Diphenylamine‐Substituted Cruciform Oligo(phenylene vinylene): Enhanced One‐ and Two‐Photon Excited Fluorescence in the Solid State

1,4‐di(4′‐N,N‐diphenylaminostyryl)benzene (DPA‐DSB) is a well known compound with a large two‐photon absorption (TPA) section and strong fluorescence in solution. However, the ease with which it crystallizes results in the formation of discontinuous crystalline phases during vacuum deposition processes, thereby greatly limiting its applicability in solid‐state devices. A cruciform dimer of DPA‐DSB, 2,5,2′,5′‐tetra(4′‐N,N‐diphenylaminostyryl)biphenyl (DPA‐TSB) is reported, wherein two DPA‐DSB molecules are linked through a central biphenyl bond. The DPA‐TSB molecules take on a cruciform configuration because of the steric crowding around the central biphenyl core, which has the effect of efficiently suppressing crystalline and intermolecular interactions. The neat DPA‐TSB solid shows strong green–blue fluorescence because of both steady‐state absorption as well as TPA. The DPA‐TSB solid exhibits a photoluminescence (PL) efficiency (η_solid) of 29 % and a solid‐state two‐photon action cross section (δη_solid) of 954 GM (1 GM = 1 × 10^–50 cm⁴ s photon^–1 molecule^–1), which is much greater than for the model compound DPA‐DSB (η_solid = 16 % and δη_solid = 150 GM, where δ is the TPA cross section and η is the fluorescence quantum yield). Based on its high PL efficiency, good film‐forming ability, and strong TPA, DPA‐TSB seems to be a good candidate for applications in solid‐state optical devices.     

Hydrophobic Chromophores in Aqueous Micellar Solution Showing Large Two‐Photon Absorption Cross Sections

A series of new hydrophobic two‐photon absorbing (2PA) chromophores with varied electron‐donating groups in quasi‐linear and multibranched structures are synthesized to correlate their structure/photophysical property relationships. The feasibility of using these large two‐photon absorption cross‐sectional (δ, expressed in GM = 1 × 10^–50 cm⁴ s photon^–1 molecule^–1) materials in aqueous solution is also explored. All four hydrophobic 2PA materials can be encapsulated into micelles generated by dispersing an amphiphilic block copolymer, poly(methacrylic acid)‐block‐polystyrene (PMAA‐b‐PS), into water. The micellar nanostructures are characterized using dynamic light scattering, atomic force microscopy, and transmission electron microscopy. After these dyes are incorporated into micelles, they exhibit strong fluorescence in water. It is found that the quantum yield and δ values of these chromophores are strongly dependent on the diameters of the micelles, concentrations of the PMAA‐b‐PS, and molecular structures of the 2PA chromophores. One of the compounds that has a strong triarylamino donor and a multibranched structure exhibits a large δ value of 2790 GM and high quantum yield (0.56) in micelle‐containing water. Although this value is smaller than the original value of 5300 GM in toluene, it is still substantially larger than the values of most water‐soluble 2PA materials, which have δ values of less than 100 GM.     

Two-dimensional synthetic aperture images over a land surface scene

The Soil Moisture and Ocean Salinity (SMOS) space mission is currently undergoing phase-B studies at the European Space Agency. The SMOS payload is an L-band interferometric radiometer based on a two-dimensional aperture synthesis concept. This paper presents the first images obtained by a demonstrator of the SMOS instrument over land surfaces at the Avignon test site in 1999     

Traffic engineering in a multipoint-to-point network

The need to guarantee quality-of-service (QoS) to multimedia applications leads to a tight integration between the routing and forwarding functions in the Internet. multiprotocol label switching tries to provide a global solution for this integration. In this context, multipoint-to-point (m2p) networks appear as a key architecture since they provide a cheaper way to connect edge nodes than point-to-point connections. M2p networks have been mainly studied for their load balancing ability. In this paper, we go a step further: we propose and evaluate a traffic management scheme that provides deterministic QoS guarantees for multimedia sources in an m2p network. We first derive an accurate upper bound on the end-to-end delay in an m2p architecture based on the concept of additivity. Broadly speaking, an m2p network is additive if the maximum end-to-end delay is equal to the sum of local maximum delays. We then introduce two admission control algorithms for additive networks: a centralized algorithm and a distributed algorithm and discuss their complexity and their scalability     

