Widmayer P. 《Evolutionary Computation, IEEE Transactions on》2003,7(2):189-203
We propose a new solution to the problem of positioning base station transmitters of a mobile phone network and assigning frequencies to the transmitters, both in an optimal way. Since an exact solution cannot be expected to run in polynomial time for all interesting versions of this problem (they are all NP-hard), our algorithm follows a heuristic approach based on the evolutionary paradigm. For this evolution to be efficient, i.e., goal-oriented and sufficiently random at the same time, problem-specific knowledge is embedded in the operators. The problem requires both the minimization of the cost and of the channel interference. We examine and compare two standard multiobjective techniques and a new algorithm - the steady-state evolutionary algorithm with Pareto tournaments. One major finding of the empirical investigation is a strong influence of the choice of the multiobjective selection method on the utility of the problem-specific recombination leading to a significant difference in the solution quality. 相似文献