Novel high-efficiency concentrator for optical fiber communication

A novel high-efficiency concentrator based on nonimaging optics has been designed and fabricated with micromachining technique. The shape of the concentrator utilizes compound parabolic concentrator (CPC), which can concentrate the all rays that have the angles less than a critical angle &thetas;_c. The theoretical concentration efficiency was calculated by ray trace simulation considering the reflectance of the concentrator's reflective layer. The metal reflection layer of reflectance 95% was formed by gold-nickel mirror plating method in a glass hole. As a result, the concentration efficiency of the concentrator was measured as 89%     

Compositional design of Pb(Zr, Ti)O3 for highly reliableferroelectric memories

We have investigated Pb(Zr,Ti)O₃ (PZT) film composition suitable for highly reliable ferroelectric RAM (FeRAM) application. To obtain a wide operational margin for 2T/2C (two transistors and two capacitors) FeRAMs, the PZT film capacitor is needed to have a low coercive voltage (V_c) and a high dielectric constant on the polarization switching (ϵ_S) and a low dielectric constant on the nonswitching (ϵ_N), or essentially a large ϵ_S/ϵ_N ratio. Concerning the B-site composition in the perovskite structure, it is found that lowering the Zr/Ti ratio from 47/53 to Ti-richer ones increases the ratio of ϵ_S/ϵ_N as a positive effect on the wide operational margin, but increased V_c as a negative effect. Taking the balance of these factors into consideration, it is concluded that an optimum composition, such as Zr/Ti=30/70, provides the maximum operational margin. The A-site composition, on the other hand, affects the long-term reliability of a PZT capacitor. The endurance to the fatigue and imprint are enhanced by reduction of the Pb-excess and dope of La in the A-site. A La-doped PZT (Zr/Ti =30/70) capacitor is successfully integrated to the 8 kbit FeRAM macro with double-layer Al wiring to confirm the feasibility of this capacitor     

Characterization method of thermomechanical parameters for microelectronic materials

Reliability of thermomechanical simulations is critically linked to the accuracy of the mechanical properties that govern the behaviour of structure, like Young's modulus (E) and coefficient of thermal expansion (CTE). For many cases, the values found in literatures are dealing with bulk properties without detailed information on temperature effects. To address such issues, it is necessary to measure the materials parameters as a function of temperature. The measurement of CTE is usually accomplished by evaluating the thermal deflections of a subjected material layer deposited on a substrate, providing that E is known at a specific temperature of experiment. A bilayer method, based on theory of elasticity, is proposed to determine both E and CTE for a given temperature with a good resolution. This paper presents the theoretical analysis, the design and process of the microsystem test structures, and the main calculation results.     

Influence of the nonlinear phase and ASE noise on DPSK balanced optical receiver in optical fiber communication system

The analytical expression of bit error probability in a balanced differential phase-shift keying(DPSK) optical receiver considering nonlinear phase noise and EDFA ASE noise is given,which is very useful to estimate the performance of DPSK balanced and unbalanced receiver in optical communication system.Through analysis,if only nonlinear phase noise is considered,both the balance and unbalanced receivers have the same performances.But if adding the ASE noise of EDFA,the balanced receiver is better.     

A hybrid neural network model for predicting silicon content

The silicon content of the hot metal in the blast furnace ironmaking process normally reflects the thermal state of the furnace and affects the fuel rate. In this paper a hybrid neural network model is proposed to predict the silicon contentn steps ahead. A time-delay neural network, which has self-loops to represent dynamics, is adopted here. The learning procedure of this network has been divided into two states. A BP algorithm with forgetting factor is first introduced to find the appropriate structure of the network. The temporal difference (TD) method with forgetting factor is then used forn-step-ahead prediction. The results show that the method can perform satisfactoryn-step-ahead prediction and is suited for implementation.